Citation: HU Sheng-Zhi, XIE Zhao-Xiong, PALENIK G. J.. Bond Valence Parameters for Sn(II)―X and Sn(IV)―X (X=O, S, N, C, P, As, Se, Te, F, Cl, Br, I)[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 19-24. doi: 10.3866/PKU.WHXB20122819 shu

Bond Valence Parameters for Sn(II)―X and Sn(IV)―X (X=O, S, N, C, P, As, Se, Te, F, Cl, Br, I)

1.
1. Department of Chemistry, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
2. State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian Province, P. R. China;
3. Chemistry Department, The University of Floride, P. O. Box 117200, Gainesville, FL 32611-7200, USA

Received Date: 13 September 2011
Available Online: 9 November 2011

The bond valence parameters (R₀) for homoleptic Sn(II)―X and Sn(IV)―X complexes, where X=O, S, N, C, P, As, Se, Te, F, Cl, Br, and I, were determined using data retrieved from the Cambridge Structural Database with bond valence parameter B=0.037 nm. Some are the first reported experimental values for Sn(II)―X or Sn(IV)―X bonds. In the case of Sn(II)―O, R₀=0.1956 nm with B=0.037 nm can be used to assign the oxidation state of the central Sn(II) ion for almost all coordination numbers. In contrast, the reported parameter set of R₀=0.1859 nm with B=0.055 nm appears applicable mainly to complexes with a low coordination number. Our results suggest that further studies of bond valence parameters are required to better understand the factors that are important in bond valence sum (BVS) calculations.
- Tin compound,
- Bond valence parameter,
- Oxidation state,
- Secondary bond
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