Citation: HAN Xia, CHENG Xin-Hao, HUANG Jian-Bin. Application of Anion-Cation Pair Surfactant Systems to Achieve Ultra-Low Oil-Water Interfacial Tension[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 146-153. doi: 10.3866/PKU.WHXB201228146 shu

Application of Anion-Cation Pair Surfactant Systems to Achieve Ultra-Low Oil-Water Interfacial Tension

1.
1. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. Shengli Engineering & Consulting Co., Ltd., Dongying 257026, Shandong Province, P. R. China

Received Date: 26 August 2011
Available Online: 4 November 2011
Fund Project: 国家自然科学基金(20873001, 50821061, 21073006) (20873001, 50821061, 21073006)国家重点基础研究发展规划项目(973) (2007CB936201)资助 (973) (2007CB936201)

In this paper, ultra-low interfacial tension was obtained in realistic oil-water systems using ion pair surfactant systems. To improve the solubility of the ion pair surfactants, polyoxyethylene chain was introduced into the anionic surfactant molecular structure, and a three-component strategy where ion pair surfactants were combined with a non-ionic surfactant was used. Furthermore, the effects of the structures of the cationic and non-ionic surfactants, distribution ratio of the three components, and surfactant concentration on oil-water interfacial tension were studied. We successfully achieved the ultra-low interfacial tension in the Shengli oil fields using the mixed systems combining ion pairs and non-ionic agents. Several systems possessed an interfacial tension as low as 10^-4 mN·m^-1. Because of the strong electrostatic attraction between surfactant ions, our systems possess ultra-low interfacial tension after adsorption. The results show that after 48 h quartz adsorption, the systems can still reduce the interfacial tension to an ultra-low level.
- Anion-cation pair surfactants,
- Surfactants mixed system,
- Ultra-low interfacial tension,
- Enhanced oil recovery,
- Oil recovery
1. [1]
  (1) Zhang, F.; Hao, J. K.; Lü,W.; Lü, F. L.;Wang, M. Fault-Block Oil & Gas Field 2010, 17 (3), 357. [张峰, 郝金克, 吕玮, 吕芳蕾, 王铭. 断块油气田, 2010, 17 (3), 357.]
2. [2]
  (2) Pang, L. L.; Ning, Y. Q. Inner Mon lia Petrochemical Industry 2010, 8, 142. [庞丽丽, 宁宇清. 内蒙古石油化工, 2010, 8, 142.]
3. [3]
  (3) Wang, Y. F.; Zhang, C. G.; Hou,W. G. Surfactant and Its Applications in Oil Fields; Petroleum Industry Press: Beijing, 1995; p 2. [王云峰, 张春光, 侯万国. 表面活性剂及其在油气田中的应用. 北京: 石油工业出版社, 1995: 2.]
4. [4]
  (4) Zhang, G. Y.; Liu, Q. M.; Li, L. Y.;Wang, H. F.; Yang, Y.; Shan, C. L.;Wu, X. L. Sino-Global Energy 2010, 15, 56. [张国印, 刘庆梅, 李凌云, 王海峰, 杨勇, 单存龙, 伍晓林. 中外能源, 2010, 15, 56.]
5. [5]
  (5) Liu, Q. C. Science Technology and Engineering 2011, 11 (10), 2185. [刘其成. 科学技术与工程, 2011, 11 (10), 2185.]
6. [6]
  (6) Fulcher, R. A., Jr.; Turgay, E. SPE 12170-PA 1985.
7. [7]
  (7) Paul, G.W.; Lake, L.W.; Pope, G. A. SPE 10733 1982.
8. [8]
  (8) Lake, L.W.; Stock, L. G.; Lawson, J. B.; SPE 7069; SPE 5th Symposium on Improved Methods for Oil Recovery: Tulsa Oklahoma, 1978; 16-19.
9. [9]
  (9) Chen, Z. H.; Li, H. B.; Cao, B. G. Offshore Oil 2005, 25 (3), 53. [陈中华, 李华斌, 曹宝格. 海洋石油, 2005, 25 (3), 53.]
10. [10]
  (10) Kang,W. L.; Liu, Y. J. China Surfactant Detergent & Cosmetics 2000, No. 4, 30. [康万利, 刘永建. 日用化学工业, 2000, No. 4, 30.]
11. [11]
  (11) Kang,W. L.; Shan, X. L. Petroleum Geology & Oilfield Development in Daqing 1998, 17 (2), 32. [康万利, 单希林. 大庆石油地质与开发1998, 17 (2), 32.]
12. [12]
  (12) Li, Z. Q.; Guo, X. L.;Wang, H. Y.; Li, Q. H.; Yuan, S. L.; Xu, G. Y.; Liu, C. B. Acta Phys. -Chim. Sin. 2009, 25 (1), 6. [李振泉, 郭新利, 王红艳, 李青华, 苑世领, 徐桂英, 刘成卜. 物理化学学报, 2009, 25 (1), 6.]
13. [13]
  (13) Zhao, T. T.; ng, H. J.; Xu, G. Y.; Cao, X. L.; Song, X.W.; Wang, H. Y. Oilfield Chemistry 2010, 27 (1), 112. [赵涛涛, 宫厚健, 徐桂英, 曹绪龙, 宋新旺, 王红艳. 油田化学2010, 27 (1), 112.]
14. [14]
  (14) Li, S. J.; Yang, Z. Y.; Song, K. P.; Kang,W. L. Acta Petrol Ei Sinica 2003, 24 (5), 72. [李世军, 杨振宇, 宋考平, 康万利. 石油学报, 2003, 24 (5), 72.]
15. [15]
  (15) Zhao, G. X. Physical Chemistry of Surfactants; Peking University Press: Beijing, 1984; pp 179-230. [赵国玺. 表面活性剂物理化学. 北京: 北京大学出版社, 1984: 179-230]
16. [16]
  (16) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action; China light Industry Press: Beijing, 2003; pp 356-382. [赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中国轻工业出版社, 2003: 356-382.]
17. [17]
  (17) Zhu, B. Y.; Shi, H. T.; Huang, J. B.; He, X. Acta Chim. Sin. 2001, 59, 913. [朱瑶, 石洪涛, 黄建滨, 何煦. 化学学报, 2001, 59, 913.]
1. [1]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
2. [2]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
3. [3]
  Yuhui Yang , Jintian Luo , Biao Zuo . A Teaching Approach to Polymer Surface and Interface in Undergraduate Polymer Physics Courses. University Chemistry, 2025, 40(4): 126-130. doi: 10.12461/PKU.DXHX202408056
4. [4]
  Ruilin Han , Xiaoqi Yan . Comparison of Multiple Function Methods for Fitting Surface Tension and Concentration Curves. University Chemistry, 2024, 39(7): 381-385. doi: 10.3866/PKU.DXHX202311023
5. [5]
  Yingying Chen , Di Xu , Congmin Wang . Exploration and Practice of the “Four-Level, Three-Linkage” General Chemistry Course System. University Chemistry, 2024, 39(8): 119-125. doi: 10.3866/PKU.DXHX202401057
6. [6]
  Honglian Liang , Xiaozhe Kuang , Fuping Wang , Yu Chen . Exploration and Practice of Integrating Ideological and Political Education into Physical Chemistry: a Case on Surface Tension and Gibbs Free Energy. University Chemistry, 2024, 39(10): 433-440. doi: 10.12461/PKU.DXHX202405073
7. [7]
  Ruiqin Feng , Ye Fan , Yun Fang , Yongmei Xia . Strategy for Regulating Surface Protrusion of Gold Nanoflowers and Their Surface-Enhanced Raman Scattering. Acta Physico-Chimica Sinica, 2024, 40(4): 2304020-0. doi: 10.3866/PKU.WHXB202304020
8. [8]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
9. [9]
  Meng Lin , Heng Zhang , Shiling Yuan . Exploring a Combined Theory-Practice-Simulation Teaching Model in Physical Chemistry: A Case Study of Surface Tension. University Chemistry, 2025, 40(4): 189-194. doi: 10.12461/PKU.DXHX202407053
10. [10]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259
11. [11]
  Jiandong Liu , Xin Li , Daxiong Wu , Huaping Wang , Junda Huang , Jianmin Ma . Anion-Acceptor Electrolyte Additive Strategy for Optimizing Electrolyte Solvation Characteristics and Electrode Electrolyte Interphases for Li||NCM811 Battery. Acta Physico-Chimica Sinica, 2024, 40(6): 2306039-0. doi: 10.3866/PKU.WHXB202306039
12. [12]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2408007-0. doi: 10.3866/PKU.WHXB202408007
13. [13]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
14. [14]
  Yajuan Xing , Hui Xue , Jing Sun , Niankun Guo , Tianshan Song , Jiawen Sun , Yi-Ru Hao , Qin Wang . Cu₃P-Induced Charge-Oriented Transfer and Surface Reconstruction of Ni₂P to Achieve Efficient Oxygen Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(3): 2304046-0. doi: 10.3866/PKU.WHXB202304046
15. [15]
  Zhuo Han , Danfeng Zhang , Haixian Wang , Guorui Zheng , Ming Liu , Yanbing He . Research Progress and Prospect on Electrolyte Additives for Interface Reconstruction of Long-Life Ni-Rich Lithium Batteries. Acta Physico-Chimica Sinica, 2024, 40(9): 2307034-0. doi: 10.3866/PKU.WHXB202307034
16. [16]
  Yanhui Sun , Junmin Nan , Guozheng Ma , Xiaoxi Zuo , Guoliang Li , Xiaoming Lin . Exploration and Teaching Practice of Ideological and Political Elements in Interface Physical Chemistry: Taking “Additional Pressure on Curved Surfaces” as an Teaching Example. University Chemistry, 2024, 39(11): 20-27. doi: 10.3866/PKU.DXHX202402023
17. [17]
  Jianan Hong , Chenyu Xu , Yan Liu , Changqi Li , Menglin Wang , Yanwei Zhang . Decoding the interfacial competition between hydrogen evolution and CO₂ reduction via edge-active-site modulation in photothermal catalysis. Acta Physico-Chimica Sinica, 2025, 41(9): 100099-0. doi: 10.1016/j.actphy.2025.100099
18. [18]
  Jingkun Yu , Xue Yong , Ang Cao , Siyu Lu . Bi-Layer Single Atom Catalysts Boosted Nitrate-to-Ammonia Electroreduction with High Activity and Selectivity. Acta Physico-Chimica Sinica, 2024, 40(6): 2307015-0. doi: 10.3866/PKU.WHXB202307015
19. [19]
  Wentao Xu , Xuyan Mo , Yang Zhou , Zuxian Weng , Kunling Mo , Yanhua Wu , Xinlin Jiang , Dan Li , Tangqi Lan , Huan Wen , Fuqin Zheng , Youjun Fan , Wei Chen . Bimetal Leaching Induced Reconstruction of Water Oxidation Electrocatalyst for Enhanced Activity and Stability. Acta Physico-Chimica Sinica, 2024, 40(8): 2308003-0. doi: 10.3866/PKU.WHXB202308003
20. [20]
  Jing Zhang , Su Zhang , Qiqi Li , Linken Ji , Yutong Li , Yukang Ren , Xiaobei Zang , Ning Cao , Han Hu , Peng Liang , Zhuangjun Fan . Integrating high surface area and electric conductivity in activated carbon by in situ formation of the less-defective carbon network during selective chemical etching. Acta Physico-Chimica Sinica, 2025, 41(10): 100114-0. doi: 10.1016/j.actphy.2025.100114

Get Citation

PDF

XML

Metrics

PDF Downloads(1194)
Abstract views(2944)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142