Citation:
XIA Da-Hai, SONG Shi-Zhe, WANG Ji-Hui, BI Hui-Chao, HAN Zhe-Wen. Corrosion Behavior of Tinplates in a Functional Beverage[J]. Acta Physico-Chimica Sinica,
;2012, 28(01): 121-126.
doi:
10.3866/PKU.WHXB201228121
-
In this paper, the corrosion process of a tinplate in a functional beverage was investigated using electrochemical impedance spectroscope (EIS), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), scanning probe microscopy (SPM), and X-ray photoelectron spectroscopy (XPS), and a corrosion mechanism is proposed. We conclude that an increase in the impedance modulus at low frequency is due to the corrosion product forming on the surface of the tinplate over the first 31 h. With an increase in the immersion time a decrease in the impedance modulus at low frequency is due to the detachment of the corrosion product and the corrosion of the carbon steel substrate. X-ray photoelectron spectroscopy (XPS) results show that the corrosion product is mainly composed of a Sn(II)/Sn(IV) citrate complex or an Fe(III) citrate complex. Furthermore, the corrosion product film is first enriched with Sn and then enriched with Fe after immersion in functional beverage for 24 d. We propose that the tinplate is mainly corroded by the organic acids that exist in functional beverages.
-
-
-
[1]
(1) Huang, X. Q.; Li, N.; Cao, L. X.; Zheng, H. Mater. Lett. 2008,62, 466.
-
[2]
(2) Xia, D.;Wang, J.; Song, S.; Zhong, B.; Han, Z. Advanced Materials Research 2011, 233 -235, 1747.
-
[3]
(3) Toniolo, R.; Pizzariello, A.; Tubaro, F.; Susmel, S.; Dossi, N.;Bontempelli, G. J. Appl. Electrochem. 2009, 39, 979.
-
[4]
(4) Patrick, G.W. Anti-Corros. Method. M. 1976, 23 (6), 9.
-
[5]
(5) Blunden, S.;Wallace, T. Food Chem. Toxicol. 2003, 41, 1651.
-
[6]
(6) Boogaard, P. J.; Boisset, M.; Blunden, S.; Davies, S.; Ong, T. J.;Taverne, J. P. Food Chem. Toxicol. 2003, 41, 1663.
-
[7]
(7) Huang, B. X.; Tornatore, P.; Li, Y. S. Electrochim. Acta 2000,46, 671.
-
[8]
(8) Sasaki, T.; Kanagawa, R.; Ohtsuka, T.; Miura, K. Corrosion Sci.2003, 45, 847.
- [9]
-
[10]
(10) Refaey, S. A. M.; Schwitzgebel, G. Appl. Surf. Sci. 1998, 135
-
[11]
(1-4), 243.
-
[12]
(11) Jafarian, M.; bal, F.; Danaee, I.; Biabani, R.; Mahjani, M. G.Electrochim. Acta 2008, 53, 4528.
-
[13]
(12) El-Sherbini, E. E. F.; Abd-El-Wahab, S. M.; Amin, M. A.;Deyab, M. A. Corrosion Sci. 2006, 48, 1885.
-
[14]
(13) Almeida, C. M. V. B.; Giannetti, B. F. Mater. Chem. Phys. 2001,69 (1-3), 261.
-
[15]
(14) Gervasi, C. A.; Palacios, P. A.; Bimbi, M. V. F.; Alvarez, P. E.J. Electroanal. Chem. 2010, 639 (1-2), 141.
-
[16]
(15) Zumelzua, E.; Cabezasb, C. Mater. Charact. 1995, 34, 143.
-
[17]
(16) Kontominas, M. G.; Prodromidis, M. I.; Paleolo s, E. K.;Badeka, A. V.; Georgantelis, D. Food Chem. 2006, 98, 225.
-
[18]
(17) Haanappel, V. A. C.; Stroosnijder, M. F. Corrosion 2001, 57,557.
-
[19]
(18) Doherty, M.; Sykes, J. M. Corrosion Sci. 2008, 50, 2755.
-
[20]
(19) Liu, X.; Xiong, J.; Lv, Y.; Zuo, Y. Prog. Org. Coat. 2009, 64,497.
-
[21]
(20) Zhang,W.;Wang, J.; Zhao, Z. Y.; Jiang, J. Chem. J. Chin. Univ.2009, 30, 762. [张伟, 王佳, 赵增元, 姜晶. 高等学校化学学报, 2009, 30, 762.]
-
[22]
(21) Rezaei, F.; Sharif, F.; Sarabi, A. A.; Kasiriha, S. M.; Rahmanian,M.; Akbarinezhad, E. J. Coat. Technol. Res. 2010, 7, 209.
-
[23]
(22) Zhu, Y. F.; Xiong, J. P.; Tang, Y. M.; Zuo, Y. Prog. Org. Coat.2010, 69, 7.
-
[24]
(23) Betova, I.; Bojinov, M.; Karastoyanov, V.; Kinnunen, P.; Saario,T. Electrochim. Acta 2010, 55, 6163.
-
[25]
(24) Huang, X. Q.; Li, N.;Wang, H. Y.; Sun, H. X.; Sun, S. S.;Zheng, H. Thin Solid Films 2008, 516, 1037.
-
[26]
(25) Graat, P. C. J.; Somers, M. A. J. Appl. Surf. Sci. 1996, 100-101,36.
-
[27]
(26) Abd El Rehim, S. S.; Hassan, H. H.; Mohamed, N. F. Corrosion Sci. 2004, 46, 1071.
-
[1]
-
-
-
[1]
Chongjing Liu , Yujian Xia , Pengjun Zhang , Shiqiang Wei , Dengfeng Cao , Beibei Sheng , Yongheng Chu , Shuangming Chen , Li Song , Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036
-
[2]
Lingbang Qiu , Jiangmin Jiang , Libo Wang , Lang Bai , Fei Zhou , Gaoyu Zhou , Quanchao Zhuang , Yanhua Cui . In Situ Electrochemical Impedance Spectroscopy Monitoring of the High-Temperature Double-Discharge Mechanism of Nb12WO33 Cathode Material for Long-Life Thermal Batteries. Acta Physico-Chimica Sinica, 2025, 41(5): 100040-0. doi: 10.1016/j.actphy.2024.100040
-
[3]
Yue-Zhou Zhu , Kun Wang , Shi-Sheng Zheng , Hong-Jia Wang , Jin-Chao Dong , Jian-Feng Li . Application and Development of Electrochemical Spectroscopy Methods. Acta Physico-Chimica Sinica, 2024, 40(3): 2304040-0. doi: 10.3866/PKU.WHXB202304040
-
[4]
Minghui Wu , Markus Mühlinghaus , Xuechao Li , Chaojie Xu , Qiang Chen , Haiming Zhang , Klaus Müllen , Lifeng Chi . On-Surface Synthesis of Chevron-Shaped Conjugated Ladder Polymers Consisting of Benzo[a]azulene Units. Acta Physico-Chimica Sinica, 2024, 40(8): 2307024-0. doi: 10.3866/PKU.WHXB202307024
-
[5]
Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
-
[6]
Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
-
[7]
Li Jiang , Changzheng Chen , Yang Su , Hao Song , Yanmao Dong , Yan Yuan , Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002
-
[8]
Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
-
[9]
Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
-
[10]
Jingwen Wang , Minghao Wu , Xing Zuo , Yaofeng Yuan , Yahao Wang , Xiaoshun Zhou , Jianfeng Yan . Advances in the Application of Electrochemical Regulation in Investigating the Electron Transport Properties of Single-Molecule Junctions. University Chemistry, 2025, 40(3): 291-301. doi: 10.12461/PKU.DXHX202406023
-
[11]
Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
-
[12]
Zhaoyu Wen , Na Han , Yanguang Li . Recent Progress towards the Production of H2O2 by Electrochemical Two-Electron Oxygen Reduction Reaction. Acta Physico-Chimica Sinica, 2024, 40(2): 2304001-0. doi: 10.3866/PKU.WHXB202304001
-
[13]
Dong Xiang , Kunzhen Li , Kanghua Miao , Ran Long , Yujie Xiong , Xiongwu Kang . Amine-Functionalized Copper Catalysts: Hydrogen Bonding Mediated Electrochemical CO2 Reduction to C2 Products and Superior Rechargeable Zn-CO2 Battery Performance. Acta Physico-Chimica Sinica, 2024, 40(8): 2308027-0. doi: 10.3866/PKU.WHXB202308027
-
[14]
Pengcheng Yan , Peng Wang , Jing Huang , Zhao Mo , Li Xu , Yun Chen , Yu Zhang , Zhichong Qi , Hui Xu , Henan Li . Engineering Multiple Optimization Strategy on Bismuth Oxyhalide Photoactive Materials for Efficient Photoelectrochemical Applications. Acta Physico-Chimica Sinica, 2025, 41(2): 100014-. doi: 10.3866/PKU.WHXB202309047
-
[15]
Ying Zhang , Fang Ge , Zhimin Luo . AI-Driven Biochemical Teaching Research: Predicting the Functional Effects of Gene Mutations. University Chemistry, 2025, 40(3): 277-284. doi: 10.12461/PKU.DXHX202412104
-
[16]
Hong Yan , Wenfeng Wang , Keyin Ye , Yaofeng Yuan . Organic Electrochemistry and Its Integration into Chemistry Teaching. University Chemistry, 2025, 40(5): 301-310. doi: 10.12461/PKU.DXHX202407027
-
[17]
Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
-
[18]
Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
-
[19]
Shuhui Li , Xucen Wang , Yingming Pan . Exploring the Role of Electrochemical Technologies in Everyday Life. University Chemistry, 2025, 40(3): 302-307. doi: 10.12461/PKU.DXHX202406059
-
[20]
Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
-
[1]
Metrics
- PDF Downloads(792)
- Abstract views(2575)
- HTML views(17)