Citation: GAO Li-Xia, WANG Li-Na, QI Tao, YU Jiang. Preparation of Ni and Ni-Al Alloys from 2AlCl₃/Et₃NHCl Ionic Liquid by Electrodeposition[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 111-120. doi: 10.3866/PKU.WHXB201228111 shu

Preparation of Ni and Ni-Al Alloys from 2AlCl₃/Et₃NHCl Ionic Liquid by Electrodeposition

GAO Li-Xia ^1,2 ,
WANG Li-Na ¹ ,
QI Tao ^1, ,
YU Jiang ^2,

1.
1. National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2. College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, P. R. China

Received Date: 12 August 2011
Available Online: 8 November 2011
Fund Project: 国家重点基础研究发展规划项目(973) (2007CB613501) (973) (2007CB613501) 中国科学院知识创新项目(082814) (082814) 国家自然科学基金(21076019) (21076019) 中央高校基本科研业务费专项资金(ZY1130) (ZY1130)中国博士后科学基金项目(2011M500224)资助 (2011M500224)

Nickel and nickel-aluminum alloy were successfully electrodeposited on Cu electrodes from 2: 1 molar ratio aluminum chloride (AlCl₃)/triethylamine hydrochloride (Et₃NHCl) ionic liquids containing Ni²⁺ by constant potential electrolysis. The nucleation mechanism of nickel electrodeposition on Cu was investigated by cyclic voltammograms and chronoamperometry. The mechanism and the influence of experimental conditions on the current efficiency and the surface morphology of nickel-aluminum alloy electrodeposition on Cu electrodes were studied. The electrodeposition of nickel on Cu electrodes was controlled by three-dimensional instantaneous nucleation with diffusion-controlled growth. The Ni-Al alloy composition did not become independent of the deposition charge until at least 3.0 C had been accumulated. The mechanism of Ni-Al alloy formation appears to involve the underpotential deposition of aluminum on the developing nickel deposit and alloy formation must be kinetically hindered because the aluminum content is always less than that predicted from theoretical considerations. The Ni-Al alloy that was obtained on the Cu electrode was dense, continuous, and well adherent when the deposition current was small and stationary. If these conditions were not met, a nodule surface morphology appeared. The current efficiency of the Ni-Al alloy electrodeposition was greater than 90% and the deposition composition was close to that of the Ni₃Al alloy.
- Ionic liquid,
- Aluminum chloride/Triethylamine hydrochloride,
- Constant potential,
- Electrodeposition,
- Nickel-aluminum alloy
1. [1]
  (1) Wu, Z. J.;Wu, X. F.; Yang, J. Machinist Metal Forming 2009, No. 18, 23. [吴朝军, 吴晓峰, 杨杰. 金属加工(热加工), 2009, No. 18, 23.]
2. [2]
  (2) Yin, C. L.; Yu, Y. G.; Zeng, K. L.; Ren, X. J. The Chinese Journal of Process Engineering 2004, 4, 156. [尹春雷, 于月光, 曾克里, 任先京. 过程工程学报, 2004, 4, 156.]
3. [3]
  (3) Yu, Y. G.; Zeng, K. L.; Song, X. J.; Xu, G. G.; Chen, S. Y.; Xie, J. G. Al-Coated-Ni Composite Powder Coated by Ultramicroor- Nano Al Powder and its Preparation Method. CN. Patent 02100588.5, 2005-07-06. [于月光, 曾克里, 宋希剑, 许根国, 陈舒予, 谢建刚. 超微或纳米铝粉包覆的铝包镍复合粉末及其制备方法: 中国, 02100588.5[P]. 2005-07-06.]
4. [4]
  (4) Moffat, T. P. J. Electrochem. Soc. 1994, 141, L115.
5. [5]
  (5) Uchida, J.; Tsuda, T.; Yamamoto, Y.; Seto, H.; Abe, M.; Shibuya, A. ISIJ Int. 1993, 33, 1029.
6. [6]
  (6) Moffat, T. P. J. Electrochem. Soc. 1994, 141, 3059.
7. [7]
  (7) Stafford, G. R.; Haarberg, G. M. Plasmas & Ions 1999, 2, 35.
8. [8]
  (8) Stafford, G. R. J. Electrochem. Soc. 1994, 141, 945.
9. [9]
  (9) Ueda, M.; Kigawa, H.; Ohtsuka, T. Electrochim. Acta 2007, 52, 2515.
10. [10]
  (10) Zhu, Q.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 2001, 148, C88.
11. [11]
  (11) Carlin, R. T.; Trulove, P. C.; DeLong, H. C. J. Electrochem. Soc. 1996, 143, 2747.
12. [12]
  (12) Zell, C. A.; Freyland,W. Langmuir 2003, 19, 7445.
13. [13]
  (13) Mitchell, J. A.; Pitner,W. R.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 1996, 143, 3448.
14. [14]
  (14) Ali, M. R.; Nishikata, A.; Tsuru, T. Electrochim. Acta 1997, 42, 1819.
15. [15]
  (15) Ali, M. R.; Nishikata, A.; Tsuru, T. Electrochim. Acta 1997, 42, 2347.
16. [16]
  (16) Tierney, B. J.; Pitner,W. R.; Mitchell, J. A.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 1998, 145, 3110.
17. [17]
  (17) Zhu, Q.; Hussey, C. L. J. Electrochem. Soc. 2001, 148, C395.
18. [18]
  (18) Tsuda, T.; Nohira, T.; Ito, Y. Electrochim. Acta 2002, 47, 2817.
19. [19]
  (19) Tsuda, T.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 2004, 151, C379.
20. [20]
  (20) De Long, H. C.; Mitchell, J. A.; Trulove, P. C. High Temp. Mater. Processes (New York) 1998, 2, 507.
21. [21]
  (21) Aravinda, C. L.; Mukhopadhyay, I.; Freyland,W. Phys. Chem. Chem. Phys. 2004, 6, 5225.
22. [22]
  (22) Pradhan, D.; Reddy, R.; Lahiri, A. Metall. Mater. Trans. B 2009, 40, 114.
23. [23]
  (23) Tsuda, T.; Hussey, C. L.; Stafford, G. R.; Kongstein, O. J. Electrochem. Soc. 2004, 151, C447.
24. [24]
  (24) Tsuda, T.; Arimoto, S.; Kuwabata, S.; Hussey, C. L. J. Electrochem. Soc. 2008, 155, D256.
25. [25]
  (25) Tsuda, T.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 2005, 152, C620.
26. [26]
  (26) Gao, L. X.;Wang, L. N.; Qi, T.; Li, Y. P.; Chu, J. L.; Qu, J. K. Acta Physico-Chimica Sinica 2008, 24, 939. [高丽霞, 王丽娜, 齐涛, 李玉平, 初景龙, 曲景奎. 物理化学学报, 2008, 24, 939.]
27. [27]
  (27) Gale, R. J.; Gilbert, B.; Osteryoung, R. A. Inorg. Chem. 1979, 18, 2723.
28. [28]
  (28) Lee, J. J.; Miller, B.; Shi, X.; Kalish, R.; Wheeler, K. A. J. Electrochem. Soc. 2000, 147, 3370.
29. [29]
  (29) Ali, M. R.; Nishikata, A.; Tsuru, T. J. Electroanal. Chem. 2001, 513, 111.
30. [30]
  (30) u, S. P.; Sun, I.W. Electrochim. Acta 2008, 53, 2538.
31. [31]
  (31) Pitner,W. R.; Hussey, C. L.; Stafford, G. R. J. Electrochem. Soc. 1996, 143, 130.
32. [32]
  (32) Deng, M. J.; Sun, I.W.; Chen, P. Y.; Chang, J. K.; Tsai,W. T. Electrochim. Acta 2008, 53, 5812.
33. [33]
  (33) Mann, O.; Freyland,W. J. Phys. Chem. C 2007, 111, 9832.
34. [34]
  (34) Kaufman, L. CALPHAD; Pergamon Press: New York, 1977; Vol. 1, pp 1-89.
35. [35]
  (35) Lupis, C. H. P. Chemical Thermodynamics of Materials, North- Holland: New York, 1983; p 581.
36. [36]
  (36) Shi, L. Alloy Thermodynamics, 1st ed.; China Machine Press: Beijing, 1992; pp 285-348. [石霖. 合金热力学, 第一版; 北京: 机械工业出版社, 1992: 285-348.]
37. [37]
  (37) Ye, D. L. Handbook of Thermodynamic Data for Applied Inorganic Material, 2nd ed.; Metallurgical Industry Press: Beijing, 2002; pp 43-46, 270-272. [叶大伦. 实用无机物热力学数据手册, 第二版; 北京: 冶金工业出版社, 2002: 43-46, 270-272.]
1. [1]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
2. [2]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
3. [3]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
4. [4]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
5. [5]
  Baohua LÜ , Yuzhen LI . Anisotropic photoresponse of two-dimensional layered α-In₂Se₃(2H) ferroelectric materials. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1911-1918. doi: 10.11862/CJIC.20240105
6. [6]
  Ming ZHENG , Yixiao ZHANG , Jian YANG , Pengfei GUAN , Xiudong LI . Energy storage and photoluminescence properties of Sm³⁺-doped Ba_0.85Ca_0.15Ti_0.90Zr_0.10O₃ lead-free multifunctional ferroelectric ceramics. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 686-692. doi: 10.11862/CJIC.20230388
7. [7]
  Yingran Liang , Fei Wang , Jiabao Sun , Hongtao Zheng , Zhenli Zhu . Construction and Application of a New Experimental Device for Determination of Alkaline Metal Elements by Plasma Atomic Emission Spectrometry Based on Solution Cathode Glow Discharge: An Alternative Approach for Fundamental Teaching Experiments in Emission Spectroscopy. University Chemistry, 2024, 39(5): 380-387. doi: 10.3866/PKU.DXHX202312024
8. [8]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
9. [9]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
10. [10]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
11. [11]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
12. [12]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
13. [13]
  Mei Yan , Rida Feng , Yerdos·Tohtarkhan , Biao Long , Li Zhou , Chongshen Guo . Expansion and Extension of Liquid Saturated Vapor Measurement Experiment. University Chemistry, 2024, 39(3): 294-301. doi: 10.3866/PKU.DXHX202308103
14. [14]
  Hao GUO , Tong WEI , Qingqing SHEN , Anqi HONG , Zeting DENG , Zheng FANG , Jichao SHI , Renhong LI . Electrocatalytic decoupling of urea solution for hydrogen production by nickel foam-supported Co₉S₈/Ni₃S₂ heterojunction. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2141-2154. doi: 10.11862/CJIC.20240085
15. [15]
  Lei Shi . Nucleophilicity and Electrophilicity of Radicals. University Chemistry, 2024, 39(11): 131-135. doi: 10.3866/PKU.DXHX202402018
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  Shicheng Yan . Experimental Teaching Design for the Integration of Scientific Research and Teaching: A Case Study on Organic Electrooxidation. University Chemistry, 2024, 39(11): 350-358. doi: 10.12461/PKU.DXHX202408036
18. [18]
  Xuan Zhou , Yi Fan , Zhuoqi Jiang , Zhipeng Li , Guowen Yuan , Laiying Zhang , Xu Hou . Liquid Gating Mechanism and Basic Properties Characterization: a New Experimental Design for Interface and Surface Properties in the Chemistry “101 Plan”. University Chemistry, 2024, 39(10): 113-120. doi: 10.12461/PKU.DXHX202407111
19. [19]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
20. [20]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

Get Citation

PDF

XML

Metrics

PDF Downloads(953)
Abstract views(2359)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Preparation of Ni and Ni-Al Alloys from 2AlCl3/Et3NHCl Ionic Liquid by Electrodeposition

Metrics

通讯作者: 陈斌, bchen63@163.com

Preparation of Ni and Ni-Al Alloys from 2AlCl₃/Et₃NHCl Ionic Liquid by Electrodeposition