Citation: XU Ke, SHEN Lai-Fa, MI Chang-Huan, ZHANG Xiao-Gang. Synthesis and Electrochemical Performance of Graphene Modified LiFePO₄ Cathode Materials[J]. Acta Physico-Chimica Sinica, ;2012, 28(01): 105-110. doi: 10.3866/PKU.WHXB201228105 shu

Synthesis and Electrochemical Performance of Graphene Modified LiFePO₄ Cathode Materials

1.
College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, P. R. China

Received Date: 26 July 2011
Available Online: 20 October 2011
Fund Project: 国家重点基础研究发展计划项目(973) (2007CB209703) (973) (2007CB209703) 国家自然科学基金(20873064, 21173120, 21103090) (20873064, 21173120, 21103090) 江苏省普通高校科研创新计划(CXZZ11_0204) (CXZZ11_0204)南京航空航天大学博士学位论文创新与创优基金资助(BCXJ11-10) (BCXJ11-10)

Graphene-modified mesoporous LiFePO₄ microsphere composites were synthesized by a hydrothermal method and subsequent annealing. X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy, and galvanostatic charge-discharge techniques were used to characterize the morphology, structure and electrochemical performance of the resulting composites. The graphene-modified LiFePO₄ microspheres exhibited a high discharge capacity of 141 mAh·g^-1 at 1C, and 105 mAh·g^-1 at 50C, while LiFePO₄/C only delivered 137 mAh·g^-1 at 1C, 64 mAh·g^-1 at 50C in an aqueous electrolyte of 2 mol·L^-1 LiNO₃. The graphene-modified LiFePO₄ exhibited excellent cyclability compared with LiFePO₄/C, with a capacity retention of about 83.7% after 60 cycles versus about 70.2% for LiFePO₄/C. The improved electrochemical performance is attributed to the formation of a three-dimensional (3D) graphene network.
- Lithium iron phosphate,
- Graphene,
- Hydrothermal,
- Li-ion battery
1. [1]
  (1) Padhi, A. K.; Nanjundaswamy, K. S.; Masquelier, C.; Okada, S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1188.
2. [2]
  (2) Padhi, A. K.; Nanjundaswamy, K. S.; Masquelier, C.; Okada, S.; odenough, J. B. J. Electrochem. Soc. 1997, 144, 1609.
3. [3]
  (3) Ravet, N.; odenough, J. B.; Besner, S.; Simoneau, M.; Hovington, P.; Armand, M. Proceedings of the 196th ECS Meeting, Honolulu, HI, Oct 1999; pp 17-22.
4. [4]
  (4) Belharouak, I.; Johnson, C.; Amine, K. Electrochem. Commun. 2005, 7, 983.
5. [5]
  (5) Takeuchi, T.; Tabuchi, M.; Nakashima, A.; Nakamura, T.; Miwa, Y.; Kageyama, H.; Tatsumi, K. J. Power Sources 2005, 146, 575.
6. [6]
  (6) Chen, Z. Y.; Zhu, H. L.; Ji, S.; Fakir, R.; Linkov, V. Solid State Ionics 2008, 179, 1810.
7. [7]
  (7) Chen, Z. H.; Dahn, J. R. J. Electrochem. Soc. 2002, 149, A1184.
8. [8]
  (8) Zhang, D.; Cai, R.; Zhou, Y. K.; Shao, Z. P.; Liao, X. Z.; Ma, Z. F. Electrochim. Acta 2010, 55, 2653.
9. [9]
  (9) Chung, S. Y.; Bloking, J. T.; Chiang, Y. M. Nat. Mater. 2002, 1, 123.
10. [10]
  (10) Wang, Y.;Wang, Y.; Hosono, E.;Wang, K.; Zhou, H. Angew. Chem. Int. Edit. 2008, 47, 7461.
11. [11]
  (11) Qian, J. F.; Zhou, M.; Cao, Y. L.; Ai, X. P.; Yang, H. X. J. Phys. Chem. C 2010, 114, 3477.
12. [12]
  (12) Liu, J. L.; Jiang, R. R.;Wang, X.; Huang, T.; Yu, A. S. J. Power Sources 2009, 194, 536.
13. [13]
  (13) Kostecki, R.; Schnyder, B.; Alliata, D.; Song, X.; Kinoshita, K.; Kotz, R. Thin Solid Films 2001, 396, 36.
14. [14]
  (14) He, P.; Zhang, X.;Wang, Y. G.; Cheng, L.; Xia, Y. Y. J. Electrochem Soc. 2008, 155, A144.
15. [15]
  (15) Luo, J. Y.; Cui,W. J.; He, P.; Xia, Y. Y. J. Nat. Chem. 2010, 2, 760.
16. [16]
  (16) He, P.; Liu, J. L.; Cui,W. J.; Luo, J. Y.; Xia, Y. Y. Electrochim. Acta. 2011, 56, 2351.
17. [17]
  (17) Chen, S. Y.; Gao, B.; Su, L. H.; Mi, C. H.; Zhang, X. G. J. Solid State Electrochem. 2009, 13, 1361.
18. [18]
  (18) Su, F. Y.; You, C. H.; He, Y. B.; Lv,W.; Cui,W.; Jin, F. M.; Li, B. H.; Yang, Q. H.; Kang, F. Y. J. Mater. Chem. 2010, 20, 9644.
19. [19]
  (19) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339.
20. [20]
  (20) Wang, D. Y.; Li, H.; Shi, S. Q.; Huang, X. J.; Chen, L. Q. Electrochim. Acta 2005, 50, 2955.
21. [21]
  (21) Shi, Z. C.; Ye,W. L.;Wang, Q.; Li, Y. X.; Yang, Y. Electrochim. Acta 2008, 53, 2665.
22. [22]
  (22) Szabo, T.; Berkesi, O.; Dekany, I. Carbon 2005, 43, 3186.
23. [23]
  (23) Burba, C. M.; Frech, R. J. Electrochem Soc. 2004, 151, A1032.
24. [24]
  (24) Julien, C.M.; Zaghib, K.; Mauger, A.; Massot, M.; Salah, A. A.; Selmane, M.; Gendron, F. J. Appl. Phys. 2006, 100, 063511.
25. [25]
  (25) Dresselhaus, M.S.; Dresselhaus, G. Light Scattering in Solids, 3rd ed.; Springer: Berlin, 1982; p 3.
26. [26]
  (26) Morishita, T.; Soneda, Y.; Hatori, H.; Inagaki, M. Electrochim. Acta 2007, 52, 2478.
27. [27]
  (27) Appapillai, A. T.; Mansour, A. N.; Cho, J.; Yang, S. H. Chem. Mater. 2007, 19, 5748.
28. [28]
  (28) Mai, L. Q.; Yang, F.; Zhao, Y. L.; Xu, X.; Xu, L.; Luo, Y. Z. Nat. Commun. 2011, 2, 381.
29. [29]
  (29) Shen, L. F.; Yuan, C. Z.; Luo, H. J.; Zhang, X. G.; Yang, S. D.; Lu, X. Nanoscale 2011, 3, 572.
1. [1]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
2. [2]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
3. [3]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
4. [4]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
5. [5]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
6. [6]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
7. [7]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
10. [10]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
11. [11]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
12. [12]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
13. [13]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
14. [14]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
15. [15]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
16. [16]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
17. [17]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
18. [18]
  Limei CHEN , Mengfei ZHAO , Lin CHEN , Ding LI , Wei LI , Weiye HAN , Hongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312
19. [19]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
20. [20]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023

Get Citation

PDF

XML

Metrics

PDF Downloads(1890)
Abstract views(3652)
HTML views(11)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Electrochemical Performance of Graphene Modified LiFePO4 Cathode Materials

Metrics

通讯作者: 陈斌, bchen63@163.com

Synthesis and Electrochemical Performance of Graphene Modified LiFePO₄ Cathode Materials