Citation: LIU Dan-Dan, XU Zhi-Cheng, ZHAO Qun, ZHANG Lei, ZHANG Lu, ZHAO Sui. Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 569-575. doi: 10.3866/PKU.WHXB201212284 shu

Adsorption Behavior of Cationic and Zwitterionic Surfactants on Poly(methyl methacrylate)

LIU Dan-Dan ^1,2 ,
XU Zhi-Cheng ¹ ,
ZHAO Qun ³ ,
ZHANG Lei ¹ ,
ZHANG Lu ¹ ,
ZHAO Sui ¹

1.
1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China;
2 Graduate University of Chinese Academy of Sciences, Beijing 100049, P. R. China;
3 Petrochina Liaohe Oilfield Company Xinglongtai Oil Production Plant, Panjin 124000, Liaoning Province, P. R. China

Received Date: 1 November 2012
Available Online: 28 December 2012
Fund Project: 国家科技重大专项(2011ZX05011-004)资助项目 (2011ZX05011-004)

The wetting behavior of poly(methyl methacrylate) (PMMA) surfaces by aqueous solutions of cationic surfactants, hexadecanol glycidyl ether ammonium chloride (C₁₆PC), hexadecanol polyoxyethylene (3) glycidyl ether ammonium chloride (C₁₆(EO)₃PC), and zwitterionic surfactants, hexadecanol glycidyl ether glycine betaine (C₁₆PB) and hexadecanol polyoxyethylene(3) glycidyl ether glycine betaine (C₁₆(EO)₃PB), were investigated by sessile drop analysis. The influence of surfactant type and concentration on contact angle was determined. The PMMA surface is modified hydrophobically only slightly at low bulk concentration because the surfactant molecules are parallel to the substrate surface and the hydrophilic groups are close to the surface. However, at high concentration, the surfactant molecules can adsorb onto the PMMA surface through Lifshitz-van der Waals interactions and hydrophilic groups directed towards the bulk phase of solution, which increases the hydrophilic character of the PMMA surface. The contact angles of cationic surfactants show little variation following the insertion of polyoxyethylene units. However, the presence of polyoxyethylene units in the zwitterionic surfactants leads to an obvious decrease of contact angle because of the formation of hemimicelles on the PMMA surface.
- Cationic surfactant,
- Zwitterionic surfactant,
- Contact angle,
- Adsorption,
- Poly(methyl methacrylate) surface
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