Citation: PAN Hui, ZHAO Tian, ZHANG Yu-Dong, ZHANG Zhi-Jun. Preparation, Characterization and Properties of Titania/Graphite Oxide Nanocomposite[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 660-666. doi: 10.3866/PKU.WHXB201212282 shu

Preparation, Characterization and Properties of Titania/Graphite Oxide Nanocomposite

1.
1 Key Laboratory of Ministry of Education for Special Functional Materials, Henan University, Kaifeng 475004, Henan Province, P.R.China;
2 The college of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan Province, P.R.China

Received Date: 9 October 2012
Available Online: 28 December 2012
Fund Project: 河南省重点实验室项目(122300413205) (122300413205)河南大学博士后科学研究基金(BH2011054)资助 (BH2011054)

Titania/graphite oxide (TiO₂/ ) nanocomposites were obtained from a facile in-situ method using titanium tetrachloride (TiCl₄) and . Nanocomposite structures and properties were characterized by Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric-differential thermal analysis (TG-DTA), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and UV-Vis absorption spectroscopy. TiO₂/ nanocomposites could be well dispersed in water, and the addition of waterborne polyurethane (WPU) yielded TiO₂/ -WPU coatings. During oxidation, the graphite structural layer bound with numerous functional groups, some of which were chemically bound TiO₂. The peak disappeared after combining with TiO₂ nanoparticles. UV absorption data indicated an increasing percentage of WPU with increasing content. There was an optimal additive concentration at which the best absorbance results were achieved. The thermal stability and UV and wear resistance of the WPU were greatly improved upon the addition of TiO₂/ .
- Titania,
- Graphite oxide,
- Nanocomposite,
- Preparation,
- Characterization
1. [1]
  
  (1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang,Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A. Science2004, 306, 666. doi: 10.1126/science.1102896
2. [2]
  (2) Geim, A. K.; Novoselov, K. S. Nature Materials 2007, 6, 183.doi: 10.1038/nmat1849
3. [3]
  (3) Gao, B.; Peng, C.; Chen, G. Z.; Li Puma, G. Applied CatalysisB: Environmental 2008, 85, 17. doi: 10.1016/j.apcatb.2008.06.027
4. [4]
  (4) Zhang, Y.;Wu, Y.; Chen, M.;Wu, L. Colloids and Surfaces A:Physicochemical and Engineering Aspects 2010, 353, 216. doi: 10.1016/j.colsurfa.2009.11.016
5. [5]
  (5) Chen, J.; Zhou, Y.; Nan, Q.; Sun, Y.; Ye, X.;Wang, Z. AppliedSurface Science 2007, 253, 9154. doi: 10.1016/j.apsusc.2007.05.046
6. [6]
  (6) Hsu, S.; Chou, C.W.; Tseng, S. M. Macromolecular Materialsand Engineering 2004, 289, 1096.
7. [7]
  (7) Shah, M. S. A. S.; Nag, M.; Kalagara, T.; Singh, S.; Manorama,S. V. Chemistry of Materials 2008, 20, 2455. doi: 10.1021/cm7033867
8. [8]
  (8) Marcano, D. C.; Kosynkin, D. V.; Berlin, J. M.; Sinitskii, A.;Sun, Z.; Slesarev, A.; Alemany, L. B.; Lu,W.; Tour, J. M. ACSNano 2010, 4, 4806. doi: 10.1021/nn1006368
9. [9]
  (9) Fan,W.; Lai, Q.; Zhang, Q.;Wang, Y. The Journal of PhysicalChemistry C 2011, 115, 10694. doi: 10.1021/jp2008804
10. [10]
  (10) Huang, Q.; Sun, H. J.; Yang, Y. H. Chin. J. Inorg. Chem. 2011,27, 1721. [黄桥, 孙红娟, 杨勇辉. 无机化学学报, 2011, 27,1721.]
11. [11]
  (11) Yang, Y. H.; Sun, H. J.; Peng, T. J.; Huang, Q. Acta Phys. -Chim.Sin. 2011, 27, 736. [杨勇辉, 孙红娟, 彭同江, 黄桥. 物理化学学报, 2011, 27, 736.] doi: 10.3866/PKU.WHXB20110320
12. [12]
  (12) Hu, B.; Pan, H.; Yu, L. G.;Wang, L. G.; Zhao, L.; Zhang, Z. J.Journal of Inorganic Materials 2011, 26, 1181. [胡宾,潘卉, 余来贵, 王龙阁, 赵磊, 张治军. 无机材料学报,2011, 26, 1181.] doi: 10.3724/SP.J.1077.2011.01181
13. [13]
  (13) Zhang, H.; Lv, X.; Li, Y.;Wang, Y.; Li, J. ACS Nano 2009, 4,380.
14. [14]
  (14) Han, Z. D.;Wang, J. Q. Chin. J. Inorg. Chem. 2003, 19, 1366.[韩志东, 王建祺. 无机化学学报, 2003, 19, 1366.]
15. [15]
  (15) Zhang, Q.; He,W. Q.; Chen, X. G.; Hu, D. H.; Li, L. J.; Ji, L. L.;Yi, T. Chinese Science Bulletin 2010, 5, 620. [张琼, 贺蕴秋, 陈小刚, 胡栋虎, 李林江, 季伶俐, 尹婷. 科学通报, 2010,5, 620.]
16. [16]
  (16) Shen, J.; Yan, B.; Shi, M.; Ma, H.; Li, N.; Ye, M. J. Mater.Chem. 2011, 21, 3415. doi: 10.1039/c0jm03542d
17. [17]
  (17) Li, N.; Liu, G.; Zhen, C.; Li, F.; Zhang, L.; Cheng, H. M.Advanced Functional Materials 2011, 21, 1717. doi: 10.1002/adfm.201002295
18. [18]
  (18) Matsumoto, Y.; Koinuma, M.; Ida, S.; Hayami, S.; Taniguchi, T.;Hatakeyama, K.; Tateishi, H.;Watanabe, Y.; Amano, S.The Journal of Physical Chemistry C 2011, 115, 19280. doi: 10.1021/jp206348s
19. [19]
  (19) Zhang, Y.; Tang, Z. R.; Fu, X.; Xu, Y. J. ACS Nano 2010, 4,7303. doi: 10.1021/nn1024219
20. [20]
  (20) Ramanathan, T.; Abdala, A. A.; Stankovich, S.; Dikin, D. A.;Herrera-Alonso, M.; Piner, R. D.; Adamson, D. H.; Schniepp,H. C.; Chen, X.; Ruoff, R. S. Nature Nanotechnology 2008, 3,327. doi: 10.1038/nnano.2008.96
21. [21]
  (21) Huo, X. D.;Wang, Q.; Liang, J.; Zhang, K.; Mu, M. Tribology2012, 32, 133. [霍晓迪, 王青, 梁军, 张凯, 穆明.摩擦学学报, 2012, 32, 133.]
22. [22]
  (22) Mu, M.; Zhou, X.; Xiao, Q.; Liang, J.; Huo, X. Applied SurfaceScience 2012, 258, 8570. doi: 10.1016/j.apsusc.2012.05.051
23. [23]
  (23) Gudarzi, M. M.; Sharif, F. Soft Matter 2011, 7, 3432. doi: 10.1039/c0sm01311k
24. [24]
  (24) Wang, X.; Hu, Y.; Song, L.; Yang, H.; Xing,W.; Lu, H. J. Mater.Chem. 2011, 21, 4222. doi: 10.1039/c0jm03710a
25. [25]
  (25) Liang, Y. Y.;Wang, H. L.; Casalongue, S. H.; Chen, Z.; Dai, H. J.Nano Res. 2010, 3, 701. doi: 10.1007/s12274-010-0033-5
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