Citation: YANG Gui-Jun, WANG Shen-Rui, ZHANG Yong-Chang, WANG Gang, CHEN Hui-Yuan, NAN Hui, LIN Hong, . Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 539-545. doi: 10.3866/PKU.WHXB201212254 shu

Effect of pH Values on Performance of Trollius Chinensis Pigment Sensitized Solar Cells

YANG Gui-Jun ¹ ,
WANG Shen-Rui ² ,
ZHANG Yong-Chang ³ ,
WANG Gang ¹ ,
CHEN Hui-Yuan ¹ ,
NAN Hui ¹ ,
LIN Hong ³ ,
^1,3,,

1.
1 Collage of Chemical Engineering, Qinghai University, Xining, Qinghai 810016, P. R. China;
2 Collage of Material, Beijing University of Technology, Beijing 100081, P. R. China;
3 State Key Laboratory of New Ceramics & Fine Processing, Department of Material Science and Engineering, Tsinghua University, Beijing 100084,P. R. China

Corresponding author: ,
Received Date: 9 October 2012
Available Online: 25 December 2012
Fund Project: 青海省科技厅三江源项目(2010-N-S03) (2010-N-S03)青海省科技厅国际合作项目(2011-H-802)资助 (2011-H-802)

Trollius chinensis pigment was extracted, and ultraviolet-visible (UV-Vis) absorption and Fourier transform infrared (FTIR) spectroscopy confirmed that anthocyanin compounds were the main components. Dye sensitized solar cells (DSCs) were sensitized from the natural pigments dissolved in different pH solutions. Open-circuit voltage increased with increasing pH,while short-circuit current density first increased and then decreased, attributed to an anthocyanin structural change with pH value. The highest observed power conversion efficiency was 0.292% at pH=5.
- Dye sensitized solar cell,
- Natural pigment,
- pH value,
- Trollius chinensis,
- Photovoltaic perfomance
1. [1]
  
  (1) O'Regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Grätzel, M. Nature 2001, 414, 338. doi: 10.1038/35104607
3. [3]
  (3) Kong, F. T.; Dai, S. Y. Progress in Chemistry 2006, 18, 1409.[孔凡太, 戴松元. 化学进展, 2006, 18, 1409.]
4. [4]
  (4) Kay, A.; Grätzel, M. J. Phys. Chem. 1993, 97, 6272. doi: 10.1021/j100125a029
5. [5]
  (5) Kay, A.; Robin, H. B.; Grätzel, M. J. Phys. Chem. 1994, 98,952. doi: 10.1021/j100054a035
6. [6]
  (6) Wang, X. F.; Zhan, C. H.; Maoka, T.;Wada, Y.; Koyama, Y.Chemical Physics Letters 2007, 447, 79. doi: 10.1016/j.cplett.2007.08.097
7. [7]
  (7) Wang, X. F.; Kitao, O.; Zhou, H. S.; Tamiaki, H.; Sasaki, S. I.J. Phys. Chem. C 2009, 112, 7954.
8. [8]
  (8) Wang, X. F.; Koyama, Y.; Kitao, O.;Wada, Y.; Sasaki, S. I.;Tamiaki, H.; Zhou, H. S. Biosensors and Bioelectronics 2010,25, 1970. doi: 10.1016/j.bios.2010.01.015
9. [9]
  (9) Campbell,W. M.; Jolley, K.W.;Wagner, P.;Wagner, K.;Walsh,P. J.; rdon, K. G.; Mende, L. S.; Nazeeruddin, M. K.;Wang,Q.; Grätzel, M.; Officer, D. L. J. Phys. Chem. C 2007, 111,11760. doi: 10.1021/jp0750598
10. [10]
  (10) Yoshitaka, S.; Hitoshi, T. J. Photochem. Photobiol. B-Biol.2004, 73, 29. doi: 10.1016/j.jphotobiol.2003.10.001
11. [11]
  (11) Patrocinio, A. O. T.; Mizoguchi, S. K.; Paterno, L. G.; Garcia, C.G.; Murakami iha, N. Y. Synthetic Metals 2009, 159, 2342. doi: 10.1016/j.synthmet.2009.08.027
12. [12]
  (12) Tennakone, K.; Kumarasinghe, A. R.; Kumara, G. R. R. A.;Wijayantha, K. G. U.; Sirimanne, P. M. J. Photochem.Photobiol. A-Chem. 1997, 108, 193. doi: 10.1016/S1010-6030(97)00090-7
13. [13]
  (13) Andre, S. P.; Neyde, Y. M. I. Solar Energy Materials and SolarCells 2006, 90, 1936. doi: 10.1016/j.solmat.2006.02.006
14. [14]
  (14) Dai, Q.; Rabani, J. Chem. Commun. 2001, 2142. doi: 10.1039/b106197f
15. [15]
  (15) Furukawa, S.; Iino, H.; Iwamoto, T.; Kukita, T.; Yamauchi, S.Thin Solid Films 2009, 518, 526. doi: 10.1016/j.tsf.2009.07.045
16. [16]
  (16) Giuseppe, C.; Gaetano, D. M. Solar Energy Material and SolarCells 2008, 92, 1341. doi: 10.1016/j.solmat.2008.05.007
17. [17]
  (17) Luo, P. H.; Niu, H. J.; Zheng, G.; Bai, X. D.; Zhang, M. L.;Wang,W. Spectro. Acta Pt. A-Molec. Biomolec. Spectr. 2009,74, 936. doi: 10.1016/j.saa.2009.08.039
18. [18]
  (18) Gao, F. G.; Bard, A. J.; Kispert, L. D. J. Photochem. Photobiol.A-Chem. 2000, 130, 49. doi: 10.1016/S1010-6030(99)00193-8
19. [19]
  (19) Khaled, M.; Andreas, H.; Lowell, D. K. J. Phys. Chem. 1991,95, 2438. doi: 10.1021/j100159a060
20. [20]
  (20) Jeevarajan, J. A.; Kispert, L. D. J. Electroanal. Chem. 1996,411, 57.
21. [21]
  (21) Li, Y. L.; Ma, S. C.; Yang, Y. T.; Ye, S. M.; But, P. P. H.J. Ethnopharmacol. 2002, 79, 365. doi: 10.1016/S0378-8741(01)00410-X
22. [22]
  (22) Li, X.; Lin, H.; Li, J. B.;Wang, N.; Lin, C. F.; Zhang, L. Z.J. Photochem. Photobiol. A-Chem. 2008, 195, 247. doi: 10.1016/j.jphotochem.2007.10.010
23. [23]
  (23) Lu, X. R.; Lu, J. L.;Wu, Y.W.; Ouyuang, J.; Sun, S. Q.Spectroscopy and Spectral Analysis 2010, 30, 38. [卢晓蕊,路金丽, 武彦文, 欧阳杰, 孙素琴. 光谱学与光谱分析, 2010,30, 38.]
24. [24]
  (24) Lu, Y.; Dong, X. Y.; Du, J. P.; Li, Y. Q.;Wang, M. L. ResearchProgress on Anthocyanins 2004, 35, 315. [卢钰, 董现义,杜景平, 李永强, 王明林. 山东农业大学学报, 2004, 35, 315.]
25. [25]
  (25) Wang, F.; Deng, J. H.; Tan, X. H.; Zhang, L. H.; Zhong, H.; Li,Q. M. Food Science 2008, 29, 472. [王峰, 邓洁红, 谭兴和,张礼红, 钟浩, 李清明. 食品科学, 2008, 29, 472.]
26. [26]
  (26) Paulo, F.; Mourad, E.; Norio, S.; Raymond, B. J. Am. Chem.Soc. 1996, 118, 4788. doi: 10.1021/ja9535064
27. [27]
  (27) Sun, J. X.; Zhang, Y.; Hu, X. S.;Wu, J. H.; Liao, X. J. ScientiaAgricultura Sinica 2009, 42, 996. [孙建霞, 张燕, 胡小松,吴继红, 廖小军. 中国农业科学, 2009, 42, 996.]
28. [28]
  (28) Nerine, J. C.; Greg, P. S.; Gratzel, M.; Zhang, J. Z. J. Phys.Chem. B 1997, 101, 9342. doi: 10.1021/jp972197w
29. [29]
  (29) Lin, H.; Liu, Y. Z.; Liu, C. J.; Li, X.; Shen, H. P.; Zhang, J.; Ma,T. L.; Li, J. B. Journal of Electroanalytical Chemistry 2011,653, 81. doi: 10.1016/j.jelechem.2010.12.025
1. [1]
  Yipeng Zhou , Chenxin Ran , Zhongbin Wu . Metacognitive Enhancement in Diversifying Ideological and Political Education within Graduate Course: A Case Study on “Solar Cell Performance Enhancement Technology”. University Chemistry, 2024, 39(6): 151-159. doi: 10.3866/PKU.DXHX202312096
2. [2]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
3. [3]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
4. [4]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
5. [5]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
6. [6]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
7. [7]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
8. [8]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
9. [9]
  Wei HE , Jing XI , Tianpei HE , Na CHEN , Quan YUAN . Application of solar-driven inorganic semiconductor-microbe hybrids in carbon dioxide fixation and biomanufacturing. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 35-44. doi: 10.11862/CJIC.20240364
10. [10]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371
11. [11]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
12. [12]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
13. [13]
  Rui Gao , Ying Zhou , Yifan Hu , Siyuan Chen , Shouhong Xu , Qianfu Luo , Wenqing Zhang . Design, Synthesis and Performance Experiment of Novel Photoswitchable Hybrid Tetraarylethenes. University Chemistry, 2024, 39(5): 125-133. doi: 10.3866/PKU.DXHX202310050
14. [14]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
15. [15]
  Xinzhe HUANG , Lihui XU , Yue YANG , Liming WANG , Zhangyong LIU , Zhongjian WANG . Preparation and visible light responsive photocatalytic properties of BiSbO₄/BiOBr. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 284-292. doi: 10.11862/CJIC.20240212
16. [16]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
17. [17]
  Zihan Lin , Wanzhen Lin , Fa-Jie Chen . Electrochemical Modifications of Native Peptides. University Chemistry, 2025, 40(3): 318-327. doi: 10.12461/PKU.DXHX202406089
18. [18]
  Yujia LI , Tianyu WANG , Fuxue WANG , Chongchen WANG . Direct Z-scheme MIL-100(Fe)/BiOBr heterojunctions: Construction and photo-Fenton degradation for sulfamethoxazole. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 481-495. doi: 10.11862/CJIC.20230314
19. [19]
  Jiaxin Su , Jiaqi Zhang , Shuming Chai , Yankun Wang , Sibo Wang , Yuanxing Fang . Optimizing Poly(heptazine imide) Photoanodes Using Binary Molten Salt Synthesis for Water Oxidation Reaction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408012-. doi: 10.3866/PKU.WHXB202408012
20. [20]
  Di ZHANG , Tianxiang XIE , Xu HE , Wanyu WEI , Qi FAN , Jie QIAO , Gang JIN , Ningbo LI . Construction and antitumor activity of pH/GSH dual-responsive magnetic nanodrug. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 786-796. doi: 10.11862/CJIC.20240329

Get Citation

PDF

XML

Metrics

PDF Downloads(718)
Abstract views(1113)
HTML views(22)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142