Citation: LIU Su-Qin, DAI Gao-Peng, LIANG Ying, LIU Hua-Jun, LIANG Gui-Jie. Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO₂ Hollow Sphere[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 585-589. doi: 10.3866/PKU.WHXB201212253 shu

Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO₂ Hollow Sphere

1.
1 Department of Chemical engineering and Food Science; Hubei University of arts and science, Xiangyang 441053, Hubei Province, P. R. China;
2 Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices, Xiangyang 441053, Hubei Province, P. R. China

Received Date: 2 October 2012
Available Online: 25 December 2012
Fund Project: 湖北省自然科学基金(2012FFB01903) (2012FFB01903)湖北省教育厅项目(T201215, Z20102601, Q20122507)资助 (T201215, Z20102601, Q20122507)

Carbon and nitrogen co-doped TiO₂ hollow spheres (CNTHs) were synthesized by hydrothermal treatment of titanium carbonitride (TiCN) in a mixture of H₂O₂, HF, ethanol, and water. CNTHs were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-visible (UV-Vis) diffuse reflectance spectroscopy. Some of the carbon and nitrogen from TiCN was doped into the lattice of TiO₂ in situ, and some carbon atoms were incorporated into the interstitial positions of the TiO₂ lattice. The CNTHs exhibited enhanced absorption over the whole visible-light region and an obvious red shift at the absorption edges compared with that of TiO₂. The ability of the CNTHs to degrade methylene blue (MB) in aqueous solution under visible light irradiation (λ≥400 nm) was investigated. The CNTHs showed much higher photocatalytic activity than P25 in the degradation of MB because of the synergetic effects of their strong visible absorption and unique hollow sphere structure.
- Carbon and nitrogen co-doping,
- TiO₂ hollow sphere,
- Visible light,
- Photocatalysis
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Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO2 Hollow Sphere

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Fabrication and Visible-Light Photocatalytic Activity of In situ Carbon and Nitrogen Co-Doped TiO₂ Hollow Sphere