Citation: LIU Ying, TONG Wen-Chao, YANG Li, ZHANG Tong-Lai, FENG Chang-Gen. Solution Heat of Potassium Styphnate and Caesium Styphnate in Water and DMF at 298.15 K[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 467-472. doi: 10.3866/PKU.WHXB201212202 shu

Solution Heat of Potassium Styphnate and Caesium Styphnate in Water and DMF at 298.15 K

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State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology, Beijing 100081, P. R. China

Received Date: 16 November 2012
Available Online: 20 December 2012
Fund Project: 应用物理化学实验室科技基金(9140C3703051105, 9140C370303120C37142)与爆炸科学与技术国家重点实验室基金(QNKT12-02, YBKT10-05)资助项目 (9140C3703051105, 9140C370303120C37142)与爆炸科学与技术国家重点实验室基金(QNKT12-02, YBKT10-05)

The dissolution and thermochemical properties of potassium styphnate [K₂(TNR)(H₂O)]_n and cesium styphnate [Cs₂(TNR)(H₂O)₂]_n in water and N,N-dimethylformamide (DMF) at 298.15 K were studied by calorimetry. The processes are endothermic in water, and exothermic in DMF because of the different molecular structure and polarity of the solutes and solvents. Empirical formulas for the solution enthalpies (Δ_solH), relative apparent molar solution enthalpies (ФL_i), relative partial molar enthalpies (L_i), and dilution enthalpies (Δ_dilH_1,2) are deduced by polynomial expressions, and standard solution enthalpies (Δ_solH_m^θ) are also calculated.
- Dissolving process,
- Thermochemistry,
- 2,4,6-Trinitro-resorcinol,
- Solution enthalpy,
- Dilution enthalpy
1. [1]
  
  (1) Liu, Y.; Chen, Y. Accounts Chem. Res. 2006, 39, 681. doi: 10.1021/ar0502275
2. [2]
  (2) Liu, Y.; Zhang, N.; Chen, Y.;Wang, L. H. Org. Lett. 2007, 9,315. doi: 10.1021/ol062816w
3. [3]
  (3) Cai,W. S.; Xia, B. Y.; Shao, X. G.; Maigret, B.; Pan, Z. X.Chem. Phys. Lett. 2000, 319, 708. doi: 10.1016/S0009-2614(00)00177-9
4. [4]
  (4) Jiang, J. Q.; Jiang, T.; Zhang, C. B.; Cheng, H.; Liu, X. Y.;Zhang, S.W.; Chen, M. Q. Acta Phys. -Chim. Sin. 2011, 27,2691. [江金强, 姜韬, 张成邦, 成浩, 刘晓亚, 张胜文, 陈明清. 物理化学学报, 2011, 27, 2691.] doi: 10.3866/PKU.WHXB20111019
5. [5]
  (5) Liu, L. H.; ng, Z. Q.; Zheng, Y. J.; Zhang, Q. F.; Guan, L. X.Acta Phys. -Chim. Sin. 2002, 18, 604. [刘立华, 龚竹青, 郑雅杰, 张钦发, 关鲁雄. 物理化学学报, 2002, 18, 604.] doi: 10.3866/PKU.WHXB20020707
6. [6]
  (6) Qu, X. K.; Sun, D. Z.; Zheng,W. Q.; Liu, M.;Wei, X. L. Acta Phys. -Chim. Sin. 2007, 23, 116. [曲秀葵, 孙德志, 郑文清,刘敏, 魏西莲. 物理化学学报, 2007, 23, 116.] doi: 10.3866/PKU.WHXB20070124
7. [7]
  (7) Xu, P.; Song, L. X. Acta Phys. -Chim. Sin. 2008, 24, 2214.[徐鹏, 宋乐新. 物理化学学报, 2008, 24, 2214.] doi: 10.3866/PKU.WHXB20081212
8. [8]
  (8) Xu, P.; Song, L. X. Acta Phys. -Chim. Sin. 2008, 24, 729.[徐鹏, 宋乐新. 物理化学学报, 2008, 24, 729.] doi: 10.3866/PKU.WHXB20080433
9. [9]
  (9) Chen, Y.; Liu, Y. Chem. Soc. Rev. 2010, 39, 495. doi: 10.1039/b816354p
10. [10]
  (10) Zhang, Y. M.; Yang, Z. X.; Chen, Y.; Ding, F.; Liu, Y. Cryst. Growth Des. 2012, 12, 1370. doi: 10.1021/cg201446x
11. [11]
  (11) Song, L. X.;Wang, M.; Dang, Z.; Du, F. Y. J. Phys. Chem. B2010, 114, 3404. doi: 10.1021/jp100308x
12. [12]
  (12) Hubert, C.; Denicourt-Nowicki, A.; Roucoux, A.; Landy, D.;Leger, B.; Crowyn, G.; Monflier, E. Chem. Commun. 2009,1228.
13. [13]
  (13) Yang, J.; Song, L. X.; Yang, J.; Dang, Z.; Chen, J. Dalton Trans.2012, 41, 2393. doi: 10.1039/c2dt11666a
14. [14]
  (14) Pan, S. Z.; Song, L. X.; Bai, L.;Wang, M.; Zhu, L. H.; Chen, J.Curr. Org. Chem. 2011, 15, 862. doi: 10.2174/138527211794518916
15. [15]
  (15) Dang, Z.; Song, L. X.; Pan, S. Z.;Wang, M. Acta Phys. -Chim. Sin. 2009, 25, 1059. [党政, 宋乐新, 潘淑珍, 王莽. 物理化学学报, 2009, 25, 1059.] doi: 10.3866/PKU.WHXB20090529
16. [16]
  (16) Song, L. X.; Bai, L. J. Phys. Chem. B 2009, 113, 11724. doi: 10.1021/jp902456h
17. [17]
  (17) Mhamdi, T. M.; Ghorbel, A.; Delahay, G. Catal. Today 2009,142, 239. doi: 10.1016/j.cattod.2008.07.026
18. [18]
  (18) Liu, Q.; Dong, X. H.; Xiao, G. L.; Zhao, F.; Chen, F. L. Adv. Mater. 2010, 22, 5478. doi: 10.1002/adma.v22.48
19. [19]
  (19) Bose, A. C.; Shimizu, Y.; Mariotti, D.; Sasaki, T.; Terashima, K.;Koshizaki, N. Nanotechnology 2006, 17, 5976. doi: 10.1088/0957-4484/17/24/012
20. [20]
  (20) Li, X. J.; Zhang,W. P.; Li, X.; Liu, S. L.; Huang, H. J.; Han, X.W.; Xu, L. Y.; Bao, X. H. J. Phys. Chem. C 2009, 113, 8228.doi: 10.1021/jp901103e
21. [21]
  (21) Gao, Y. L.; Fang, X. C.; Cheng, Z. M. Catal. Today 2010, 158,496. doi: 10.1016/j.cattod.2010.07.024
22. [22]
  (22) Lu, Y. K.; Xu, J. N.; Cui, X. B.; Jin, J.; Shi, S. Y.; Xu, J. Q.Inorg. Chem. Commun. 2010, 13, 46. doi: 10.1016/j.inoche.2009.10.003
23. [23]
  (23) Itoh, T.; Matsubara, I.; Shin,W.; Izu, N.; Nishibori, M. J. Ceram. Soc. Jpn. 2010, 118, 171. doi: 10.2109/jcersj2.118.171
24. [24]
  (24) Harada, A.; Kawaguchi, Y.; Nishiyama, T.; Kamachi, M.Macromol. Rapid Commun. 1997, 18, 535. doi: 10.1002/marc.1997.030180701
25. [25]
  (25) Li, J.; Li, X.; Toh, K. C.; Ni, X. P.; Zhou, Z. H.; Leong, K.W.Macromolecules 2001, 34, 8829. doi: 10.1021/ma011129b
26. [26]
  (26) Chen, Y.; Pang, Y.;Wu, J. L.; Su, Y.; Liu, J. Y.;Wang, R. B.;Zhu, B. S.; Yao, Y. F.; Yan, D. Y.; Zhu, X. Y.; Chen, Q.Langmuir 2010, 26, 9011. doi: 10.1021/la9048133
27. [27]
  (27) Okamoto, Y.; Oshima, N.; Kobayashi, Y.; Terasaki, O.;Kodairad, T.; Kubotaa, T. Phys. Chem. Chem. Phys. 2002, 4,2852.
28. [28]
  (28) Song, L. X.;Wang, M.; Pan, S. Z.; Yang, J.; Chen, J.; Yang, J.J. Mater. Chem. 2011, 21, 7982. doi: 10.1039/c1jm10252d
29. [29]
  (29) Xue, S. J.; Xiang, C. S.;Wei, Y. G.; Tao, Z.W.; Chai, A.; Bian,W. D.; Xu, Z. Cryst. Growth Des. 2008, 8, 2437. doi: 10.1021/cg8000174
30. [30]
  (30) Hayden, T. F.; Dumesic, J. A.; Sherwood, R. D.; Baker, R. T. K.J. Catal. 1987, 105, 299. doi: 10.1016/0021-9517(87)90060-1
31. [31]
  (31) Pal, M.; Hirota, K.; Tsujigami, Y.; Sakata, H. J. Phys. D: Appl. Phys. 2001, 34, 459. doi: 10.1088/0022-3727/34/4/303
32. [32]
  (32) Song, L. X.; Chen, J.; Zhu, L. H.; Xia, J.; Yang, J. Inorg. Chem.2011, 50, 7988. doi: 10.1021/ic200137f
33. [33]
  (33) Song, L. X.; Xia, J.; Dang, Z.; Yang, J.; Chen, J.;Wang, L. B.CrystEngComm 2012, 14, 2675. doi: 10.1039/c2ce06567c
34. [34]
  (34) Aritani, H.; Tanaka, T.; Funabiki, T.; Yoshida, S. J. Phys. Chem.1996, 100, 5440. doi: 10.1021/jp9525245
35. [35]
  (35) Xue, X. Y.; Chen, Z. H.; Xing, L. L.; Yuan, S.; Chen, Y. J.Chem. Commun. 2011, 47, 5205. doi: 10.1039/c1cc00076d
36. [36]
  (36) Debecker, D. P.; Schimmoeller, B.; Stoyanova, M.; Poleunis, C.;Bertrand, P.; Rodemerck, U.; Gaigneaux, E. M. J. Catal. 2011,277, 154. doi: 10.1016/j.jcat.2010.11.003
37. [37]
  (37) Dang, Z.; Song, L. X.; Yang, J.; Chen, J.; Teng, Y. Dalton Trans.2012, 41, 3006. doi: 10.1039/c2dt11794k
38. [38]
  (38) Chen, L. M.; Liu, Y. N. CrystEngComm 2011, 13, 6481. doi: 10.1039/c1ce05557g
39. [39]
  (39) Chen, J.; Song, L. X.; Yang, J.; Xia, J.; Shao, Z. C. J. Mater. Chem. 2012, 22, 6251. doi: 10.1039/c2jm00082b
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