Citation: HONG Zhou-Qin, LI Jin-Xia, ZHANG Fang, ZHOU Li-Hui. Synthesis of Magnetically Graphitic Mesoporous Carbon from Hard Templates and Its Application in the Adsorption Treatment of Traditional Chinese Medicine Wastewater[J]. Acta Physico-Chimica Sinica, ;2013, 29(03): 590-596. doi: 10.3866/PKU.WHXB201212123 shu

Synthesis of Magnetically Graphitic Mesoporous Carbon from Hard Templates and Its Application in the Adsorption Treatment of Traditional Chinese Medicine Wastewater

1.
Research Center of Analysis and Test, East China University of Science and Technology, Shanghai 200237, P. R. China

Received Date: 2 October 2012
Available Online: 12 December 2012
Fund Project:

Magnetically graphitic mesoporous carbon (Fe/GMC) was synthesized, using SBA-15 as a template and sucrose as a carbon source, with the assistance of ferric nitrate impregnation. The properties of the products were characterized using powder X-ray diffraction (XRD), transmission electron microscopy (TEM), N₂ adsorption-desorption (BET), and Raman spectroscopy. The impregnation of Fe³⁺ promoted the partial graphitization of ordered mesoporous carbon at low temperature (900℃), and resulted in the production of magnetic Fe₃O₄ particles. These complex materials possessed an ordered mesoporous pore structure, large surface area, and magnetic properties. The adsorption properties of Fe/GMC for traditional Chinese medicine wastewater were studied in detail using UV-Vis spectroscopy. The results showed that the Fe/GMC materials displayed rapid adsorption, and had a high adsorption capacity. Fe/GMC could be used as an absorbent for the highly efficient removal of pigments from Carthamus tinctorius flowers via rapid solid-liquid magnetic separation.
- SBA-15,
- Hard template,
- Mesoporous carbon,
- Graphitization,
- Magnetic Fe₃O₄
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沈阳化工大学材料科学与工程学院沈阳 110142