Citation: QIN Guo-Heng, HUANG Xiao-Wei, HU Zhi. Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 311-318. doi: 10.3866/PKU.WHXB201212062 shu

Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials

1.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, P.R. China

Received Date: 17 September 2012
Available Online: 6 December 2012
Fund Project: 福建省自然科学基金(2008J0146)资助项目 (2008J0146)

Powders of La_0.90Sr_0.10Al_0.97Mg_0.03O_3-δ (LSAM) were synthesized by the glycine-nitrate process, and then sintered at 1500 °C for 5 h. Impedance spectroscopy at 900 °C in air revealed that the conductivity of LSAM was 1.11×10^-2 S·cm^-1. The chemical compatibility of LSAM with anode materials NiO-Ce_0.9Gd_0.1O_1.95 (Ni-GDC), Sr_0.88Y_0.08TiO₃ (SYT) and La_0.75Sr_0.25Cr_0.5Mn_0.5O₃ (LSCM) was characterized by X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray spectroscopy and AC impedance spectroscopy. The results indicated that SYT and LSCM had poor chemical compatibility with LSAM because Sr²⁺, Ti⁴⁺, Mn³⁺, and Cr³⁺ diffused readily into the LSAM lattice. The interdiffusion of cations between LSAM and Ni- GDC at 1300 °C was limited, implying excellent chemical compatibility. The electrochemical performance of symmetrical cells of the anode materials was measured under hydrogen atmosphere. The area-specific polarization resistance of Ni-GDC was 5.12 Ω·cm² at 800 ° C. An open-circuit voltage of 0.925 V and a power density of 19.5 mW·cm^-2 were obtained at 800 °C for a 550 μm thick LSAM electrolyte-supported single cell (Ni-GDC/GDC/LSAM/GDC/La0.75Sr0.25FeO3).
- LaAlO₃-based electrolyte,
- Chemical compatibility,
- Area-specific polarisation resistance,
- Solid oxide fuel cell
1. [1]
  
  (1) Wang, Z.W.; Hashimoto, S.; Mori, M. J. Power Sources 2009,193, 49. doi: 10.1016/j.jpowsour.2009.01.004
2. [2]
  (2) Hayashi, H.; Inaba, H.; Matsuyama, M.; Lan, N. G.; Dokiya,M.; Tagawa, H. Solid State Ionics 1999, 122, 1. doi: 10.1016/S0167-2738(99)00066-1
3. [3]
  (3) Chen, T. Y.; Fung, K. Z. J. Alloy. Compd. 2004, 368, 106. doi: 10.1016/j.jallcom.2003.08.059
4. [4]
  (4) Park, J. Y.; Choi, G. M. Solid State Ionics 2002, 154 -155, 535.
5. [5]
  (5) Park, J. Y.; Choi, G. M. Solid State Ionics 2005, 176, 2807. doi: 10.1016/j.ssi.2005.09.007
6. [6]
  (6) Nomura, K.; Tanase, S. Solid State Ionics 1997, 98, 229. doi: 10.1016/S0167-2738(97)00101-X
7. [7]
  (7) Nguyen, T. L.; Dokiya, M.;Wang, S. R.; Tagawa, H.;Hashimoto, T. Solid State Ionics 2000, 130, 229. doi: 10.1016/S0167-2738(00)00640-8
8. [8]
  (8) Chen, T. Y.; Pan, R. Y. J. Phys. Chem. Solids 2008, 69, 540. doi: 10.1016/j.jpcs.2007.07.039
9. [9]
  (9) Tarancón, A.; Martínez, J. P.; López, D. M.; Morales, J. C. R.;Núñez, P. Solid State Ionics 2008, 179, 2372. doi: 10.1016/j.ssi.2008.09.016
10. [10]
  (10) López, D. M.; Martínez, J. P.; Morales, J. C. R.; Gabás, M.;Núñez, P.; Aranda, M. A. G.; Barrado, J. R. R. Solid State Ionics2010, 180, 1672. doi: 10.1016/j.ssi.2009.11.005
11. [11]
  (11) Lee, D.; Han, J. H.; Chun, Y.; Song, R. H.; Shin, D. R. J. Power Sources 2007, 166, 35. doi: 10.1016/j.jpowsour.2006.12.099
12. [12]
  (12) Park, H. J.; Kim, S. Solid State Ionics 2008, 27 -32, 1329.
13. [13]
  (13) Lybye, D.; Poulsen, F.W.; Mogensen, M. Solid State Ionics2000, 128, 91. doi: 10.1016/S0167-2738(99)00337-9
14. [14]
  (14) Chen, T. Y.; Fung, K. Z. J. Power Sources 2004, 132, 1. doi: 10.1016/j.jpowsour.2003.12.062
15. [15]
  (15) Kostogloudis, G. C.; Ftikos, C.; Khanlou, A. A.; Naoumidis, A.;Stöver, D. Solid State Ionics 2000, 134, 127. doi: 10.1016/S0167-2738(00)00721-9
16. [16]
  (16) López, D. M.; Sedeñoc, M. C. M.; Martínez, J. P.; Morales, J. C.R.; Núñez, P.; Aranda, M. A. G.; Barrado, J. R. R. J. Power Sources 2010, 195, 2496. doi: 10.1016/j.jpowsour.2009.11.068
17. [17]
  (17) Sudireddy, B. R.; Blennow, P.; Nielsen, K. A. Solid State Ionics2012, 216, 44. doi: 10.1016/j.ssi.2011.11.025
18. [18]
  (18) Qiao, L.; Droubay, T. C.; Kaspar, T. C.; Chambers, S. A.;Sushko, P. V. Surface Science 2011, 605, 1381. doi: 10.1016/j.susc.2011.04.035
19. [19]
  (19) Kalabukhov, A. S.; Boikov, Y. A.; Serenkov, I. T.; Sakharov, V.I.; Popok, V. N. Phys. Rev. Lett. 2009, 103, 146101. doi: 10.1103/PhysRevLett.103.146101
20. [20]
  (20) Tao, S.W.; Irvine, J. T. S.; Kilner, J. A. Adv. Mater. 2005, 17,1734.
21. [21]
  (21) Martínez, J. P.; López, D. M.; Morales, J. C. R.; Buergler, B. E.;Núñez, P.; Gauckler, L. J. J. Power Sources 2006, 159, 914. doi: 10.1016/j.jpowsour.2005.11.036
22. [22]
  (22) Martínez, J. P.; López, D. M.; Savaniu, C.; Núñez, P.; Irvine, J.T. S. Chem. Mater. 2006, 18, 1001. doi: 10.1021/cm0516659
23. [23]
  (23) Zhu, C. F.;Wang, G.; Xue, J. H.; Ouyang, P. K. Acta Phys. -Chim. Sin. 2009, 25, 2211. [朱承飞, 王刚, 薛金花,欧阳平凯. 物理化学学报, 2009, 25, 2211.] doi: 10.3866/PKU.WHXB20091132
24. [24]
  (24) Vázquez, J. M. P.; Gómez, L. D. S.; Santacruz, I.; Aranda, M. A.G.; López, D. M.; Losilla, E. R. S. Ceram. Inter. 2012, 38, 3327.doi: 10.1016/j.ceramint.2011.12.042
25. [25]
  (25) Zou, Y. M.;Wang, S. Z. Acta Phys. -Chim. Sin. 2006, 22, 958.[邹玉满, 王世忠. 物理化学学报, 2006, 22, 958.] doi: 10.3866/PKU.WHXB20060810
26. [26]
  (26) Li, Y.;Wang, L. S. Fuel Cell; Metallurgical Industry Press:Beijing, 2000; pp 36-39. [李瑛, 王林山. 燃料电池. 北京:冶金工业出版社, 2000: 36-39.]
27. [27]
  (27) Fung, K. Z.; Chen, T. Y. Solid State Ionics 2011, 188, 64.doi: 10.1016/j.ssi.2010.09.035
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Chemical Compatibility and Electrochemical Performance between LaAlO3-Based Electrolyte and Selected Anode Materials

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通讯作者: 陈斌, bchen63@163.com

Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials