Citation: QIN Guo-Heng, HUANG Xiao-Wei, HU Zhi. Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 311-318. doi: 10.3866/PKU.WHXB201212062 shu

Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials

1.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, P.R. China

Received Date: 17 September 2012
Available Online: 6 December 2012
Fund Project: 福建省自然科学基金(2008J0146)资助项目 (2008J0146)

Powders of La_0.90Sr_0.10Al_0.97Mg_0.03O_3-δ (LSAM) were synthesized by the glycine-nitrate process, and then sintered at 1500 °C for 5 h. Impedance spectroscopy at 900 °C in air revealed that the conductivity of LSAM was 1.11×10^-2 S·cm^-1. The chemical compatibility of LSAM with anode materials NiO-Ce_0.9Gd_0.1O_1.95 (Ni-GDC), Sr_0.88Y_0.08TiO₃ (SYT) and La_0.75Sr_0.25Cr_0.5Mn_0.5O₃ (LSCM) was characterized by X-ray diffraction, scanning electron microscopy with energy-dispersive X-ray spectroscopy and AC impedance spectroscopy. The results indicated that SYT and LSCM had poor chemical compatibility with LSAM because Sr²⁺, Ti⁴⁺, Mn³⁺, and Cr³⁺ diffused readily into the LSAM lattice. The interdiffusion of cations between LSAM and Ni- GDC at 1300 °C was limited, implying excellent chemical compatibility. The electrochemical performance of symmetrical cells of the anode materials was measured under hydrogen atmosphere. The area-specific polarization resistance of Ni-GDC was 5.12 Ω·cm² at 800 ° C. An open-circuit voltage of 0.925 V and a power density of 19.5 mW·cm^-2 were obtained at 800 °C for a 550 μm thick LSAM electrolyte-supported single cell (Ni-GDC/GDC/LSAM/GDC/La0.75Sr0.25FeO3).
- LaAlO₃-based electrolyte,
- Chemical compatibility,
- Area-specific polarisation resistance,
- Solid oxide fuel cell
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Chemical Compatibility and Electrochemical Performance between LaAlO3-Based Electrolyte and Selected Anode Materials

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通讯作者: 陈斌, bchen63@163.com

Chemical Compatibility and Electrochemical Performance between LaAlO₃-Based Electrolyte and Selected Anode Materials