Citation: LIU Na, YI Cheng-Lin, SUN Jian-Hua, WANG Juan-Qin, LIU Xiao-Ya. Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 327-334. doi: 10.3866/PKU.WHXB201212032 shu

Structure and Emulsification Performance of Amphiphilic Copolymer Self-Assembled Micelles

1.
Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 23 October 2012
Available Online: 3 December 2012
Fund Project: 国家自然科学基金(20974041, 21174056) (20974041, 21174056)中央高校基本科研业务费专项资金(JUDCF09007)资助项目 (JUDCF09007)

The photosensitive amphiphilic copolymer poly-(styrene-alt-maleic anhydride)-co-poly (7-(4-vinylbenzyloxyl)-4-methylcoumarin-alt-maleic anhydride) (PSMVM) micelles with various degrees of swelling were used as polymeric micellar emulsifiers to stabilize toluene-in-water emulsions. This paper focuses on the influence of the degree of photo-crosslinking on the micellar structure and the emulsification performance of the micelles. The research results indicated that the degree of photo-crosslinking, the degree of swelling, and the charge on the micelles played an important role in the micellar structure and the emulsifying performance of the micelles.
- Amphipathy,
- Self-assembly,
- Photo-crosslinking degree,
- Swelling degree,
- Emulsification
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