Citation: ZHANG Long, HAN Jing-Jing, LI Jia-Jia, LIU Tian-Qing. Properties and Spreading Kinetics of Water-Based Cypermethrin Microemulsions[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 346-350. doi: 10.3866/PKU.WHXB201211302 shu

Properties and Spreading Kinetics of Water-Based Cypermethrin Microemulsions

1.
1 School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, Jiangsu Province, P. R. China;
2 Jiangsu Animal Husbandry and Veterinary College, Taizhou 225300, Jiangsu Province, P. R. China

Received Date: 16 September 2012
Available Online: 30 November 2012
Fund Project: 国家自然科学基金(20573091) (20573091)

Water-based cypermethrin microemulsions were prepared by adding oil to emulsified water, with ethyl butyrate as the solvent, TritonX-100 (TX-100) and sodium dodecyl benzene sulfonate (SDBS) as surfactants, and n-butyl alcohol (n-C₄H₉OH) as a co-surfactant. The structure and properties of the microemulsions were investigated by determining the phase diagram, and using negative-staining transmission electron microscopy, and conductivity, surface tension, dynamic light scattering, and contact angle measurements. The spreading kinetics of the microemulsions on the leaf surface of Youngfu wheat was also studied. The results showed that the cypermethrin microemulsions followed the oil-in-water model, and had a strong solubilizing effect on cypermethrin. The microemulsions showed a low contact angle, and low surface tension, and the droplet radius was about 45 nm. The kinetics for the spreading of the microemulsions on the leaf surface of Youngfu wheat fitted a second-order kinetic equation. The kinetic rate constants were 0.1090 (°)^-1·min^-1 (20℃) and 0.1572 (°)^-1·min^-1 (30℃), and the activation energy was 27.03 kJ·mol^-1.
- Cypermethrin,
- Microemulsion,
- Oil in water,
- Contact angle,
- Spreading kinetics
1. [1]
  
  (1) Wang, L. J.; Li, X. F.; Zhang, G. Y.; Dong, J. F.; Eastoe, J.J. Colloid Interface Sci. 2007, 314, 230. doi: 10.1016/j.jcis.2007.04.079
2. [2]
  (2) Chen, F. L.;Wang, Y.; Zheng, F. N.;Wu, Y. T.; Liang,W. P.Colloids Surf. A 2000, 175, 257. doi: 10.1016/S0927-7757(00)00505-7
3. [3]
  (3) Lee, H. J.; Shan, G.; Ahn, K. C.; Park, E. K.;Watanabe, T.; Gee,S. J.; Hammock, B. D. J. Agric. Food Chem. 2004, 52, 1039.doi: 10.1021/jf030519p
4. [4]
  (4) Rosenheimer, M. S.; Dubowski, Y. J. Phys. Chem. C 2007, 111,11682. doi: 10.1021/jp072937t
5. [5]
  (5) Nurettin, S.; Sultan, B.; Pinar, I. Colloids Surf. A 2011, 386, 16.doi: 10.1016/j.colsurfa.2011.06.023
6. [6]
  (6) Liu,W. P.; Gan, J. J.; Lee, S.;Werner, I. J. Agric. Food Chem.2004, 52, 6233. doi: 10.1021/jf0490910
7. [7]
  (7) Wang, Q.; Qiu, J.; Zhu,W.; Jia, G.; Li, J.; Bi, C.; Zhou, Z.Environ. Sci. Technol. 2006, 40, 721. doi: 10.1021/es052025+
8. [8]
  (8) Qin, S. J.; Gan, J. J. J. Agric. Food Chem. 2007, 55, 5734. doi: 10.1021/jf0708894
9. [9]
  (9) Sundaram, K. M. S.; Szeto, S. Y. J. Agric. Food Chem. 1984,32, 1138. doi: 10.1021/jf00125a052
10. [10]
  (10) Schafer, R. B.; Pettigrove, V.; Rose, G.; Allinson, G.;Wightwick, A.; Shimeta, J.; Kühne, R.; Kefford, B. J. Environ. Sci. Technol. 2011, 45, 1665. doi: 10.1021/es103227q
11. [11]
  (11) Sherma, J. Anal. Chem. 1995, 67, 1.
12. [12]
  (12) Zhang, X.; Liu, J. J. Agric. Food Chem. 2011, 59, 1308. doi: 10.1021/jf1034459
13. [13]
  (13) Clarens, A. F.; Zimmerman, J. B.; Keoleian, G. A.; Hayes, K. F.;Skerlos, S. J. Environ. Sci. Technol. 2008, 42, 8534. doi: 10.1021/es800791z
14. [14]
  (14) Nichkova, M.; Fu, X.; Yang, Z.; Zhong, P.; Sanborn, J. R.;Chang, D.; Gee, S. J.; Hammock, B. D. J. Agric. Food Chem.2009, 57, 5673. doi: 10.1021/jf900652a
15. [15]
  (15) Hartnik, T.; Styrishave, B. J. Agric. Food Chem. 2008, 56,11057. doi: 10.1021/jf8017904
16. [16]
  (16) Guo, R.; Liu, T. Q.; Yu,W. L. Langmuir 1999, 15, 624.
17. [17]
  (17) Liu, T. Q.; Song, L.; Gan, Y. Y.; Chen, L. H. Colloids Surf. A2008, 329, 198. doi: 10.1016/j.colsurfa.2008.07.009
18. [18]
  (18) Qiao, Y.; Lin, Y. Y.;Wang, Y. J.; Li, Z. B.; Huang, J. B.Langmuir 2011, 27, 1718. doi: 10.1021/la104447d
19. [19]
  (19) Peng, X. H.; Zheng, P. Z.; Ma, Y. M.; Yin, T. X.; An, X. Q.;Shen,W. G. Acta Phys. -Chim. Sin. 2011, 27, 1026. [彭旭红,郑佩珠, 马元明, 殷天翔, 安学勤, 沈伟国. 物理化学学报,2011, 27, 1026.] doi: 10.3866/PKU.WHXB20110503
20. [20]
  (20) Pasandideh, F. M.; Qiao, Y. M.; Chandra, S.; Mostaghimi, J.Phys. Fluids 1996, 8, 650. doi: 10.1063/1.868850
21. [21]
  (21) Ukiwe, C.; Kwok, D. Y. Langmuir 2005, 21, 666. doi: 10.1021/la0481288
22. [22]
  (22) Vadillo, D. C.; Soucemarianadin, A.; Delattre, C.; Roux, D. C.D. Phys. Fluids 2009, 21, 122002. doi: 10.1063/1.3276259
23. [23]
  (23) Lee, J. B.; Lee, S. H. Langmuir 2011, 27, 6565. doi: 10.1021/la104829x
24. [24]
  (24) Svitova, T.; Hoffmann, H.; Hill, R. M. Langmuir 1996, 12,1712. doi: 10.1021/la9505172
25. [25]
  (25) Guo, R.; Liu, T. Q. J. Disper. Sci. Technol. 1999, 20, 1327. doi: 10.1080/01932699908943856
26. [26]
  (26) Liu, T. Q.; Zhang, Q. Q.; Fan, G. K.; Guo, R. Acta Chim. Sin.2000, 58, 840. [刘天晴, 张启清, 范国康, 郭荣. 化学学报,2000, 58, 840.]
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