Citation: WU Xu, CAI Xiao-Xin, WANG Jin-Ben, YANG Hui, SHI Xue-Feng. Salt Effect on Controlling Aggregation Behavior of Brush-Like Amphiphilic Polymers[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 341-345. doi: 10.3866/PKU.WHXB201211262 shu

Salt Effect on Controlling Aggregation Behavior of Brush-Like Amphiphilic Polymers

1.
1 College of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, P. R. China;
2 Key Laboratory of Colloid, Interface and Chemical Thermodynamics, Institute of Chemistry, the Chinese Academy of Sciences, Beijing 100190, P. R. China

Received Date: 17 September 2012
Available Online: 26 November 2012
Fund Project:

The extraordinary properties of amphiphilic polymers originate from their unique skeleton structures and the aggregation behavior of the polymer chains. In the present work, we introduced different amounts of NaCl into AMPS-AMC₁₂S brush-like amphiphilic polymers synthesized via the statistical polymerization of 2-(acrylamido)-dodecanesulfonic acid (AMC₁₂S) with 2-(acrylamido)-2-methylpropanesulfonic acid (AMPS), and investigated the effects of the NaCl on the aggregation behavior of the polymers, using steady-state fluorescence, dynamic light scattering, and transmission electron microscopy. The results showed that the effects of the salt were more intense for polymers with fewer side chains. As the NaCl concentration increased, the polymer chains associated at a lower critical concentration. The polymers tended to aggregate in an intrapolymer configuration, in preference to an interpolymer configuration; this resulted in the formation of smaller unimers, rather than giant multipolymer aggregates. The results described here provide an efficient approach for controlling the aggregation behavior of amphiphilic polymers, and have significance in advancing the design and control of functional aqueous systems, as well as in promoting the development and application of novel polymers.
- Aggregation behavior,
- NaCl,
- Aggregate,
- Brush-like polymer,
- Control
1. [1]
  
  (1) Sambe, L.; Stoffelbach, F.; Lyskawa, J.; Delattre, F.; Fournier, D.; Bouteiller, L.; Charleux, B.; Cooke, G.; Woisel, P. Macromolecules 2011, 44, 6532. doi: 10.1021/ma2009854
2. [2]
  (2) Tanner, P.; Baumann, P.; Enea, R.; Onaca, O.; Palivan, C.; Meier, W. Accounts of Chemical Research 2011, 44, 1039. doi: 10.1021/ar200036k
3. [3]
  (3) Burke, S. E.; Eisenberg, A. Langmuir 2001, 17, 6705. doi: 10.1021/la010640v
4. [4]
  (4) Förster, S.; Abetz, V.; Müller, A. H. E. Adv. Polym. Sci. 2004, 166, 173. doi: 10.1007/b10951
5. [5]
  (5) Borisov, O. V.; Zhulina, E. B. Langmuir 2005, 21, 3229. doi: 10.1021/la0469203
6. [6]
  (6) Noda, T.; Hashidzume, A.; Morishima, Y. Macromolecules 2001, 34, 1308. doi: 10.1021/ma0017283
7. [7]
  (7) Oda, Y.; Kanaoka, S.; Sato, T.; Aoshima, S.; Kuroda, K. Biomacromolecules 2011, 12, 3581. doi: 10.1021/bm200780r
8. [8]
  (8) Noda, T.; Hashidzume, A.; Morishima, Y. Langmuir 2000, 16, 5324. doi: 10.1021/la9916070
9. [9]
  (9) Tomatsu, I.; Hashidzume, A.; Yusa, S.; Morishima, Y. Macromolecules 2005, 38, 7837. doi: 10.1021/ma051145z
10. [10]
  (10) Yamamoto, H.; Morishima, Y. Macromolecules 1999, 32, 7469. doi: 10.1021/ma9907791
11. [11]
  (11) Yamamoto, H.; Tomatsu, I.; Hashidzume, A.; Morishima, Y. Macromolecules 2000, 33, 7852. doi: 10.1021/ma9920487
12. [12]
  (12) Suwa, M.; Hashidzume, A.; Morishima, Y.; Nakato, T.; Tomida, M. Macromolecules 2000, 33, 7884. doi: 10.1021/ma0008342
13. [13]
  (13) Hashidzume, A.; Kawaguchi, A.; Tagawa, A.; Hyoda, K.; Sato, T. Macromolecules 2006, 39, 1135. doi: 10.1021/ma051950d
14. [14]
  (14) Noda, T.; Hashidzume, A.; Morishima, Y. Macromolecules 2000, 33, 3694. doi: 10.1021/ma991680x
15. [15]
  (15) Kawata, T.; Hashidzume, A.; Sato, T. Macromolecules 2007, 40, 1174. doi: 10.1021/ma062299x
16. [16]
  (16) Mitsukami, Y.; Hashidzume, A.; Yusa, S.; Morishima, Y.; Lowe, A. B.; Mccormick, C. L. Polymer 2006, 47, 4333. doi: 10.1016/j.polymer.2006.04.026
17. [17]
  (17) Yusa, S.; Yama , S.; Sugahara, M.; Morikawa, S.; Yamamoto, T.; Morishima, Y. Macromolecules 2007, 40, 5907. doi: 10.1021/ma070769x
18. [18]
  (18) Wu, X.; Qiao, Y. J.; Yang, H.; Wang, J. B. J. Colloid Interface Sci. 2010, 349, 560. doi: 10.1016/j.jcis.2010.05.093
19. [19]
  (19) Wu, X.; Qiao, Y. J.; Wang, J. B. J. Chem. Eng. Data 2010, 55, 919. doi: 10.1021/je900497f
20. [20]
  (20) Li, R. Q.; Wei, L. B.; Hu, C. C.; Xu, C. F.; Wang, J. B. J. Phys. Chem. B 2010, 114, 12448. doi: 10.1021/jp102685w
21. [21]
  (21) Hu, C. C.; Li, R. Q.; Yang, H.; Wang, J. B. J. Colloid Interface Sci. 2011, 356, 605. doi: 10.1016/j.jcis.2011.01.062
22. [22]
  (22) Wu, X.; Qiao, Y. J.; Hu, C. C.; Yang, H.; Wang, J. B. Acta Phys. Chim. Sin. 2010, 26, 324. [吴旭, 乔英杰, 胡长朝, 杨惠, 王金本. 物理化学学报 2010, 26, 324.] doi: 10.3866/PKU.WHXB20100204
23. [23]
  (23) Ueda, M.; Hashidzume, A.; Sato, T. Macromolecules 2011, 44, 2970. 10.1021/ma102635y
24. [24]
  (24) Zhu, X. W.; Liu, M. H. Langmuir 2011, 27, 12844. doi: 10.1021/la202680j
25. [25]
  (25) Yamamoto, H.; Tomatsu, I.; Hashidzume, A.; Morishima, Y. Macromolecules 2000, 33, 7852. doi: 10.1021/ma9920487
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Salt Effect on Controlling Aggregation Behavior of Brush-Like Amphiphilic Polymers

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com