Citation: AO Yin-Yong, WANG Qian, PENG Jing, HUANG Wei, ZHAI Mao-Lin, LONG Xing-Gui. Influence of Atmosphere on the Radiolysis Products of BPC6 under γ-Irradiation[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 418-422. doi: 10.3866/PKU.WHXB201211215 shu

Influence of Atmosphere on the Radiolysis Products of BPC6 under γ-Irradiation

AO Yin-Yong ^1,2 ,
WANG Qian ¹ ,
PENG Jing ² ,
HUANG Wei ¹ ,
ZHAI Mao-Lin ^2, ,
LONG Xing-Gui ^1,

1.
1 Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China;
2 Beijing National Laboratory for Molecular Sciences, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 25 September 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金(91126014, 11079007, 21073008) (91126014, 11079007, 21073008)高等学校博士点基金(20100001110021)资助项目 (20100001110021)

Bis(2-propyloxy)calix[4]crown-6 (BPC6) is an effective separation agent for the removal of cesium from high-level liquid wastes, because of its high selectivity and coordination capacity toward cesium ions. BPC6 will be exposed to ionizing radiation generated by radionuclides during the treatment of high-level liquid nuclear wastes, so it is necessary to investigate the radiolysis mechanism of BPC6 under γ-irradiation conditions. In this work, the radiolysis products including the gaseous and solid products of BPC6 solid were systematically assessed using gas chromatography (GC), micro Fourier transform infrared (Micro-FTIR) spectroscopy, and nuclear magnetic resonance spectroscopy. The radiolysis ratio for BPC6 in an O₂ atmosphere (approximately 10.4%) was significantly higher than that in an N₂ atmosphere (approximately 2.5%). The main radiolytic gas products of BPC6 under O₂ were H₂, CH₄, CO, and CO₂, while those under N₂ were H₂, CH₄, CO, CO₂, C₂H₄, C₂H₆, C₃H₆, and C₃H₈. Finally, a mechanism for the radiolysis of BPC6 under different atmospheres was suggested, in terms of the gas and solid radiolytic products. This work will be of significant help in understanding the degradation mechanism of the BPC6 extraction system.
- BPC6,
- Cs⁺ extractant,
- γ-Radiation,
- Radiolytic product,
- Gas chromatography analysis
1. [1]
  
  (1) Lumetta, G. I.; Nash, K. L.; Clark, S. B.; Friese, J. I. Ind. Eng. Chem. Res. 2006, 44, 2887.
2. [2]
  (2) Salorinne, K.; Nissinen, M. J. Inclusion Phenom. Macro. 2008,61, 11. doi: 10.1007/s10847-008-9411-y
3. [3]
  (3) Mathieu, A.; Asfari, Z.; Thuery, P.; Nierlich, M.; Faure, S.;Vicens, J. J. Inclusion Phenom. Macro. 2001, 40, 173. doi: 10.1023/A:1011803705182
4. [4]
  (4) Kim, J. S.; Yu, I. Y.; Pang, J. H.; Kim, J. K.; Lee, Y. I.; Lee, K.W.; Oh,W. Z. Microchem. J. 1998, 58, 225. doi: 10.1006/mchj.1997.1545
5. [5]
  (5) Arnaud-Neu, F.; Asfari, Z.; Souley, B.; Vicens, J. Anales De Quimica-International Edition 1997, 93, 404.
6. [6]
  (6) Arnaud-Neu, F.; Asfari, Z.; Souley, B.; Vicens, J. New J. Chem.1996, 20, 453.
7. [7]
  (7) Haverlock, T. J.; Bonnesen, P. V.; Sachleben, R. A.; Moyer, B.A. Radiochim. Acta 1997, 76, 103.
8. [8]
  (8) Khrifi, S.; Guelzim, A.; Baert, F.; Asfari, Z.; Vicens, J.J. Inclusion Phenom. Mol. Recognit. Chem. 1997, 29, 187. doi: 10.1023/A:1007923507891
9. [9]
  (9) Alfieri, C.; Dradi, E.; Pochini, A.; Ungaro, R.; Andreetti, G. D.Journal of the Chemical Society-Chemical Communications1983, 1075.
10. [10]
  (10) Lamouroux, C.; Aychet, N.; Lelievre, A.; Jankowski, C. K.;Moulin, C. Rapid Commun. Mass Spectrom. 2004, 18, 1493.
11. [11]
  (11) Jankowski, C. K.; Hocquelet, C.; Arseneau, S.; Moulin, C.;Mauclaire, L. J. Photochem. Photobiol. A 2006, 184, 216. doi: 10.1016/j.jphotochem.2006.04.018
12. [12]
  (12) Jankowski, C. K.; Allain, F.; Dozol, J. F.; Virelizier, H.; Tabet, J.C.; Moulin, C.; Lamouroux, C. Rapid Commun. Mass Spectrom.2003, 17, 1247.
13. [13]
  (13) Jankowski, C. K.; Dozol, J. F.; Allain, F.; Tabet, J. C.; Ungaro,R.; Casnati, A.; Vicens, J.; Asfari, A.; Boivin, J. Pol. J. Chem.2002, 76, 701.
14. [14]
  (14) Kroupa, J.; Lhotak, P.; Cuba, V.; John, J.; Rudzevich, V.;Bohmer, V. Radiochim. Acta 2009, 97, 429. doi: 10.1524/ract.2009.1629
15. [15]
  (15) Feng,W.; Yuan, L. H.; Zheng, S. Y.; Huang, G. L.; Qiao, J. L.;Zhou, Y. Radiat. Phys. Chem. 2000, 57, 425. doi: 10.1016/S0969-806X(99)00451-X
16. [16]
  (16) Ao, Y. Y.; Peng, J.; Zhang, Y.W.; Yuan, L. Y.; Yu, C. H.; Li, J.Q.; Zhai, M. L. Chin. Sci. Bull. accepted.
17. [17]
  (17) Zhu, X.W.;Wang, J. C.; Song, L. C. Atomic Energy Science and Technology 2004, 38, 301. [朱晓文, 王建晨, 宋崇立.原子能科学技术, 2004, 38, 301.]
18. [18]
  (18) Casnati, A.; Pochini, A.; Ungaro, R.; U zzoli, F.; Arnaud, F.;Fanni, S.; Schwing, M. J.; Egberink, R. J. M.; Dejong, F.;Reinhoudt, D. N. J. Am. Chem. Soc. 1995, 117, 2767. doi: 10.1021/ja00115a012
19. [19]
  (19) Zhu, X.W.;Wang, J. C.; Tong, L. B.; Song, L. C. Atomic Energy Science and Technology 2003, 37, 428. [朱晓文, 王建晨, 童利斌, 宋崇立. 原子能科学技术, 2003, 37, 428.]
20. [20]
  (20) Shi, J.; Barker, J. R. Journal of Geophysical Research 1992, 97,13039. doi: 10.1029/92JD00571
21. [21]
  (21) Heller, C. A.; rdon, A. S. J. Phys. Chem. 1960, 64, 390.doi: 10.1021/j100833a003
22. [22]
  (22) Heller, C. A.; rdon, A. S. J. Phys. Chem. 1956, 60, 1315.doi: 10.1021/j150543a038
23. [23]
  (23) Ge, M.;Wang,W. F.; Zhao, H.W.; Zhang, Z. Y.; Yu, X. H.; Li,W. X. Chem. Phys. Lett. 2007, 444, 355. doi: 10.1016/j.cplett.2007.07.028
24. [24]
  (24) Devlin, H. R.; Harris, I. J. Industrial & Engineering Chemistry Fundamentals 1984, 23, 387. doi: 10.1021/i100016a002
1. [1]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
4. [4]
  Xue Dong , Xiaofu Sun , Shuaiqiang Jia , Shitao Han , Dawei Zhou , Ting Yao , Min Wang , Minghui Fang , Haihong Wu , Buxing Han . 碳修饰的铜催化剂实现安培级电流电化学还原CO₂制C₂₊产物. Acta Physico-Chimica Sinica, 2025, 41(3): 2404012-. doi: 10.3866/PKU.WHXB202404012
5. [5]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
6. [6]
  Yuchen Zhou , Huanmin Liu , Hongxing Li , Xinyu Song , Yonghua Tang , Peng Zhou . 设计热力学稳定的贵金属单原子光催化剂用于乙醇的高效非氧化转化形成高纯氢和增值产物乙醛. Acta Physico-Chimica Sinica, 2025, 41(6): 100067-. doi: 10.1016/j.actphy.2025.100067
7. [7]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
8. [8]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
9. [9]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
10. [10]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
11. [11]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
12. [12]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
13. [13]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
14. [14]
  Yulian Hu , Xin Zhou , Xiaojun Han . A Virtual Simulation Experiment on the Design and Property Analysis of CO₂ Reduction Photocatalyst. University Chemistry, 2025, 40(3): 30-35. doi: 10.12461/PKU.DXHX202403088
15. [15]
  Mi Wen , Baoshuo Jia , Yongqi Chai , Tong Wang , Jianbo Liu , Hailong Wu . Improvement of Fluorescence Quantitative Analysis Experiment: Simultaneous Determination of Rhodamine 6G and Rhodamine 123 in Food Using Chemometrics-Assisted Three-Dimensional Fluorescence Method. University Chemistry, 2025, 40(4): 390-398. doi: 10.12461/PKU.DXHX202405147
16. [16]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
17. [17]
  . . University Chemistry, 2024, 39(6): 0-0.
18. [18]
  . 第41卷第6期封面和目次. Acta Physico-Chimica Sinica, 2025, 41(6): -.
19. [19]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
20. [20]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011

Get Citation

PDF

XML

Metrics

PDF Downloads(633)
Abstract views(1408)
HTML views(7)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142