Citation: AO Yin-Yong, WANG Qian, PENG Jing, HUANG Wei, ZHAI Mao-Lin, LONG Xing-Gui. Influence of Atmosphere on the Radiolysis Products of BPC6 under γ-Irradiation[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 418-422. doi: 10.3866/PKU.WHXB201211215 shu

Influence of Atmosphere on the Radiolysis Products of BPC6 under γ-Irradiation

AO Yin-Yong ^1,2 ,
WANG Qian ¹ ,
PENG Jing ² ,
HUANG Wei ¹ ,
ZHAI Mao-Lin ^2, ,
LONG Xing-Gui ^1,

1.
1 Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, Sichuan Province, P. R. China;
2 Beijing National Laboratory for Molecular Sciences, Department of Applied Chemistry, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 25 September 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金(91126014, 11079007, 21073008) (91126014, 11079007, 21073008)高等学校博士点基金(20100001110021)资助项目 (20100001110021)

Bis(2-propyloxy)calix[4]crown-6 (BPC6) is an effective separation agent for the removal of cesium from high-level liquid wastes, because of its high selectivity and coordination capacity toward cesium ions. BPC6 will be exposed to ionizing radiation generated by radionuclides during the treatment of high-level liquid nuclear wastes, so it is necessary to investigate the radiolysis mechanism of BPC6 under γ-irradiation conditions. In this work, the radiolysis products including the gaseous and solid products of BPC6 solid were systematically assessed using gas chromatography (GC), micro Fourier transform infrared (Micro-FTIR) spectroscopy, and nuclear magnetic resonance spectroscopy. The radiolysis ratio for BPC6 in an O₂ atmosphere (approximately 10.4%) was significantly higher than that in an N₂ atmosphere (approximately 2.5%). The main radiolytic gas products of BPC6 under O₂ were H₂, CH₄, CO, and CO₂, while those under N₂ were H₂, CH₄, CO, CO₂, C₂H₄, C₂H₆, C₃H₆, and C₃H₈. Finally, a mechanism for the radiolysis of BPC6 under different atmospheres was suggested, in terms of the gas and solid radiolytic products. This work will be of significant help in understanding the degradation mechanism of the BPC6 extraction system.
- BPC6,
- Cs⁺ extractant,
- γ-Radiation,
- Radiolytic product,
- Gas chromatography analysis
1. [1]
  
  (1) Lumetta, G. I.; Nash, K. L.; Clark, S. B.; Friese, J. I. Ind. Eng. Chem. Res. 2006, 44, 2887.
2. [2]
  (2) Salorinne, K.; Nissinen, M. J. Inclusion Phenom. Macro. 2008,61, 11. doi: 10.1007/s10847-008-9411-y
3. [3]
  (3) Mathieu, A.; Asfari, Z.; Thuery, P.; Nierlich, M.; Faure, S.;Vicens, J. J. Inclusion Phenom. Macro. 2001, 40, 173. doi: 10.1023/A:1011803705182
4. [4]
  (4) Kim, J. S.; Yu, I. Y.; Pang, J. H.; Kim, J. K.; Lee, Y. I.; Lee, K.W.; Oh,W. Z. Microchem. J. 1998, 58, 225. doi: 10.1006/mchj.1997.1545
5. [5]
  (5) Arnaud-Neu, F.; Asfari, Z.; Souley, B.; Vicens, J. Anales De Quimica-International Edition 1997, 93, 404.
6. [6]
  (6) Arnaud-Neu, F.; Asfari, Z.; Souley, B.; Vicens, J. New J. Chem.1996, 20, 453.
7. [7]
  (7) Haverlock, T. J.; Bonnesen, P. V.; Sachleben, R. A.; Moyer, B.A. Radiochim. Acta 1997, 76, 103.
8. [8]
  (8) Khrifi, S.; Guelzim, A.; Baert, F.; Asfari, Z.; Vicens, J.J. Inclusion Phenom. Mol. Recognit. Chem. 1997, 29, 187. doi: 10.1023/A:1007923507891
9. [9]
  (9) Alfieri, C.; Dradi, E.; Pochini, A.; Ungaro, R.; Andreetti, G. D.Journal of the Chemical Society-Chemical Communications1983, 1075.
10. [10]
  (10) Lamouroux, C.; Aychet, N.; Lelievre, A.; Jankowski, C. K.;Moulin, C. Rapid Commun. Mass Spectrom. 2004, 18, 1493.
11. [11]
  (11) Jankowski, C. K.; Hocquelet, C.; Arseneau, S.; Moulin, C.;Mauclaire, L. J. Photochem. Photobiol. A 2006, 184, 216. doi: 10.1016/j.jphotochem.2006.04.018
12. [12]
  (12) Jankowski, C. K.; Allain, F.; Dozol, J. F.; Virelizier, H.; Tabet, J.C.; Moulin, C.; Lamouroux, C. Rapid Commun. Mass Spectrom.2003, 17, 1247.
13. [13]
  (13) Jankowski, C. K.; Dozol, J. F.; Allain, F.; Tabet, J. C.; Ungaro,R.; Casnati, A.; Vicens, J.; Asfari, A.; Boivin, J. Pol. J. Chem.2002, 76, 701.
14. [14]
  (14) Kroupa, J.; Lhotak, P.; Cuba, V.; John, J.; Rudzevich, V.;Bohmer, V. Radiochim. Acta 2009, 97, 429. doi: 10.1524/ract.2009.1629
15. [15]
  (15) Feng,W.; Yuan, L. H.; Zheng, S. Y.; Huang, G. L.; Qiao, J. L.;Zhou, Y. Radiat. Phys. Chem. 2000, 57, 425. doi: 10.1016/S0969-806X(99)00451-X
16. [16]
  (16) Ao, Y. Y.; Peng, J.; Zhang, Y.W.; Yuan, L. Y.; Yu, C. H.; Li, J.Q.; Zhai, M. L. Chin. Sci. Bull. accepted.
17. [17]
  (17) Zhu, X.W.;Wang, J. C.; Song, L. C. Atomic Energy Science and Technology 2004, 38, 301. [朱晓文, 王建晨, 宋崇立.原子能科学技术, 2004, 38, 301.]
18. [18]
  (18) Casnati, A.; Pochini, A.; Ungaro, R.; U zzoli, F.; Arnaud, F.;Fanni, S.; Schwing, M. J.; Egberink, R. J. M.; Dejong, F.;Reinhoudt, D. N. J. Am. Chem. Soc. 1995, 117, 2767. doi: 10.1021/ja00115a012
19. [19]
  (19) Zhu, X.W.;Wang, J. C.; Tong, L. B.; Song, L. C. Atomic Energy Science and Technology 2003, 37, 428. [朱晓文, 王建晨, 童利斌, 宋崇立. 原子能科学技术, 2003, 37, 428.]
20. [20]
  (20) Shi, J.; Barker, J. R. Journal of Geophysical Research 1992, 97,13039. doi: 10.1029/92JD00571
21. [21]
  (21) Heller, C. A.; rdon, A. S. J. Phys. Chem. 1960, 64, 390.doi: 10.1021/j100833a003
22. [22]
  (22) Heller, C. A.; rdon, A. S. J. Phys. Chem. 1956, 60, 1315.doi: 10.1021/j150543a038
23. [23]
  (23) Ge, M.;Wang,W. F.; Zhao, H.W.; Zhang, Z. Y.; Yu, X. H.; Li,W. X. Chem. Phys. Lett. 2007, 444, 355. doi: 10.1016/j.cplett.2007.07.028
24. [24]
  (24) Devlin, H. R.; Harris, I. J. Industrial & Engineering Chemistry Fundamentals 1984, 23, 387. doi: 10.1021/i100016a002
1. [1]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
2. [2]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
3. [3]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060
4. [4]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
5. [5]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
6. [6]
  Jingyi Chen , Fu Liu , Tiejun Zhu , Kui Cheng . Practice of Integrating Ideological and Political Education into Raman Spectroscopy Analysis Experiment Course. University Chemistry, 2024, 39(2): 140-146. doi: 10.3866/PKU.DXHX202310111
7. [7]
  Fang Niu , Rong Li , Qiaolan Zhang . Analysis of Gas-Solid Adsorption Behavior in Resistive Gas Sensing Process. University Chemistry, 2024, 39(8): 142-148. doi: 10.3866/PKU.DXHX202311102
8. [8]
  Jingming Li , Bowen Ding , Nan Li , Nurgul . Application of Comparative Teaching Method in Experimental Project Design of Instrumental Analysis Course: A Case Study in Chromatography Experiment Teaching. University Chemistry, 2024, 39(8): 263-269. doi: 10.3866/PKU.DXHX202312078
9. [9]
  Lihui Jiang , Wanrong Dong , Hua Yang , Yongqing Xia , Hongjian Peng , Jun Yuan , Xiaoqian Hu , Zihan Zeng , Yingping Zou , Yiming Luo . Study on Extraction of p-Hydroxyacetophenone. University Chemistry, 2024, 39(11): 259-268. doi: 10.12461/PKU.DXHX202402056
10. [10]
  Lijuan Wang , Yuping Ning , Jian Li , Sha Luo , Xiongfei Luo , Ruiwen Wang . Enhancing the Advanced Nature of Natural Product Chemistry Laboratory Courses with New Research Findings: A Case Study of the Application of Berberine Hydrochloride in Photodynamic Antimicrobial Films. University Chemistry, 2024, 39(11): 241-250. doi: 10.12461/PKU.DXHX202403017
11. [11]
  . . University Chemistry, 2024, 39(6): 0-0.
12. [12]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
13. [13]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
14. [14]
  Zhen Liu , Zhi-Yuan Ren , Chen Yang , Xiangyi Shao , Li Chen , Xin Li . Asymmetric alkenylation reaction of benzoxazinones with diarylethylenes catalyzed by B(C₆F₅)₃/chiral phosphoric acid. Chinese Chemical Letters, 2024, 35(5): 108939-. doi: 10.1016/j.cclet.2023.108939
15. [15]
  Ruizhi Yang , Xia Li , Weiping Guo , Zixuan Chen , Hongwei Ming , Zhong-Zhen Luo , Zhigang Zou . New thermoelectric semiconductors Pb5Sb12+xBi6-xSe32 with ultralow thermal conductivity. Chinese Journal of Structural Chemistry, 2024, 43(3): 100268-100268. doi: 10.1016/j.cjsc.2024.100268
16. [16]
  Zhengzheng LIU , Pengyun ZHANG , Chengri WANG , Shengli HUANG , Guoyu YANG . Synthesis, structure, and electrochemical properties of a sandwich-type {Co₆}-cluster-added germanotungstate. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1173-1179. doi: 10.11862/CJIC.20240039
17. [17]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
18. [18]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
19. [19]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
20. [20]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336

Get Citation

PDF

XML

Metrics

PDF Downloads(633)
Abstract views(1184)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142