Citation: GUO Li-Mei, KUANG Yuan-Jiang, YANG Xiao-Dan, YU Yan-Long, YAO Jiang-Hong, CAO Ya-An. Photocatalytic Reduction of CO₂ into CH₄ Using SrB₂O₄ Catalyst[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 397-402. doi: 10.3866/PKU.WHXB201211161 shu

Photocatalytic Reduction of CO₂ into CH₄ Using SrB₂O₄ Catalyst

GUO Li-Mei ^1,2 ,
KUANG Yuan-Jiang ³ ,
YANG Xiao-Dan ^1,2 ,
YU Yan-Long ^1,2 ,
YAO Jiang-Hong ^1,2 ,
CAO Ya-An ^1,2,

1.
1 College of Physics, Nankai University, Tianjin 300071, P. R. China;
2 Teda Applied Physics School, Key Laboratory of Weak Light Nonlinear Photonics, Ministry of Education, Nankai University, Tianjin 300457, P. R. China;
3 Maintenance Training Center, Zhenjiang Watercraft College, Zhenjiang 212000, Jiangsu Province, P. R. China

Received Date: 28 September 2012
Available Online: 21 November 2012
Fund Project: 国家自然科学基金(51072082, 21173121)资助项目 (51072082, 21173121)

The reduction of carbon dioxide to methane in the presence of water was used to evaluate the photocatalytic activity of a prepared strontium metaborate catalyst. The strontium metaborate (SrB₂O₄) was prepared by a simple sol-gel method, and was shown to exhibit better photocatalytic performance than TiO₂ (P25) under UV-light irradiation. The structure, morphology, and energy levels of the photocatalysts were studied by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), photoluminescence (PL) spectroscopy, and UV-Vis diffuse reflectance absorption spectroscopy. It was revealed that the SrB₂O₄ valence band (VB) was located at 2.07 V (vs normal hydrogen electrode, NHE), which is more positive than E_redox^o (H₂O/H⁺) (0.82 V (vs NHE)); the conduction band was estimated to be -1.47 V (vs NHE)), which is more negative than E_redox^o (CO₂/CH₄) (-0.24 V (vs NHE)). Therefore, it is clear that strontium metaborate is capable of transforming CO₂ into CH₄. Moreover, the potential at the bottom of the conduction band for SrB₂O₄ is more negative than that for TiO₂(P25), leading to a higher deoxidization capacity, which also favors CH₄ formation. Thus, SrB₂O₄ exhibits a higher photocatalytic activity than TiO₂(P25).
- Strontium metaborate,
- Photocatalytic reduction of CO₂,
- CH₄,
- Redox potential,
- Photocatalytic activity
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Photocatalytic Reduction of CO₂ into CH₄ Using SrB₂O₄ Catalyst