Citation: CHEN Mei-Ling, CHEN Shan-Shan, YI Cheng-Lin, WANG Li-Xiang, GENG Zhi-Xin, LIU Xiao-Ya. Influence of Common Solvents on Micellization Behavior and Properties of the Amphiphilic Random Copolymer P(St-co-DM)[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 335-340. doi: 10.3866/PKU.WHXB201211145 shu

Influence of Common Solvents on Micellization Behavior and Properties of the Amphiphilic Random Copolymer P(St-co-DM)

1.
Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, College of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, P. R. China

Received Date: 24 September 2012
Available Online: 14 November 2012
Fund Project: 国家自然科学基金(20974041) (20974041)中央高校基本科研项目(JUSRP211A11)资助 (JUSRP211A11)

Styrene monomer (St) and dimethylaminoethyl methacrylate monomer (DMAEMA) were used to synthesize the amphiphilic random copolymer P(St-co-DM) via free radical copolymerization. The polymer structure was characterized by Fourier transform infrared (FTIR) spectroscopy, ¹H nuclear magnetic resonance (¹H NMR) spectroscopy, gel permeation in chromatography (GPC), and differential scanning calorimetry (DSC). We investigated the influence on the microstructure of the P(St-co-DM) nanoscale micelles by self-assembly in three common solvents (co-solvent), and also investigated the effect of micelle structure on the emulsion properties. The morphologies and size distributions of the P(St-co-DM) colloid particles were studied by transmission electron microscopy (TEM) and dynamic light scattering (DLS). The results show that the more critical water content, the higher hydrophilic and the bigger hydrodynamic radius of the micelles are observed when tetrahydrofuran (THF) is used as cosolvent. When dioxane or THF is used as co-solvent, the P(St-co-DM) self-assembles into spherical micelles with a relatively loose outer layer and a compact inner layer. In the case of N,N-dimethylformamide (DMF), particles are distributed uniformly inside the spherical micelles. The hydrophilic properties of the micelles were characterized by recording the contact angle for the toluene/water interface. The contact angles of all the micelles are less than 90°. The O/W type (oil-in-water type) emulsions were obtained for three co-solvents. The type of emulsions was determined by drop test. The emulsifier experiment shows that the solid particulate emulsifiers have excellent emulsifying properties for dioxane and THF as co-solvents.
- Amphiphilic copolymer,
- Common solvent,
- Self-assembly,
- Micelle,
- Emulsification
1. [1]
  
  (1) Gao, Z. S.; Varshney, S. K.;Wong, S.; Eisenberg, A.Macromolecules 1994, 27 (26), 7923. doi: 10.1021/ma00104a058
2. [2]
  (2) Nardin, C.; Bolikal, D.; Kohn, J. Langmuir 2004, 20, 11721.doi: 10.1021/la0490285
3. [3]
  (3) Zhang, L. F.; Yu, K.; Eisenberg, A. Science 1996, 272 (5269),1777. doi: 10.1126/science.272.5269.1777
4. [4]
  (4) Liu, F.; Eisenberg, A. J. Am. Chem. Soc. 2003, 125 (49), 15059.doi: 10.1021/ja038142r
5. [5]
  (5) Soo, P. L.; Luo, L. B.; Maysinger, D.; Eisenberg, A. Langmuir2002, 18, 9996. doi: 10.1021/la026339b
6. [6]
  (6) Jiang, J. Q.; Shu, Q. Z.; Chen, X.; Yang, Y. Q.; Yi, C. L.; Song,X. Q.; Liu, X. Y. Langmuir 2010, 26, 14247. doi: 10.1021/la102771h
7. [7]
  (7) Bendejacq, D.; Ponsinet, V.; Joanicot, M.; Loo, Y. L.; Register,R. A. Macromolecules 2002, 35 (17), 6645. doi: 10.1021/ma020158z
8. [8]
  (8) Binks, B. P. Curr. Opin. Colloid Interface Sci. 2002, 7, 21. doi: 10.1016/S1359-0294(02)00008-0
9. [9]
  (9) Yi, C. L.; Yang, Y. Q.; Zhu, Y.; Liu, N.; Liu, X. Y.; Luo, J.;Jiang, J. Q. Langmuir 2012, 28, 9211. doi: 10.1021/la301605a
10. [10]
  (10) Guo, P. D.; Guan,W. Y.; Liang, L.; Yao, P. J. Colloid Interface Sci. 2008, 323, 229. doi: 10.1016/j.jcis.2008.04.009
11. [11]
  (11) Ayoub Magdy, M. H.; Nasr, H. E.; Rozik, N. N. Macromolecules1998, A35 (7), 1415.
12. [12]
  (12) Xu, K.; Yao, P. Langmuir 2009, 25, 9714. doi: 10.1021/la900960g
13. [13]
  (13) Zhang, L. F.; Eisenberg, A. Polym. Adv. Technol. 1998, 9, 677.
14. [14]
  (14) Zhang, L. F.; Eisenberg, A. Science 1995, 268 (5128), 727.
15. [15]
  (15) Eisenberg, A.; Zhang, L.; Shen, H. Macromolecules 1997, 30 (4), 1001. doi: 10.1021/ma961413g
16. [16]
  (16) Liu, X. Y.; Kim, J. S.;Wu, J.; Eisenberg, A. Macromolecules2005, 38 (16), 6749. doi: 10.1021/ma050665r
17. [17]
  (17) Zhao, Y. Q.; Fei, F.; Yi, C. L.; Jiang, J. Q.; Luo, J.; Liu, X. Y.Acta Phys. -Chim. Sin. 2010, 26 (12), 3230. [赵艳琼, 费凡,易成林, 江金强, 罗静, 刘晓亚. 物理化学学报, 2010, 26 (12), 3230.] doi: 10.3866/PKU.WHXB20101217
18. [18]
  (18) Ngai, T.; Behrens, S. H.; Auweter, H. Chem. Commun. 2005,331.
19. [19]
  (19) Cauvin, S.; Patrick, J. C.; Bon, S. A. F. Macromolecules 2005,38 (19), 7887. doi: 10.1021/ma051070z
20. [20]
  (20) Binks, B. P.; Murakami, R.; Armes, S. P.; Fujii, S. Langmuir2006, 22, 2050. doi: 10.1021/la053017+
21. [21]
  (21) Binks, B. P.; Rodrigues, J. A. Angew. Chem. Int. Edit. 2005, 44 (3), 441.
22. [22]
  (22) Liu, X. Y.; Yi, C. L.; Zhu, Y.; Yang, Y. Q.; Jiang, J. Q.; Cui, Z.G.; Jiang, M. J. Colloid Interface Sci. 2010, 351, 315. doi: 10.1016/j.jcis.2010.04.056
23. [23]
  (23) Jiang, J. Q.; Feng, Y.;Wang, H. M.; Liu, X. Y.; Zhang, S.W.;Chen, M. Q. Acta Phys. -Chim. Sin. 2008, 24 (11), 2089. [江金强, 冯艳, 王红梅, 刘晓亚, 张胜文, 陈明清. 物理化学学报,2008, 24 (11), 2089.] doi: 10.3866/PKU.WHXB20081126
24. [24]
  (24) Yi, C. L.; Liu, N.; Zheng, J. C.; Jiang, J. Q.; Liu, X. Y. J. Colloid Interface Sci. 2008, 380, 90.
25. [25]
  (25) Gu, X. Y.; Yi, C. L.; Lu, Y. B.; Fan, C. H.; Jiang, J. Q.; Liu, X.Y. Adv. Eng. Res. 2010, 1, 87.
26. [26]
  (26) Choucair, A.; Eisenberg, A. Eur. Phys. J. E 2003, 10 (1), 37.doi: 10.1140/epje/e2003-00002-5
27. [27]
  (27) Melle, S.; Lask, M.; Fuller, G. G. Langmuir 2005, 21, 2158. doi: 10.1021/la047691n
1. [1]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
2. [2]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
3. [3]
  Shihui Shi , Haoyu Li , Shaojie Han , Yifan Yao , Siqi Liu . Regioselectively Synthesis of Halogenated Arenes via Self-Assembly and Synergistic Catalysis Strategy. University Chemistry, 2024, 39(5): 336-344. doi: 10.3866/PKU.DXHX202312002
4. [4]
  Hongling Yuan , Jialin Xie , Jiawei Wang , Jixiang Zhao , Jiayan Liu , Qing Feng , Wei Qi , Min Liu . Cyclic Olefin Copolymer (COC): The Agile Vanguard in the Realm of Materials. University Chemistry, 2024, 39(7): 294-298. doi: 10.12461/PKU.DXHX202311041
5. [5]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
6. [6]
  Shipeng WANG , Shangyu XIE , Luxian LIANG , Xuehong WANG , Jie WEI , Deqiang WANG . Piezoelectric effect of Mn, Bi co-doped sodium niobate for promoting cell proliferation and bacteriostasis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1919-1931. doi: 10.11862/CJIC.20240094
7. [7]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
8. [8]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
9. [9]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
10. [10]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
11. [11]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
12. [12]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
13. [13]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
14. [14]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
15. [15]
  Qilu DU , Li ZHAO , Peng NIE , Bo XU . Synthesis and characterization of osmium-germyl complexes stabilized by triphenyl ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1088-1094. doi: 10.11862/CJIC.20240006
16. [16]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
17. [17]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
18. [18]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
19. [19]
  Wei Li , Ze Chang , Meihui Yu , Ying Zhang . Curriculum Ideological and Political Design of Piezoelectricity Measurement Experiments of Coordination Compounds. University Chemistry, 2024, 39(2): 77-82. doi: 10.3866/PKU.DXHX202308004
20. [20]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050

Get Citation

PDF

XML

Metrics

PDF Downloads(808)
Abstract views(1208)
HTML views(2)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142