Citation: DING Peng, XU You-Long, SUN Xiao-Fei. Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 293-297. doi: 10.3866/PKU.WHXB201211142 shu

Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries

DING Peng ^1,2,3 ,
XU You-Long ^1,2, ,
SUN Xiao-Fei ^1,2

1.
1 Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi’an 710049, P. R. China;
2 International Center for Dielectric Research, Xi'an Jiaotong University, Xi’an 71004
9. P. R. China;
3 Department of Power, Wuhan Ordnance Non-Commissioned Officer Academy, Wuhan 430075, P. R. China

Received Date: 10 September 2012
Available Online: 14 November 2012

Transition metal oxides, especially manganese monoxide (MnO), are being intensively studied as candidate anode materials for next generation lithium-ion batteries in high efficiency energy storage applications such as portable electronics, electric vehicles, and stationary electricity storage. In this paper, the MnC₂O₄·2H₂O precursor, prepared fromKMnO4 and ascorbic acid, was heat-treated to synthesize nano MnO by a solid-state reaction approach. X-ray diffraction (XRD) showed that the so-obtained MnO had a rock-salt structure with od crystallinity, and scanning electron microscopy (SEM) indicated that the primary particle size was about 50-100 nm, while the secondary particle size was about 400-600 nm. As an active material for lithium-ion batteries, the nano MnO material delivered a reversible capacity of 679.7 mAh·g^-1 with an initial columbic efficiency of 68.9% at a current density of 46.3 mA·g^-1. The specific discharge capacity slightly decreased from 584.5 to 581.5 mAh·g^-1 with a retention of 99.5% after 50 cycles at a current density of 141.1 mA·g^-1. Moreover, the material was able to release a capacity of 290 mAh·g^-1 at current densities as high as 494.7 mA·g^-1 (corresponding to ~2C), which demonstrates reasonable rate performance and moderately fast charge/discharge capabilities. All of the above characteristics make nano MnO promising anode materials for developing high-capacity, long-life, low-cost, and environmentally-friendly lithium-ion batteries.
- Manganese monoxide,
- Nano material,
- Conversion reaction,
- Lithium-ion battery,
- Anode material
1. [1]
  
  (1) Wang, B.;Wu, X. L.; Shu, C. Y.; Guo, Y. G.;Wang, C. R.Journal of Materials Chemistry 2010, 20, 10661. doi: 10.1039/c0jm01941k
2. [2]
  (2) Guo, Y. G.; Hu, Y. S.; Sigle,W.; Maier, J. Advanced Materials2007, 19, 2087.
3. [3]
  (3) Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Advanced Materials2010, 22, E28.
4. [4]
  (4) Li, H.;Wang, Z.; Chen, L.; Huang, X. Advanced Materials2009, 21, 4593. doi: 10.1002/adma.v21:45
5. [5]
  (5) Maier, J. Nat. Mater 2005, 4, 805. doi: 10.1038/nmat1513
6. [6]
  (6) Poizot, P.; Laruelle, S.; Grugeon, S.; Dupont, L.; Tarascon, J. M.Nature 2000, 407, 496. doi: 10.1038/35035045
7. [7]
  (7) Li, H.; Balaya, P.; Maier, J. Journal of the Electrochemical Society 2004, 151, A1878.
8. [8]
  (8) Wang, H.; Pan, Q.; Zhao, J.; Chen,W. Journal of Alloys and Compounds 2009, 476, 408. doi: 10.1016/j.jallcom.2008.09.013
9. [9]
  (9) Tang, X.; Pan, Q.; Liu, J. Journal of the Electrochemical Society2010, 157, A55.
10. [10]
  (10) Yu, X. Q.; He, Y.; Sun, J. P.; Tang, K.; Li, H.; Chen, L. Q.;Huang, X. J. Electrochemistry Communications 2009, 11, 791.doi: 10.1016/j.elecom.2009.01.040
11. [11]
  (11) Poizot, P.; Laruelle, S.; Grugeon, S.; Tarascon, J. M. Journal of the Electrochemical Society 2002, 149, A1212.
12. [12]
  (12) Zhong, K.; Xia, X.; Zhang, B.; Li, H.;Wang, Z.; Chen, L.Journal of Power Sources 2010, 195, 3300. doi: 10.1016/j.jpowsour.2009.11.133
13. [13]
  (13) Zhong, K.; Zhang, B.; Luo, S.;Wen,W.; Li, H.; Huang, X.;Chen, L. Journal of Power Sources 2011, 196, 6802. doi: 10.1016/j.jpowsour.2010.10.031
14. [14]
  (14) Ding, Y. L.;Wu, C. Y.; Yu, H. M.; Xie, J.; Cao, G. S.; Zhu, T. J.;Zhao, X. B.; Zeng, Y.W. Electrochimica Acta 2011, 56, 5844.doi: 10.1016/j.electacta.2011.04.071
15. [15]
  (15) Li, X.; Li, D.; Qiao, L.;Wang, X.; Sun, X.;Wang, P.; He, D.Journal of Materials Chemistry 2012, 22, 9189. doi: 10.1039/c2jm30604b
16. [16]
  (16) Sun, B.; Chen, Z.; Kim, H. S.; Ahn, H.;Wang, G. Journal of Power Sources 2011, 196, 3346. doi: 10.1016/j.jpowsour.2010.11.090
17. [17]
  (17) Ban, C.;Wu, Z.; Gillaspie, D. T.; Chen, L.; Yan, Y.; Blackburn,J. L.; Dillon, A. C. Advanced Materials 2010, 22, E145.
18. [18]
  (18) Mai, Y. J.; Tu, J. P.; Xia, X. H.; Gu, C. D.;Wang, X. L. Journal of Power Sources 2011, 196, 6388. doi: 10.1016/j.jpowsour.2011.03.089
19. [19]
  (19) Delmer, O.; Balaya, P.; Kienle, L.; Maier, J. Advanced Materials2008, 20, 501.
20. [20]
  (20) Lou, X.W.; Deng, D.; Lee, J. Y.; Feng, J.; Archer, L. A.Advanced Materials 2008, 20, 258.
21. [21]
  (21) Cheng, F.; Huang, K. L.; Liu, S. Q.; Fang, X.S.; Zhang, X. Acta Phys. -Chim. Sin. 2011, 27, 1439. [程凤, 黄可龙, 刘素琴,房雪松, 张新. 物理化学学报, 2011, 27, 1439.] doi: 10.3866/PKU.WHXB20110607
22. [22]
  (22) Balaya, P.; Li, H.; Kienle, L.; Maier, J. Advanced Functional Materials 2003, 13, 621.
23. [23]
  (23) Jamnik, J.; Maier, J. Physical Chemistry Chemical Physics2003, 5, 5215.
24. [24]
  (24) Kokubu, T.; Oaki, Y.; Hosono, E.; Zhou, H.; Imai, H. Advanced Functional Materials 2011, 21, 3673. doi: 10.1002/adfm.201101138
25. [25]
  (25) Liu, Y.; Zhao, X.; Li, F.; Xia, D. Electrochimica Acta 2011, 56,6448. doi: 10.1016/j.electacta.2011.04.133
26. [26]
  (26) Gao,W. C.; Huang, T.; Shen, Y. D.; Yu, A. S. Acta Phys. -Chim. Sin. 2011, 27, 2129. [高文超, 黄桃, 沈宇栋, 余爱水. 物理化学学报, 2011, 27, 2129.] doi: 10.3866/PKU.WHXB20110933
1. [1]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
2. [2]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
3. [3]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
4. [4]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
5. [5]
  Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
6. [6]
  Yuting ZHANG , Zunyi LIU , Ning LI , Dongqiang ZHANG , Shiling ZHAO , Yu ZHAO . Nickel vanadate anode material with high specific surface area through improved co-precipitation method: Preparation and electrochemical properties. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2163-2174. doi: 10.11862/CJIC.20240204
7. [7]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
8. [8]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
9. [9]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
10. [10]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
11. [11]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
12. [12]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
13. [13]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
14. [14]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137
15. [15]
  Juan Yuan , Bin Zhang , Jinping Wu , Mengfan Wang . Design of a Comprehensive Experiment on Preparation and Characterization of Cu₂(Salen)₂ Nanomaterials with Two Distinct Morphologies. University Chemistry, 2024, 39(10): 420-425. doi: 10.3866/PKU.DXHX202402014
16. [16]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
17. [17]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
18. [18]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
19. [19]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
20. [20]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223

Get Citation

PDF

XML

Metrics

PDF Downloads(1091)
Abstract views(1616)
HTML views(69)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142