Citation: DING Peng, XU You-Long, SUN Xiao-Fei. Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2013, 29(02): 293-297. doi: 10.3866/PKU.WHXB201211142 shu

Synthesis and Performance of Nano MnO as an Anode Material for Lithium-Ion Batteries

DING Peng ^1,2,3 ,
XU You-Long ^1,2, ,
SUN Xiao-Fei ^1,2

1.
1 Electronic Materials Research Laboratory, Key Laboratory of the Ministry of Education, Xi'an Jiaotong University, Xi’an 710049, P. R. China;
2 International Center for Dielectric Research, Xi'an Jiaotong University, Xi’an 71004
9. P. R. China;
3 Department of Power, Wuhan Ordnance Non-Commissioned Officer Academy, Wuhan 430075, P. R. China

Received Date: 10 September 2012
Available Online: 14 November 2012

Transition metal oxides, especially manganese monoxide (MnO), are being intensively studied as candidate anode materials for next generation lithium-ion batteries in high efficiency energy storage applications such as portable electronics, electric vehicles, and stationary electricity storage. In this paper, the MnC₂O₄·2H₂O precursor, prepared fromKMnO4 and ascorbic acid, was heat-treated to synthesize nano MnO by a solid-state reaction approach. X-ray diffraction (XRD) showed that the so-obtained MnO had a rock-salt structure with od crystallinity, and scanning electron microscopy (SEM) indicated that the primary particle size was about 50-100 nm, while the secondary particle size was about 400-600 nm. As an active material for lithium-ion batteries, the nano MnO material delivered a reversible capacity of 679.7 mAh·g^-1 with an initial columbic efficiency of 68.9% at a current density of 46.3 mA·g^-1. The specific discharge capacity slightly decreased from 584.5 to 581.5 mAh·g^-1 with a retention of 99.5% after 50 cycles at a current density of 141.1 mA·g^-1. Moreover, the material was able to release a capacity of 290 mAh·g^-1 at current densities as high as 494.7 mA·g^-1 (corresponding to ~2C), which demonstrates reasonable rate performance and moderately fast charge/discharge capabilities. All of the above characteristics make nano MnO promising anode materials for developing high-capacity, long-life, low-cost, and environmentally-friendly lithium-ion batteries.
- Manganese monoxide,
- Nano material,
- Conversion reaction,
- Lithium-ion battery,
- Anode material
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