Citation: ZHU Jun, ZHANG Yao-Hong, HU Lin-Lua, DAI Song-Yuan. Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 89-94. doi: 10.3866/PKU.WHXB201211092 shu

Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance

1.
1 Key Lab of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei, 230031, P. R. China;
2 Key Lab of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received Date: 9 October 2012
Available Online: 9 November 2012
Fund Project: 国家重点基础研究发展规划(973)(2011CBA00700) (973)(2011CBA00700) 国家高技术研究发展计划(863)(2011AA050527) (863)(2011AA050527)国家自然科学基金(21003130, 21103197, 21173227, 21173228)资助项目 (21003130, 21103197, 21173227, 21173228)

In₂S₃ is a stable semiconductor material with low toxicity. We prepared In₂S₃ sensitized solar cells using low-cost chemical bath deposition methodology. X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscopy (SEM) were used to reveal the microstructure of the In₂S₃ sensitized TiO₂ nanoporous films. Our results indicated that the deposition temperature has a remarkable effect on the morphology of In₂S₃ sensitized TiO₂ films, which in turn affects the photovoltaic performance of devices. When the deposition temperature was low, the deposition reaction rate was slow, resulting in only minimal deposition. However, if the deposition temperature was increased too much, there was insufficient time for the In₂S₃ to be deposited within the internal pore structure of the TiO₂ mesoporous films. The best homogeneous In₂S₃ sensitized TiO₂ films were obtained with a deposition temperature of 40℃. At this temperature, the optical absorption of the resulting film was optimal and displayed the largest short circuit current density among the films examined. Moreover, the fill factor was also the best, approaching 65%. The best overall power conversion efficiency was 0.32%.
- Indium sulfide,
- Sensitization,
- Solar cell,
- Chemical bath depostion,
- Recombination
1. [1]
  
  (1) Hodes, G. J. Phys. Chem. C 2008, 112, 17778. doi: 10.1021/jp803310s
2. [2]
  (2) Kamat, P. V. J. Phys. Chem. C 2008, 112, 18737. doi: 10.1021/jp806791s
3. [3]
  (3) Kamat, P. V.; Tvrdy, K.; Baker, D. R.; Radich, J. G. Chem. Rev.2010, 110, 6664. doi: 10.1021/cr100243p
4. [4]
  (4) Mora-Serö, I.; Bisquert, J. J. Phys. Chem. Lett. 2010, 1, 3046.doi: 10.1021/jz100863b
5. [5]
  (5) Semonin, O.; Luther, J. M.; Choi, S.; Chen, H. Y.; Gao, J.;Nozik, A. J.; Beard, M. C. Science 2011, 334, 1530. doi: 10.1126/science.1209845
6. [6]
  (6) Rühle, S.; Shalom, M.; Zaban, A. ChemPhysChem 2010, 11,2290. doi: 10.1002/cphc.201000069
7. [7]
  (7) Shi, J. F.; Fan, Y.; Xu, X. Q.; Xu, G.; Chen, L. H. Acta Phys. -Chim. Sin. 2012, 28, 857. [史继富, 樊晔, 徐雪青,徐刚, 陈丽华. 物理化学学报, 2012, 28, 857.] doi: 10.3866/PKU.WHXB201202204
8. [8]
  (8) Liu, Y.; Xu. H. Y.; Qian, Y. T. Crystal Growth & Design 2006, 6,1304. doi: 10.1021/cg0504298
9. [9]
  (9) Hodes, G.; Cahen, D. Accounts Chem. Res. 2012, 45, 705. doi: 10.1021/ar200219h
10. [10]
  (10) Qiu,W. M.; Xu, M. S.; Yang, X.; Chen, F.; Nan, Y. X.; Zhang, J.L.; Iwai, H.; Chen, H. Z. J. Mater. Chem. 2011, 21, 13327. doi: 10.1039/C1JM11616A
11. [11]
  (11) Hara, K.; Sayama, K.; Arakawa, H. Solar Energy Mater. Solar Cells 2000, 62, 441. doi: 10.1016/S0927-0248(00)00027-1
12. [12]
  (12) Sarkar, S. K.; Kim, J. Y.; ldstein, D. N.; Neale, N. R.; Zhu,K.; Elliott, C. M.; Frank, A. J.; George, S. M. J. Phys. Chem. C.2010, 114, 8032. doi: 10.1021/jp9086943
13. [13]
  (13) Gan, X.; Li, X.; Gao, X.; Qiu, J.; Zhuge, F. Nanotechnology2011, 22, 305601. doi: 10.1088/0957-4484/22/30/305601
14. [14]
  (14) Hu, L. H.; Dai, S. Y.;Weng, J.; Xiao, S. F.; Sui, Y. F.; Huang, Y.;Chen, S. H.; Kong, F. T.; Pan, X.; Liang, L. Y.;Wang, K. J.J. Phys. Chem. B 2007, 111, 358. doi: 10.1021/jp065541a
15. [15]
  (15) Zhang, Y.; Zhu, J.; Yu, X.;Wei, J.; Hu, L.; Dai, S. Solar Energy2012, 86, 964. doi: 10.1016/j.solener.2012.01.006
16. [16]
  (16) Rengaraj, S.; Venkataraj, S.; Tai, C.W.; Kim, Y.; Repo, E.;Sillanpaa, M. Langmuir 2011, 27, 5534. doi: 10.1021/la104780d
17. [17]
  (17) Chai, B.; Peng, T. Y.; Zeng, P.; Mao, J. J. Mater. Chem. 2011,21, 14587. doi: 10.1039/C1JM11566A
18. [18]
  (18) Kaufmann, C.; Bayon, R.; Bohne,W.; Röhrich, J.; Klenk, R.;Dobson, P. J. J Electro. Soc. 2002, 149, C1. doi: 10.1149/1.1419183
19. [19]
  (19) Mora-Serö, I.; Giménez, S.; Fabregat-Santia , F.; Gémez, R.;Shen, Q.; Toyoda, T.; Bisquert, J. Accounts Chem. Res. 2009,42, 1848. doi: 10.1021/ar900134d
20. [20]
  (20) Chakrapani, V.; Baker, D.; Kamat, P. V. J. Am. Chem. Soc. 2011,133, 967. doi: 10.1021/ja203131b
21. [21]
  (21) Hod, I.; Tachan, Z.; Shalom, M.; Zaban, A. J. Phys. Chem. Lett.2011, 2, 1032. doi: 10.1021/jz200399n
22. [22]
  (22) Zhang, Q. B.; Feng, Z. F.; Han, N. N.; Lin, L. L.; Zhou, J. Z.;Lin, Z. H. Acta Phys. -Chim. Sin. 2010, 26, 2927. [张桥保, 冯增芳, 韩楠楠, 林玲玲, 周剑章, 林仲华. 物理化学学报, 2010,26, 2927.] doi: 10.3866/PKU.WHXB20101113
23. [23]
  (23) Diguna, L. J.; Shen, Q.; Kobayashi, J.; Toyoda, T. Appl. Phys. Lett. 2007, 91, 023116. doi: 10.1063/1.2757130
24. [24]
  (24) Shen, Q.; Kobayashi, J.; Diguna, L. J.; Toyoda, T. J. Appl. Phys.2008, 103, 084304. doi: 10.1063/1.2903059
25. [25]
  (25) nzález-Pedro, V.; Xu, X.; Mora-Seró, I.; Bisquert, J. ACS Nano 2010, 4, 5783. doi: 10.1021/nn101534y
26. [26]
  (26) Musselman, K. P.; Marin, A.; Schmidt-Mende, L.;MacManus-Driscoll, J. L. Adv. Funct. Mater. 2012, 22, 2202.doi: 10.1002/adfm.201102263
27. [27]
  (27) Boix, P. P.; Lee, Y. H.; Fabregat-Santia , F.; Im, S. H.;Mora-Serö, I.; Bisquert, J.; Seok, S., II. ACS Nano 2012, 6, 873.doi: 10.1021/nn204382k
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Preparation of In₂S₃ Sensitized Solar Cells with Chemical Bath Deposition and Their Performance