Citation: LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang. Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 111-116. doi: 10.3866/PKU.WHXB201211091 shu

Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification

1.
Institute of Materials Electrochemistry Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, Liaoning Province, P.R. China

Received Date: 6 August 2012
Available Online: 9 November 2012
Fund Project: 国家自然科学基金(51102126) (51102126) 教育部留学回国基金(2011508) (2011508) 辽宁省高等学校杰出青年学者成长计划(LJQ2011024, LJQ2012026) (LJQ2011024, LJQ2012026)辽宁省教育厅基金(L2010197)资助项目 (L2010197)

Nitrogen-doped carbon nanotubes (NCNTs) were prepared by carbonization of polyanilinecoated CNTs that were synthesized by in-situ polymerization of aniline on the CNT surface. The laser Raman spectroscopy, transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS) indicated that carbonization treatment of the polyaniline (PANI) coated CNTs produced NCNTs owning the core-shell structure of a nitrogen-doped carbon shell and a CNT core, without destroying the intrinsic CNT structure. By increasing the aniline amount, the N-doped layer of the NCNTs became thicker, and the amount of nitrogen doping increased from 7.06% to 8.64% (mass fraction). As the supercapacitor electrode material, the NCNTs capacitance in 6 mol·L^-1 aqueous KOH solution increased from 107 to 205 F·g^-1 as the N-doped layer thickness decreased, which was much higher than the capacitance of 10 F·g^-1 for the pristine CNTs. Especially, NCNT electrodes displayed od cyclability, maintaining 92.8%-97.1% of the initial capacitance after 1000 charge-discharge cycles. The high capacitance and od cyclability of the NCNTs as a supercapacitor electrode material can be attributed to the pseudo-Faradic capacitance and improved hydrophility contributed by the nitrogen functional groups and the core-shell structure of the NCNTs, respectively.
- Carbon nanotubes,
- Nitrogen doping,
- Polyaniline,
- Supercapacitor
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