Citation: LI Li-Xiang, TAO Jing, GENG Xin, AN Bai-Gang. Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 111-116. doi: 10.3866/PKU.WHXB201211091 shu

Preparation and Supercapacitor Performance of Nitrogen-Doped Carbon Nanotubes from Polyaniline Modification

1.
Institute of Materials Electrochemistry Research, School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, Liaoning Province, P.R. China

Received Date: 6 August 2012
Available Online: 9 November 2012
Fund Project: 国家自然科学基金(51102126) (51102126) 教育部留学回国基金(2011508) (2011508) 辽宁省高等学校杰出青年学者成长计划(LJQ2011024, LJQ2012026) (LJQ2011024, LJQ2012026)辽宁省教育厅基金(L2010197)资助项目 (L2010197)

Nitrogen-doped carbon nanotubes (NCNTs) were prepared by carbonization of polyanilinecoated CNTs that were synthesized by in-situ polymerization of aniline on the CNT surface. The laser Raman spectroscopy, transmission electron microscope (TEM), and X-ray photoelectron spectroscopy (XPS) indicated that carbonization treatment of the polyaniline (PANI) coated CNTs produced NCNTs owning the core-shell structure of a nitrogen-doped carbon shell and a CNT core, without destroying the intrinsic CNT structure. By increasing the aniline amount, the N-doped layer of the NCNTs became thicker, and the amount of nitrogen doping increased from 7.06% to 8.64% (mass fraction). As the supercapacitor electrode material, the NCNTs capacitance in 6 mol·L^-1 aqueous KOH solution increased from 107 to 205 F·g^-1 as the N-doped layer thickness decreased, which was much higher than the capacitance of 10 F·g^-1 for the pristine CNTs. Especially, NCNT electrodes displayed od cyclability, maintaining 92.8%-97.1% of the initial capacitance after 1000 charge-discharge cycles. The high capacitance and od cyclability of the NCNTs as a supercapacitor electrode material can be attributed to the pseudo-Faradic capacitance and improved hydrophility contributed by the nitrogen functional groups and the core-shell structure of the NCNTs, respectively.
- Carbon nanotubes,
- Nitrogen doping,
- Polyaniline,
- Supercapacitor
1. [1]
  
  (1) Dresselhaus, M. S.; Dresselhaus, G.; Eklund, P. C. Science of Fullerenes & Carbon Nanotubes; San Die : Academic Press,March 1996; pp 20-35.
2. [2]
  (2) Treacy, M. M. J.; Ebbesen, T.W.; Gibson, J. M. Nature 1996,381, 678. doi: 10.1038/381678a0
3. [3]
  (3) Frackowiak, E.; Metenier, K.; Bertagna, V.; Beguin, F. Appl. Phys. Lett. 2000, 77, 2421. doi: 10.1063/1.1290146
4. [4]
  (4) Li, C. S.;Wang, D. Z.;Wang, X. F.; Liang, J. Carbon 2005, 43,249.
5. [5]
  (5) Baughman, R. H.; Zakhidov, A. A.; de Heer,W. A. Science2002, 297, 787. doi: 10.1126/science.1060928
6. [6]
  (6) Shiratori, Y.; Sugime, H.; Noda, S. J. Phys. Chem. C 2008, 112,17974.
7. [7]
  (7) Hou, P. X.; Orikasa, H.; Yamazaki, T.; Matsuoka, K.; Tomita,A.; Setoyama, N.; Fukushima, Y.; Kyotani, T. Chem. Mater.2005, 1, 5187.
8. [8]
  (8) Eduardo, C. S.; Florentino, L. U.; Emilio, M. S. ACS Nano2009, 3, 1913. doi: 10.1021/nn900286h
9. [9]
  (9) Yang, Y.; Li, X.; Jiang, J.; Du, H.; Zhao, L.; Zhao, Y. ACS. Nano 2010, 4, 5755. doi: 10.1021/nn1014825
10. [10]
  (10) Byrne, J.; Li, Z.; Jones, S.; Fleming, P.; Larsson, J. A.; Morris,M. A.; Holmes, J. D. ChemPhysChem. 2011, 12, 2995. doi: 10.1002/cphc.v12.16
11. [11]
  (11) Liu, Y.; Jin, Z.;Wang, Y.; Cui, R. L.; Sun, H.; Peng, F.;Wei, L.;Wang, Z. X.; Liang, X. L.; Peng, L. M.; Li, Y. Adv. Funct. Mater. 2011, 21, 986. doi: 10.1002/adfm.201002086
12. [12]
  (12) Hulicova-Jurcakova, D.; Kodama, M.; Shiraishi, S.; Hatori, H.;Zhu, Z. H.; Lu, G. Q. Adv. Funct. Mater. 2009, 19, 1800. doi: 10.1002/adfm.v19:11
13. [13]
  (13) Inagakia, M.; Konno, H.; Tanaike, O. J. Power Sources 2010,195, 7880.
14. [14]
  (14) Lota, G.; Grzyb, B.; Machnikowsk, H.; Machnikowski, J.;Frackowiak, E. Chem Phys. Lett. 2005, 404, 53. doi: 10.1016/j.cplett.2005.01.074
15. [15]
  (15) Zhai, Y. P.; Dou, Y. Q.; Zhao, D. Y.; Fulvio, P. F.; Mayes, R. T.;Dai, S. Adv. Mater. 2011, 23, 4828. doi: 10.1002/adma.v23.42
16. [16]
  (16) ng, K.; Du, F.; Xia, Z.; Durstock, M.; Dai, L. Science 2009,323, 760. doi: 10.1126/science.1168049
17. [17]
  (17) Tang, Y.; Allen, B. L.; Kauffman, D. R.; Alexander, S. J. Am. Chem. Soc. 2009, 131, 13200. doi: 10.1021/ja904595t
18. [18]
  (18) Yang, S.; Zhao, G. L.; Khosravi, E. J. Phys. Chem. C 2010, 114,3371.
19. [19]
  (19) Sen, R.; Satishkumar, B. C.; vindaraj, A.; Harikumar, K. R.;Renganathan, M. K.; Rao, C. N. R. J. Mater. Chem. 1997, 7,2335. doi: 10.1039/a705891h
20. [20]
  (20) Shirazi, Y.; Tofighy, M. A.; Mohammadi, T.; Pak, A. Appl. Sur. Sci. 2011, 257, 7359. doi: 10.1016/j.apsusc.2011.03.146
21. [21]
  (21) Liu, J.; Rinzler, A. G.; Dai, H. J.; Hafner, J. H.; Bradley, R. K.;Boul, P. J.; Lu, A.; Iverson, T.; Shelimov, K.; Huffman, C. B.;Rodriguez-Macias, F.; Shon, Y. S.; Lee, T. R.; Colbert, D. T.;Smalley, R. E. Science 1998, 280, 1253. doi: 10.1126/science.280.5367.1253
22. [22]
  (22) Hiura, H.; Ebbesen, T.W.; Tanigaki, K. Adv. Mater. 1995, 7,275.
23. [23]
  (23) Arri , R.; Havecker, M.; Schlogl, R.; Su, D. S. Chem. Commun. 2008, 4891.
24. [24]
  (24) Halder, A.; Sharma, S.; Hegde, M. S.; Ravishankar, N. J. Phys. Chem. C 2009, 113, 1466. doi: 10.1021/jp8072574
25. [25]
  (25) Tessonnier, J. P.; Rosenthal, D.; Girgsdies, F.; Amadou, J.;Begin, D.; Pham-Huu, C.; Su, D. S.; Schlogl, R. Chem. Commun. 2009, 7158.
26. [26]
  (26) Li, L. X.; Liu, Y. C.; Geng, X.; An, B. G. Acta Phys. -Chim. Sin.2011, 27, 443. [李莉香, 刘永长, 耿新, 安百刚. 物理化学学报, 2011, 27, 443.] doi: 10.3866/PKU.WHXB20110225
27. [27]
  (27) Niwa,H.;Horiba,K.;Harada,Y.;Oshima,M.; Ikeda, T.; Terakura,K.; Ozaki, J. I.; Miyata, S. J. Power Sources 2009, 187, 93.doi: 10.1016/j.jpowsour.2008.10.064
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