Citation: GU Lai-Yuan, GAO Bao-Jiao, FANG Xiao-Lin. Characterization of Immobilized Composite Catalysts of Cationic Metalloporphyrin and Heteropoly Anion in Oxidation of Ethyl Benzene by Molecular Oxygen[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 191-198. doi: 10.3866/PKU.WHXB201210266 shu

Characterization of Immobilized Composite Catalysts of Cationic Metalloporphyrin and Heteropoly Anion in Oxidation of Ethyl Benzene by Molecular Oxygen

1.
Department of Chemical Engineering, North University of China, Taiyuan 030051, P. R. China

Received Date: 18 September 2012
Available Online: 26 October 2012
Fund Project: 山西省自然科学基金(2010021008-4)资助项目 (2010021008-4)

An immobilized cationic phenyl porphyrin was prepared with crosslinked polystyrene (CPS) microspheres as carriers via synthesis and immobilization. A kind of immobilized cationic cobalt porphyrin was obtained through a coordination reaction between the immobilized cationic phenyl porphyrin and the cobalt salt. In the composite reactions, phosphotungstic acid (HPW) and phosphomolybdic acid (HPMo) with Keggin structures were used as reagents, respectively, and the combination of the cationic cobalt porphyrin (CoP) with the heteropoly anions by electrostatic interaction led to the formation of the immobilized composite catalysts of CoPPW-CPS and CoPPMo-CPS. We then characterized these immobilized composite catalysts. The immobilized composite catalysts were used in the oxidation of ethylbenzene by molecular oxygen, and their catalytic characters were investigated. The results show that the immobilized composite catalysts possess high catalyst activity. They can transform ethyl benzene into acetophenone with high selectivity, and the yield of acetophenone after 12 h reaches 30.1%. The catalytic activity of the immobilized composite catalysts is 75% higher than that of the immobilized cobalt porphyrin. The catalytic activity of CoPPW-CPS is higher than that of CoPPMo-CPS. The cobalt porphyrin in the composite is the catalyst component as the heteropoly has no catalytic activity. However, the heteropoly anion has a protective effect on the metalloporphyrin against its deactivation during the catalytic reaction. In the oxidation reaction, there is an optimum addition for catalyst, and adding excessive catalyst inhibits its activity. The composite catalysts show od recycle properties.
- Cationic metalloporphyrin,
- Heteropolyacid,
- Composite catalyst,
- Immobilization,
- Ethylbenzene oxidation,
- Molecular oxygen
1. [1]
  
  (1) Rahiman, A. K.; Bharathi, K. S.; Sreedaran, S.; Rajesh, K.;Narayanan, V. Inorg. Chim. Acta 2009, 362, 1810. doi: 10.1016/j.ica.2008.08.019
2. [2]
  (2) Ma, J. J.;Wu, J.; Gu, J.; Liu, L.; Zhang, D. G.; Xu, X. Y.; Yang,X. J.; Tong, Z.W. J. Mol. Catal. A: Chem. 2012, 357, 95. doi: 10.1016/j.molcata.2012.01.025
3. [3]
  (3) Rahiman, A. K.; Rajesh, K.; Bharathi, K. S.; Sreedaran, S.;Narayanan, V. Appl. Catal. A: Gen. 2006, 314, 216. doi: 10.1016/j.apcata.2006.08.018
4. [4]
  (4) Machado, G. S.; Castro, K. A. D. F.;Wypych, F.; Nakagaki, S.J. Mol. Catal. A: Chem. 2008, 283, 99. doi: 10.1016/j.molcata.2007.12.009
5. [5]
  (5) Zhao, P.; Huang, J.W.; Ji, L. N. Spectrochim. Acta Part A 2012,88, 130. doi: 10.1016/j.saa.2011.12.017
6. [6]
  (6) Serwicka, E. M.; Poltowicz, J.; Bahranowski, K.; Olejniczak,Z.; Jones,W. Appl. Catal. A: Gen. 2004, 275, 9. doi: 10.1016/j.apcata.2004.07.005
7. [7]
  (7) Ye, T. X.; Ye, S. L.; Chen, D. M.; Chen, Q. A.; Qiu, B.; Chen, X.Spectrochim. Acta Part A 2012, 86, 467. doi: 10.1016/j.saa.2011.10.070
8. [8]
  (8) Moghadam, M.; Tangestaninejad, S.; Mirkhani, V.;Mohammadpoor-Baltork, I.; Moosavifaret, M. J. Mol. Catal. A: Chem. 2009, 302, 68. doi: 10.1016/j.molcata.2008.11.036
9. [9]
  (9) Rahiman, A. K.; Rajesh, K.; Bharathi, K. S.; Sreedaran, S.;Narayananet, V. Inorg. Chim. Acta 2009, 362, 1491. doi: 10.1016/j.ica.2008.07.011
10. [10]
  (10) Poltowicz, J.; Serwicka, E. M.; Bastardo- nzalez, E.; Jones,W.; Mokaya, R. Appl. Catal. A: Gen. 2001, 218, 211. doi: 10.1016/S0926-860X(01)00647-0
11. [11]
  (11) Vinhado, F. S.; Prado-Manso, C. M. C.; Sacco, H. C.; Iamamoto,Y. J. Mol. Catal. A: Chem. 2001, 174, 279. doi: 10.1016/S1381-1169(01)00200-X
12. [12]
  (12) Huang, G.; Guo, C. C.; Tang, S. S. J. Mol. Catal. A: Chem.2007, 261, 125. doi: 10.1016/j.molcata.2006.08.014
13. [13]
  (13) Mirkhani, V.; Moghadam, M.; Tangestaninejad, S.; Bahramian,B. Appl. Catal. A: Gen. 2006, 311, 43. doi: 10.1016/j.apcata.2006.05.043
14. [14]
  (14) Poltowicz, J.; Pamin, K.; Haber, J. J. Mol. Catal. A: Chem.2006, 257, 154. doi: 10.1016/j.molcata.2006.04.070
15. [15]
  (15) Halma, M.; Bail, A.;Wypych, F.; Nakagaki, S. J. Mol. Catal. A: Chem. 2006, 243, 44. doi: 10.1016/j.molcata.2005.08.019
16. [16]
  (16) Nakagaki, S.; Halma, M.; Bail, A.; Arízaga, G. G. C.;Wypych,F. J. Colloid Interface Sci. 2005, 281, 417. doi: 10.1016/j.jcis.2004.08.098
17. [17]
  (17) Kim, H.; Jung, J. C.; Park, D. R.; Baeck, S. H.; Song, I. K. Appl. Catal. A: Gen. 2007, 320, 159. doi: 10.1016/j.apcata.2007.01.034
18. [18]
  (18) Yuan, C. Y.; Chen, J. Chin. J. Catal. 2011, 32, 1191. doi: 10.1016/S1872-2067(10)60236-7
19. [19]
  (19) Gao, S. Y.; Cao, R.; Yan, C. P. J. Colloid Interface Sci. 2008,324, 156. doi: 10.1016/j.jcis.2008.05.011
20. [20]
  (20) Souza, A. L.; Marques, L. A.; Eberlin, M. N.; Nascente, P. A. P.;Junior, P. S. P. H.; Leite, F. L.; Rodrigues-Filho, U. P. Thin Solid Films 2012, 520, 3574. doi: 10.1016/j.tsf.2011.12.069
21. [21]
  (21) Gu, L. Y.; Gao, B. J.; Fang, X. L. Chemistry 2012, 75 (12),1114. [顾来沅, 高保娇, 房晓琳. 化学通报, 2012, 75 (12),1114.]
22. [22]
  (22) Santos, I. C. M. S.; Rebelo, S. L. H.; Balula, M. S. S.; Martins,R. R. L.; Pereira, M. M. M. S.; Simões, M. M. Q.; Neves, M. G.P. M. S.; Cavaleiro, J. A. S.; Cavaleiro, A. M. V. J. Mol. Catal. A: Chem. 2005, 231, 35. doi: 10.1016/j.molcata.2004.12.021
23. [23]
  (23) Haber, J.; Pamin, K.; Poltowicz, J. J. Mol. Catal. A: Chem.2004, 224, 153. doi: 10.1016/j.molcata.2004.07.031
24. [24]
  (24) Guo, C. C.; Chu, M. F.; Liu, Q.; Liu, Y.; Guo, D. C.; Liu, X. Q.Appl. Catal. A: Gen. 2003, 246, 303. doi: 10.1016/S0926-860X(03)00061-9
25. [25]
  (25) Tang, H.; Shen, C. G.; Lin, M. R.; Sen, A. Inorg. Chim. Acta2000, 300-302, 1109.
26. [26]
  (26) Kharat, A. N.; Pendleton, P.; Badalyan, A.; Abedini, M.; Amini,M. M. J. Mol. Catal. A: Chem. 2001, 175, 277. doi: 10.1016/S1381-1169(01)00234-5
27. [27]
  (27) Guo, C. C.; Liu, X. Q.; Liu, Y.; Liu, Q.; Chu, M. F.; Zhang, X.B. J. Mol. Catal. A: Chem. 2003, 192, 289. doi: 10.1016/S1381-1169(02)00449-1
28. [28]
  (28) Chen, Y. J.; Gao, B. J.; Tian, P.; Ma, Y. X. Acta Chim. Sin. 2011,69, 1337. [陈英军, 高保娇, 田鹏, 马云霞. 化学学报, 2011,69, 1337.]
29. [29]
  (29) Huang, G.; Luo, J.; Deng, C. C.; Guo, Y. A.; Zhao, S. K.; Zhou,H.;Wei, S. Appl. Catal. A: Gen. 2008, 338, 83. doi: 10.1016/j.apcata.2007.12.027
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