Citation: TAO Jing-Liang, XIONG Yuan-Quan. Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 205-211. doi: 10.3866/PKU.WHXB201210264 shu

Hydrogen Production from the Decomposition of Ethanol Aqueous Solution Using Glow Discharge Plasma Electrolysis

1.
Key Laboratory for Energy of Heat Conversion and its Process of Measurement and Control, School of Energy and Environment, SouthEast University, Nanjing, 210096, P. R. China

Received Date: 5 September 2012
Available Online: 26 October 2012
Fund Project: 国家重点基础研究发展规划项目(973) (2010CB227002-02) (973) (2010CB227002-02)国家高技术研究发展计划项目(863) (2011AA05A201)资助 (863) (2011AA05A201)

High-energy electrons play the most important role in the decomposition of ethanol aqueous solutions under glow discharge plasma electrolysis (GDE). The non-Faradaic currents greatly improve, resulting in the actual gas production yield exceeding the theoretical yield. In this paper, we investigated a novel process of hydrogen generation from ethanol decomposition by GDE. The main gaseous products were H₂ and CO; in addition to small amounts of C₂H₄, CH₄, O₂, and C₂H₆. The H₂ volume fraction was above 59% and CO was 20%. We conclude that voltages of points C and D (V_C and V_D) do not change with the electrolyte concentration, but the 'Kellogg area' becomes narrower with increasing electrolyte conductivity and the glow discharge is easier to attain. In addition, with increasing ethanol volume fraction, the H₂ volume fraction decreases. The maximum gas production rate occurred for ethanol volume fractions of 30% and 80%. Improving the discharge voltage and raising the electrolyte conductivity had the same effect on glow discharge plasma electrolysis as the voltage load at both ends of the plasma steam sheath increases. The H₂ volume fraction remains the same upon varying the discharge voltage or electrolyte conductivity, but increasing the electrolyte conductivity is advantageous to reduce Joule heating effects caused by GDE.
- Glow discharge electrolysis,
- Gas generation rate,
- Electrolyte,
- Ethanol,
- Steam sheath,
- Hydrogen generation
1. [1]
  
  (1) Yan, Z. C.; Chen, L.;Wang, H. L. Acta Phys. -Chim. Sin. 2007,23, 835. [严宗诚, 陈砺, 王红林. 物理化学学报, 2007, 23,835.] doi: 10.3866/PKU.WHXB20070608
2. [2]
  (2) Sengupta, S. K.; Singh, O. P. J. Electroanal. Chem. 1994, 369,113. doi: 10.1016/0022-0728(94)87089-6.
3. [3]
  (3) Gao, J. Z.;Wang, X. Y.; Hu, Z. A.; Hou, J. G.; Lu, Q. F. Plasma Sci. Technol. 2001, 3, 765. doi: 10.1088/1009-0630/3/3/003
4. [4]
  (4) Sengupta, S. K.; Singh, R.; Srivastva, A. K. J. Electrochem. Soc.1998, 145, 2209. doi: 10.1149/1.1838621
5. [5]
  (5) Kuznetsova, N. I.; Kuznetsova, L. I.; Likholobov, V. A.; Pez, G.P. Catal. Today 2005, 99, 193. doi: 10.1016/j.cattod.2004.09.040
6. [6]
  (6) Sengupta, S. K.; Sandhir, U.; Misra, N. J. Polym. Sci. Part A: Polym. Chem. 2001, 39, 1584. doi: 10.1002/pola.1134
7. [7]
  (7) ng, J. Y.;Wang, J.; Xie,W. J.; Cai,W. M. J. Appl. Electrochem. 2008, 38, 1749. doi: 10.1007/s10800-008-9626-z
8. [8]
  (8) Yang, H.; Matsumoto, Y.; Tezuka, M. J. Environ. Sci. 2009, 21 (Suppl. 1), 142. doi: 10.1016/S1001-0742(09)60059-0
9. [9]
  (9) Campbell, S. A.; Cunnane, V. J.; Schiffrin, D. J. J. Eletroanal. Soc. 1992, 325, 257. doi: 10.1016/0022-0728(92)80117-M
10. [10]
  (10) Pei, M. X.; Lin, H.; Shangguan,W. F.; Huang, Z. Acta Phys. -Chim. Sin. 2005, 21, 255. [裴梅香, 林赫, 上官文峰,黄震. 物理化学学报, 2005, 21, 255.] doi: 10.3866/PKU.WHXB20050306
11. [11]
  (11) Yu, Q. Q.; Liu, T.;Wang, H.; Xiao, L. P.; Chen, M.; Jiang, X. Y.;Zheng, X. M. Chin. J. Catal. 2012, 33, 783. [于琴琴, 刘彤,王卉, 肖丽萍, 陈敏, 蒋晓原, 郑小明. 催化学报, 2012, 33,783.] doi: 10.1016/S1872-2067(11)60362-8
12. [12]
  (12) Sengupta, S. K.; Rajeshwar, S.; Ashok, K. S. J. Electroanal. Chem. 1997, 427, 23. doi: 10.1016/S0022-0728(96)05044-9
13. [13]
  (13) Hickling, A.; Ingram, M. D. Trans. Faraday Soc. 1964, 60, 783.doi: 10.1039/TF9646000783
14. [14]
  (14) Mandin, P.; Aissa, A. A.; Roustan, H.; Hamburger, J.; Picard, G.Chem. Eng. Process. 2008, 47, 1926. doi: 10.1016/j.cep.2007.10.018
15. [15]
  (15) Mandin, P.; Le Graverend, J. B.;Wuthrich, R.; Roustan, H.ECS Trans. 2009, 16, 49. doi: 10.1149/1.3104647
16. [16]
  (16) Jin, X. L.;Wang, X. Y.; Zhang, H. M.; Xia, Q.;Wei, D. B.; Yue,J. J. Plasma Chem. Plasma Process. 2010, 30, 429. doi: 10.1007/s11090-010-9220-0
17. [17]
  (17) Jin, X. L.;Wang, X. Y.; Yun, J. J.; Cai, Y. Q.; Zhang, H. Y.Electrochim. Acta 2010, 56, 925. doi: 10.1016/j.electactta.2010.09.079
18. [18]
  (18) Yan, Z. C.; Chen, L.;Wang, H. L. J. Phys. D: Appl. Phys. 2008,41, 1. doi: 10.1088/0022-3727/41/15/155205
19. [19]
  (19) Yan, Z. C.; Chen, L.;Wang, H. L. Int. J. Hydrog. Energy 2009,34, 48. doi: 10.1016/j.ijhydene.2008.09.099
20. [20]
  (20) Shen, P. K.;Wang, S. L.; Hu, Z. Y.; Li, Y. L.; Zeng, R.; Huang,Y. Q. Acta Phys. -Chim. Sin. 2007, 23, 107. [沈培康, 汪圣龙,胡智怡, 李永亮, 曾蓉, 黄岳强. 物理化学学报, 2007, 23,107.] doi: 10.3866/PKU.WHXB20070122
21. [21]
  (21) Zeng, K.; Zhang, D. K. Prog. Energy Combust. Sci. 2010, 36,307. doi: 10.1016/j.pecs. 2009.11.002
22. [22]
  (22) Holladay, J. D.; Hu, J.; King, D. L.;Wang, Y. Catal. Today2009, 139, 244. doi: 10.1016/j.cattod.2008.08.039
23. [23]
  (23) Wüthrich, R.; Mandin, P. Electrochim. Acta 2009, 54, 4031. doi: 10.1016/j.electacta. 2009.02.029
24. [24]
  (24) Franklin, R. N. J. Phys. D: Appl. Phys. 2003, 36, 309. doi: 10.1088/0022-3727/36/22/R01
25. [25]
  (25) Yan, Z. C. Hydrogen Generation by Glow Discharge PlasmaElectrolysis of Low Alcohol. Ph. D. Dissertation, South ChinaUniversity of Technology, Guangzhou, 2007. [严宗诚. 低碳醇溶液辉光放电电解及其制氢应用[D]. 广州: 华南理工大学,2007.]
26. [26]
  (26) Luo, Y. R. Handbook of Bond Dissociation Energies in Organic Compounds; Science Press: Beijing, 2005; pp 56-195. [罗渝然. 化学键能数据手册. 北京: 科学出版社, 2005: 56-195.]
1. [1]
  Tong Zhou , Liyi Xie , Chuyu Liu , Xiyan Zheng , Bao Li . Between Sobriety and Intoxication: The Fascinating Journey of Sauce-Flavored Latte. University Chemistry, 2024, 39(9): 55-58. doi: 10.12461/PKU.DXHX202312048
2. [2]
  Siwei Lv , Tantian Tan , Xinyue Li , Siyan Zhang , Mingyuan Zhang , Minghao Li , Hangshuo Guo , Zhaorong Li , Liangjie Dong , Fengshuo Zhang , Junlong Zhao . Competition of the “King of Transboundary Medicine”. University Chemistry, 2024, 39(9): 102-108. doi: 10.12461/PKU.DXHX202403034
3. [3]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
4. [4]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
7. [7]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
8. [8]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
9. [9]
  Xuanzhu Huo , Yixi Liu , Qiyu Wu , Zhiqiang Dong , Chanzi Ruan , Yanping Ren . Integrated Experiment of “Electrolytic Preparation of Cu₂O and Gasometric Determination of Avogadro’s Constant: Implementation, Results, and Discussion: A Micro-Experiment Recommended for Freshmen in Higher Education at Various Levels Across the Nation. University Chemistry, 2024, 39(3): 302-307. doi: 10.3866/PKU.DXHX202308095
10. [10]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
11. [11]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
12. [12]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
13. [13]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
14. [14]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
15. [15]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
16. [16]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
17. [17]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
18. [18]
  Jingzhao Cheng , Shiyu Gao , Bei Cheng , Kai Yang , Wang Wang , Shaowen Cao . 4-氨基-1H-咪唑-5-甲腈修饰供体-受体型氮化碳光催化剂的构建及其高效光催化产氢研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406026-. doi: 10.3866/PKU.WHXB202406026
19. [19]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
20. [20]
  Shuying Zhu , Shuting Wu , Ou Zheng . Improvement and Expansion of the Experiment for Determining the Rate Constant of the Saponification Reaction of Ethyl Acetate. University Chemistry, 2024, 39(4): 107-113. doi: 10.3866/PKU.DXHX202310117

Get Citation

PDF

XML

Metrics

PDF Downloads(931)
Abstract views(2513)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142