Citation: WANG Hong-Zhi, GAO Cui-Xia, ZHANG Peng, YAO Su-Wei, ZHANG Wei-Guo. Synthesis and Electrochemical Performance of Graphene/Polyaniline[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 117-122. doi: 10.3866/PKU.WHXB201210234 shu

Synthesis and Electrochemical Performance of Graphene/Polyaniline

  • Received Date: 24 August 2012
    Available Online: 24 October 2012

    Fund Project: 天津市自然科学基金(11JCYBJC01900)资助项目 (11JCYBJC01900)

  • Graphene/polyaniline composites (GP) were prepared from aniline and graphite oxide using an electrochemical method. The structure characterization and surface morphology were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS), and its electrochemical properties were measured. The results show that the composite keeps the basic morphology of graphene and that the polyaniline particles are uniformly dispersed. The specific capacitances of the composite materials reach 352 and 315 F·g-1 at 500 and 1000 mA·g-1, respectively, higher than those of graphene and polyaniline. The majority (90%) of the capacitance remains after 1000 cycles of charge and recharge at 1000 mA·g-1. The composite shows potential for use in supercapacitors.

  • 加载中
    1. [1]

      (1) Miller, J. R.; Outlaw, R. A.; Holloway, B. C. Science 2010, 329,1637. doi: 10.1126/science.1194372

    2. [2]

      (2) Chen, S. M. Preparation of Novel Carbon Materials and TheirApplication in Electrochemical Field. M. E. Dissertation,Beijing University of Chemical Technology, Beijing, 2010. [陈思明. 新型石墨材料的制备及其在电化学领域方面的应用[D]. 北京: 北京化工大学, 2010.]

    3. [3]

      (3) El-Kady, M. F.; Strong, V.; Dubin, S.; Kaner, R. B. Science2012, 335, 1326. doi: 10.1126/science.1216744

    4. [4]

      (4) Korenblit, Y.; Rose, M.; Kockrick, E.; Borchardt, L.; Kvit, A.;Kaskel, S.; Yushin, G. ACS Nano 2010, 4, 1337. doi: 10.1021/nn901825y

    5. [5]

      (5) Hantel, M. M.; Kaspar, T.; Nesper, R.;Wokaun, A.; Kotz, R.Electrochem. Commun. 2011, 13, 90. doi: 10.1016/j.elecom.2010.11.021

    6. [6]

      (6) Vickery, J. L.; Patil, A. J.; Mann, S. Adv. Mater. 2009, 21, 2180.doi: 10.1002/adma.v21:21

    7. [7]

      (7) Stoller, M. D.; Park, S. J.; Zhu, Y.W.; An, J. H.; Ruoff, R. S.Nano Lett. 2008, 8, 3498. doi: 10.1021/nl802558y

    8. [8]

      (8) Wang, D.W.; Li, F.; Zhao, J. P.; Ren,W. C.; Chen, Z. G.; Tan,J.;Wu, Z. S.; Gentle, L.; Lu, G. Q.; Cheng, H. M. ACS Nano2009, 3, 1745. doi: 10.1021/nn900297m

    9. [9]

      (9) Li, D.; Muller, M. B.; Gilje, S.; Kaner, R. B.;Wallance, G. G.Nat. Nanotechnol. 2008, 3, 101. doi: 10.1038/nnano.2007.451

    10. [10]

      (10) Xu, J. J.;Wang, K.; Zu, S. Z.; Han, B. H.;Wei, Z. X. ACS Nano2010, 4, 5019. doi: 10.1021/nn1006539

    11. [11]

      (11) Cheng, Q.; Tang, J.; Ma, J.; Zhang, H.; Shinya, N.; Qin, L. C.Carbon 2011, 49, 2917. doi: 10.1016/j.carbon.2011.02.068

    12. [12]

      (12) Zhang, K.; Mao, L.; Zhang, L. L.; Chan, H. S. O.; Zhao, X. S.;Wu, J. S. J. Mater. Chem. 2011, 21, 7302. doi: 10.1039/c1jm00007a

    13. [13]

      (13) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin. 2010, 26, 2073. [胡耀娟, 金娟, 张卉,吴萍, 蔡称心. 物理化学学报, 2010, 26, 2073.] doi: 10.3866/PKU.WHXB20100812

    14. [14]

      (14) Dong, P.; Zhou, J. Z.; Xi, Y. Y.; Cai, C. D.; Zhang, Y.; Zou, X.D.; Huang, H. G.;Wu, L. L.; Lin, Z. H. Acta Phys. -Chim. Sin.2004, 20, 454. [董平, 周剑章, 席燕燕, 蔡成东, 张彦, 邹旭东, 黄怀国, 吴玲玲, 林仲华. 物理化学学报, 2004, 20, 454.]doi: 10.3866/PKU.WHXB20040502

    15. [15]

      (15) Guo, L. H.;Wang, X. F.; Qian, Q. Y.;Wang, F. B.; Xia, X. H.ACS Nano 2009, 9, 2653.

    16. [16]

      (16) Zhou, M.;Wang, Y. L.; Zhai, Y. M.; Zhai, J. F.; Ren,W.;Wang,F. A.; Dong, S. J. Chem. Eur. J. 2009, 15, 6116. doi: 10.1002/chem.v15:25

    17. [17]

      (17) Shao, Y. Y.;Wang, J.; Engelhard, M.;Wang, C. M.; Lin, Y. H.J. Mater. Chem. 2010, 20, 743. doi: 10.1039/b917975e

    18. [18]

      (18) Liu, J. C. Synthesis and Study on Graphene and Co3O4/Graphene Composite about the Characteristic ofElectrochemistry. M. E. Dissertation, Harbin EngineeringUniversity, Harbin, 2011. [刘进程. 石墨烯和石墨烯基四氧化三钴复合物的制备及其电化学性能研究[D]. 哈尔滨: 哈尔滨工程大学, 2011.]

    19. [19]

      (19) Zhang, K.; Zhang, L. L.; Zhao, X. S.;Wu, J. S. Chem. Mater.2010, 22, 1392. doi: 10.1021/cm902876u

    20. [20]

      (20) Majumdar, D.; Baskey, M.; Saha, S. K. Macromolecular Rapid Communications 2011, 32, 1.

    21. [21]

      (21) Yan, J.;Wei, T.; Shao, B.; Fan, Z. J.; Qian,W. Z.; Zhang, M. L.;Wei, F. Carbon 2010, 48, 487. doi: 10.1016/j.carbon.2009.09.066

    22. [22]

      (22) Huang, Y. Y. The Research of Interaction of Graphene/Polyanline Composite Interface. M. E. Dissertation, SunYat-Sen University, Guangzhou, 2010. [黄赟赟. 石墨烯/聚苯胺复合材料界面相互作用研究[D]. 广州: 中山大学, 2010.]

    23. [23]

      (23) Chen, L. Y.; Tang, Y. H.;Wang, K.; Liu, C. B.; Luo, S. L.Electrochem. Commun. 2011, 13, 133.

    24. [24]

      (24) Wang, H. L.; Hao, Q. L.; Yang, X. J.; Lu, L. D.;Wang, X.Nanoscale 2010, 2, 2164. doi: 10.1039/c0nr00224k

    25. [25]

      (25) Wu, K. Z.;Wang, Q. F.; Ma, Z. C.; Duan, X.W.; Li, C. B.;Zhen, X. Y. J. ShaoXing University 2010, 30, 24. [武克忠,王庆飞, 马子川, 段晓伟, 李彩宾, 甄晓燕. 绍兴文理学院学报,2010, 30, 24.]

    26. [26]

      (26) Lu, M.; Zhang, K.; Chan, H. S. O.;Wu, J. S. J. Mater. Chem.2012, 22, 80. doi: 10.1039/c1jm12869h


  • 加载中
    1. [1]

      Li Jiang Changzheng Chen Yang Su Hao Song Yanmao Dong Yan Yuan Li Li . Electrochemical Synthesis of Polyaniline and Its Anticorrosive Application: Improvement and Innovative Design of the “Chemical Synthesis of Polyaniline” Experiment. University Chemistry, 2024, 39(3): 336-344. doi: 10.3866/PKU.DXHX202309002

    2. [2]

      Zhihuan XUQing KANGYuzhen LONGQian YUANCidong LIUXin LIGenghuai TANGYuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447

    3. [3]

      Jiahong ZHENGJiajun SHENXin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO4/NiMoS4 composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253

    4. [4]

      Zhuo WANGJunshan ZHANGShaoyan YANGLingyan ZHOUYedi LIYuanpei LAN . Preparation and photocatalytic performance of CeO2-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

    5. [5]

      Limei CHENMengfei ZHAOLin CHENDing LIWei LIWeiye HANHongbin WANG . Preparation and performance of paraffin/alkali modified diatomite/expanded graphite composite phase change thermal storage material. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 533-543. doi: 10.11862/CJIC.20230312

    6. [6]

      Yuanchao LIWeifeng HUANGPengchao LIANGZifang ZHAOBaoyan XINGDongliang YANLi YANGSonglin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn0.8Fe0.2PO4/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252

    7. [7]

      Hao BAIWeizhi JIJinyan CHENHongji LIMingji LI . Preparation of Cu2O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001

    8. [8]

      Jinyi Sun Lin Ma Yanjie Xi Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094

    9. [9]

      Hong Zheng Xin Peng Chunwang Yi . The Tale of Caprolactam Cyclic Oligomers: The Ever-changing Life of “Princess Cyclo”. University Chemistry, 2024, 39(9): 40-47. doi: 10.12461/PKU.DXHX202403058

    10. [10]

      Jiahong ZHENGJingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi2S4 supported by MnO2 nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170

    11. [11]

      Min LIXianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS2 nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065

    12. [12]

      Jie XIEHongnan XUJianfeng LIAORuoyu CHENLin SUNZhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216

    13. [13]

      Xin Zhou Zhi Zhang Yun Yang Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi2MoO6 Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008

    14. [14]

      Meng Lin Hanrui Chen Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117

    15. [15]

      Yunting Shang Yue Dai Jianxin Zhang Nan Zhu Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050

    16. [16]

      Qin ZHUJiao MAZhihui QIANYuxu LUOYujiao GUOMingwu XIANGXiaofang LIUPing NINGJunming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

    17. [17]

      Qingtang ZHANGXiaoyu WUZheng WANGXiaomei WANG . Performance of nano Li2FeSiO4/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115

    18. [18]

      Kun Xu Xinxin Song Zhilei Yin Jian Yang Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050

    19. [19]

      Chuanming GUOKaiyang ZHANGYun WURui YAOQiang ZHAOJinping LIGuang LIU . Performance of MnO2-0.39IrOx composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459

    20. [20]

      Xinpeng LIULiuyang ZHAOHongyi LIYatu CHENAimin WUAikui LIHao HUANG . Ga2O3 coated modification and electrochemical performance of Li1.2Mn0.54Ni0.13Co0.13O2 cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Metrics
  • PDF Downloads(1838)
  • Abstract views(7549)
  • HTML views(167)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return