Citation: CHEN Chong, CHEN Xiang-Ying, XIE Dong-Hua. Synthesis of Nitrogen Doped Porous Carbons from Sodium Carboxymethyl Cellulose and the Capacitive Performance[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 102-110. doi: 10.3866/PKU.WHXB201210231 shu

Synthesis of Nitrogen Doped Porous Carbons from Sodium Carboxymethyl Cellulose and the Capacitive Performance

1.
Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, School of Chemical Engineering, Hefei University of Technology, Anhui 230009, P. R. China

Received Date: 2 October 2012
Available Online: 24 October 2012
Fund Project: 国家自然科学基金(21101052) (21101052) 安徽省自然科学基金(090414194) (090414194) 中国博士后科学基金(20100480045) (20100480045)

We demonstrate a direct carbonization method to prepare porous carbons as electrode materials without an activation process, using sodium carboxymethyl cellulose (NaCMC) as the carbon source, which are further doped with varying mass ratios of nitrogen. From X-ray photoelectron data, the nitrogen species include pyridinic N, graphitic N, and pyrrolic N. The relative mass ratios of NaCMC and CO(NH₂)₂ affect the nature of the nitrogen species, dopant dosages as well as specific surface areas and pore structures. The cyclic voltammetry and galvanostatic charge-discharge measurements in 6 mol·L^-1 KOH aqueous solutions reveal that the specific surface areas and capacitive performances improve after nitrogen-doping. Taking carbon-N-1:20 as example, its S_BET can reach 858 m²·g^-1, which is higher than that of carbon-blank (463 m²·g^-1) and the corresponding specific capacitance greatly improves from 94.0 to 156.7 F· g^-1, respectively. The present carbons are excellent electrode candidates for high-rate electrochemical capacitors.
- Sodium carboxymethyl cellulose,
- Porous carbon,
- Nitrogen doping,
- Capacitive performance
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