Citation: CHEN Chong, CHEN Xiang-Ying, XIE Dong-Hua. Synthesis of Nitrogen Doped Porous Carbons from Sodium Carboxymethyl Cellulose and the Capacitive Performance[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 102-110. doi: 10.3866/PKU.WHXB201210231 shu

Synthesis of Nitrogen Doped Porous Carbons from Sodium Carboxymethyl Cellulose and the Capacitive Performance

1.
Anhui Key Laboratory of Controllable Chemistry Reaction & Material Chemical Engineering, School of Chemical Engineering, Hefei University of Technology, Anhui 230009, P. R. China

Received Date: 2 October 2012
Available Online: 24 October 2012
Fund Project: 国家自然科学基金(21101052) (21101052) 安徽省自然科学基金(090414194) (090414194) 中国博士后科学基金(20100480045) (20100480045)

We demonstrate a direct carbonization method to prepare porous carbons as electrode materials without an activation process, using sodium carboxymethyl cellulose (NaCMC) as the carbon source, which are further doped with varying mass ratios of nitrogen. From X-ray photoelectron data, the nitrogen species include pyridinic N, graphitic N, and pyrrolic N. The relative mass ratios of NaCMC and CO(NH₂)₂ affect the nature of the nitrogen species, dopant dosages as well as specific surface areas and pore structures. The cyclic voltammetry and galvanostatic charge-discharge measurements in 6 mol·L^-1 KOH aqueous solutions reveal that the specific surface areas and capacitive performances improve after nitrogen-doping. Taking carbon-N-1:20 as example, its S_BET can reach 858 m²·g^-1, which is higher than that of carbon-blank (463 m²·g^-1) and the corresponding specific capacitance greatly improves from 94.0 to 156.7 F· g^-1, respectively. The present carbons are excellent electrode candidates for high-rate electrochemical capacitors.
- Sodium carboxymethyl cellulose,
- Porous carbon,
- Nitrogen doping,
- Capacitive performance
1. [1]
  
  (1) Zhai, Y. P.; Dou, Y. Q.; Zhao, D. Y.; Fulvio, P. F.; Mayes, R. T.;Dai, S. Adv. Mater. 2011, 23, 4828. doi: 10.1002/adma.201100984
2. [2]
  (2) Su, P.; Guo, H. L.; Peng, S.; Ning, S. K. Acta Phys. -Chim. Sin.2012, 28, 2745. [苏鹏, 郭慧林, 彭三, 宁生科. 物理化学学报, 2012, 28, 2745.] doi: 10.3866/PKU.WHXB201208221
3. [3]
  (3) Wang, G. P.; Zhang, L.; Zhang, J. J. Chem. Soc. Rev. 2012, 41,797. doi: 10.1039/c1cs15060J
4. [4]
  (4) Frackowiak, E. Phys. Chem. Chem. Phys. 2007, 9, 1774. doi: 10.1039/b618139m
5. [5]
  (5) Hulicova, D.; Yamashita, J.; Soneda, Y.; Hatori, H.; Kodama, M.Chem. Mater. 2005, 17, 1241. doi: 10.1021/cm049337g
6. [6]
  (6) Su, F. B.; Poh, C. K.; Chen, J. S.; Xu, G.W.;Wang, D.; Li, Q.;Lin, J. Y.; Lou, X.W. Energy Environ. Sci. 2011, 4, 717. doi: 10.1039/c0ee00277a
7. [7]
  (7) Konno, H.; Ito, T.; Ushiro, M.; Fushimi, K.; Azumi, K. J. Power Sources 2010, 195, 1739. doi: 10.1016/j.jpowsour.2009.09.072
8. [8]
  (8) Zhao, L.; Baccile, N.; Gross, S.; Zhang, Y. J.;Wei,W.; Sun, Y.H.; Antonietti, M.; Titirici, M. M. Carbon 2010, 48, 3778. doi: 10.1016/j.carbon.2010.06.040
9. [9]
  (9) White, R. J.; Antonietti, M.; Titirici, M. M. J. Mater. Chem.2009, 19, 8645. doi: 10.1039/b911528e
10. [10]
  (10) Horikawa, T.; Sakao, N.; Sekida, T.; Hayashi, J.; Do, D. D.;Katoh, M. Carbon 2012, 50, 1833. doi: 10.1016/j.carbon.2011.12.033
11. [11]
  (11) Lai, L. F.; Chen, L.W.; Zhan, D.; Sun, L.; Liu, J. P.; Lim, S. H.;Poh, C. K.; Shen, Z. X.; Lin, J. Y. Carbon 2011, 49, 3250. doi: 10.1016/j.carbon.2011.03.051
12. [12]
  (12) Zhang, D. Y.; Hao, Y.; Ma, Y.; Feng, H. X. Appl. Surf. Sci. 2012,258, 2510. doi: 10.1016/j.apsusc.2011.10.081
13. [13]
  (13) rgulho, H. F.; nçalves, F.; Pereira, M. F. R.; Figueiredo, J.L. Carbon 2009, 47, 2032. doi: 10.1016/j.carbon.2009.03.050
14. [14]
  (14) Chen, P.; Xiao, T. Y.; Li, H. H.; Yang, J. J.;Wang, Z.; Yao, H.B.; Yu, S. H. ACS Nano 2012, 6, 712. doi: 10.1021/nn204191x
15. [15]
  (15) Guo, H. L.; Gao, Q. M. J. Power Sources 2009, 186, 551. doi: 10.1016/j.jpowsour.2008.10.024
16. [16]
  (16) Zhao, X. C.;Wang, A. Q.; Yan, J.W.; Sun, G. Q.; Sun, L. X.;Zhang, T.; Zhang, T. Chem. Mater. 2010, 22, 5463. doi: 10.1021/cm101072z
17. [17]
  (17) Kwon, T.; Nishihara, H.; Itoi, H.; Yang, Q. H.; Kyotani, T.Langmuir 2009, 25, 11961. doi: 10.1021/la901318d
18. [18]
  (18) Chang, C. Y.; Zhang, L. N. Carbohydrate Polymer 2011, 84, 40.doi: 10.1016/j.carbpol.2010.12.023
19. [19]
  (19) Li,W.; Sun, B. J.;Wu, P. Y. Carbohydrate Polymer 2009, 78,454. doi: 10.1016/j.carbpol.2009.05.002
20. [20]
  (20) Biswal, D. R.; Singh, R. P. Carbohydrate Polymer 2004, 57,379. doi: 10.1016/j.carbpol.2004.04.020
21. [21]
  (21) Chen, L. F.; Zhang, X. D.; Liang, H.W.; Kong, M. G.; Guan, Q.F.; Chen, P.;Wu, Z. Y.; Yu, S. H. ACS Nano 2012, 6, 7092. doi: 10.1021/nn302147s
22. [22]
  (22) Maldonado, S.; Morin, S.; Stevenson, K. J. Carbon 2006, 44,1429. doi: 10.1016/j.carbon.2005.11.027
23. [23]
  (23) Dommele, S.; Romero-Izquirdo, A.; Brydson, R.; Jong, K. P.;Bitter, J. H. Carbon 2008, 46, 138. doi: 10.1016/j.carbon.2007.10.034
24. [24]
  (24) Matter, P. H.; Zhang, L.; Ozkan, U. S. J. Catal. 2006, 239, 83.doi: 10.1016/j.jcat.2006.01.022
25. [25]
  (25) Usachov, D.; Vilkov, O.; Grüneis, A.; Haberer, D.; Fedorov, A.;Adamchuk, V. K.; Preobrajenski, A. B.; Dudin, P.; Barinov, A.;Oehzelt, M.; Laubschat, C.; Vyalikh, D. V. Nano Lett. 2011, 11,5401. doi: 10.1021/nl2031037
26. [26]
  (26) Pevida, C.; Drage, T. C.; Snape, C. E. Carbon 2008, 46, 1464.doi: 10.1016/j.carbon.2008.06.026
27. [27]
  (27) Wu, X. L.;Wang,W.; Guo, Y. G.;Wan, L. J. J. Nanosci. Nanotech. 2011, 11, 1897. doi: 10.1166/jnn.2011.3525
28. [28]
  (28) Huang, M. C.; Teng, H. S. Carbon 2002, 40, 955. doi: 10.1016/S0008-6223(02)00068-4
29. [29]
  (29) Inagaki, M.; Konno, H.; Tanaike, O. J. Power Sources 2010,195, 7880. doi: 10.1016/j.jpowsour.2010.06.036
30. [30]
  (30) Li, Q. Y.;Wang, H. Q.; Dai, Q. F.; Yang, J. H.; Zhong, Y. L.Solid State Ionics 2008, 179, 269. doi: 10.1016/j.ssi.2008.01.085
31. [31]
  (31) Ma, Y.; Zhang, C.; Ji, G.; Lee, J. Y. J. Mater. Chem. 2012, 22,7845. doi: 10.1039/c2jm30422h
32. [32]
  (32) Zhang,W. F.; Huang, Z. H.; Gao, G. P.; Kang, F. Y.;Yang, Y. S.J. Power Sources 2012, 204, 230. doi: 10.1016/j.jpowsour.2011.12.054
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