Citation: DUAN Lin-Qiang, QIAO Cheng-Fang, WEI Qing, XIA Zheng-Qiang, CHEN San-Ping, ZHANG Guo-Chun, ZHOU Chun-Sheng, GAO Sheng-Li. Structures, Thermodecomposition Kinetics and Luminescence Properties of Three Lanthanide-Based Supramolecular Compounds with 1H-Benzimidazole-2-carboxylic Acid[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210122 shu

Structures, Thermodecomposition Kinetics and Luminescence Properties of Three Lanthanide-Based Supramolecular Compounds with 1H-Benzimidazole-2-carboxylic Acid

1.
1 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an 710069, P. R. China;
2 Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Comprehensive Utilization of Tailing Resources, Shangluo University, Shangluo 726000, Shaanxi Province, P. R. China

Received Date: 25 July 2012
Available Online: 12 October 2012
Fund Project: 国家自然科学基金(21173168, 21073142, 21127004) (21173168, 21073142, 21127004)陕西省教育厅科研基金(2010JK882, 2010JQ2007, 11JS110, 11JK0578)资助项目 (2010JK882, 2010JQ2007, 11JS110, 11JK0578)

Three lanthanide-based supramolecular compounds, [Ln(HBIC)₃]_n[Ln=Sm (1), Ho (2), Yb (3); H₂BIC=1H-benzimidazole-2-carboxylic acid], were hydrothermally synthesized and structurally characterized by X-ray single crystal diffraction (compounds 1 and 2), powder X-ray diffraction (XRD) (compound3), elemental analysis, infrared (IR) spectroscopy, and thermal analysis. Structural analyses reveal that compounds 1-3 are isomorphous and display a two-dimensional (2D) plane, in which each lanthanide center is coordinated by three N and five O atoms from five flexible HBIC^- ligands with two kinds of new coordination modes, giving rise to a slightly distorted two-capped triangle prism geometry. The 2D square networks are further assembled into a three-dimensional (3D) supramolecular framework through strong hydrogen-bonding interactions. Thermogravimetry analyses (TG) indicate that compounds 1-3 exhibit od thermostability and could be stable up to 360℃. By means of differential scanning calorimetry (DSC) techniques, the thermoanalysis kinetics parameters of the thermodecomposition of compound 1 were calculated by the Kissinger's and Ozawa-Doyle's methods; the pre-exponential factor A_K was 1.286×108 s^-1 and the apparent activation energy E_K and E_O were determined to be 199.3 and 205.2 kJ·mol^-1, respectively. In addition, the luminescent properties of compounds 1 and 3 were also studied at room temperature in the solid state. The results reveal that compounds 1 and 3 exhibit characteristic emission bands of the corresponding lanthanide ions in the visible and near-infrared regions, respectively.
- Lanthanide coordination compound,
- 1H-Benzimidazole-2-carboxylic acid,
- Structure analysis,
- Luminescence,
- Thermoanalysis kinetics
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