Citation: LIU Bei-Ping, TAN Zhi-Cheng. Thermodynamic Properties of Nd(Gly)₂Cl₃·3H₂O and Pr(Ala)₃Cl₃·3H₂O[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 17-22. doi: 10.3866/PKU.WHXB201210121 shu

Thermodynamic Properties of Nd(Gly)₂Cl₃·3H₂O and Pr(Ala)₃Cl₃·3H₂O

LIU Bei-Ping ¹ ,
TAN Zhi-Cheng ^2,

1.
1 College of Chemistry and Chemical Engineering, Hunan University of Arts and Science, Changde 415000, Hunan Province, P. R. China;
2 Thermochemistry Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 110623, Liaoning Province, P. R. China

Received Date: 23 July 2012
Available Online: 12 October 2012
Fund Project: 国家自然科学基金(20373072) (20373072)湖南省重点学科建设(应用化学)资助项目 (应用化学)

The heat capacities of rare earth complexes, Nd(Gly)₂Cl₃·3H₂O and Pr(Ala)₃Cl₃·3H₂O were measured with a high-precision automatic adiabatic calorimeter in the temperature range from 80 to 357 K for Nd(Gly)₂Cl₃·3H₂O, and from 80 to 374 K for Pr(Ala)₃Cl₃·3H₂O. The thermodynamic functions (H_T?H_298.15) and (S_T?S_298.15) relative to the reference temperature 298.15 K of the two compounds were calculated based on experimental heat capacity data. Possible mechanisms of thermal decompositions were proposed according to the thermogravimetric (TG) analysis. Based on the measurements of dissolution enthalpies using a solution-reaction isoperibol calorimeter, the standard molar enthalpies of formation were calculated in terms of a designed Hess thermochemical cycle.
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Thermodynamic Properties of Nd(Gly)₂Cl₃·3H₂O and Pr(Ala)₃Cl₃·3H₂O