Citation: DUAN Qian-Hua, WANG Sen-Lin, WANG Li-Pin. Electro-Deposition of the Porous Composite Ni-P/LaNi₅ Electrode and Its Electro-Catalytic Performance toward Hydrogen Evolution Reaction[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210095 shu

Electro-Deposition of the Porous Composite Ni-P/LaNi₅ Electrode and Its Electro-Catalytic Performance toward Hydrogen Evolution Reaction

1.
Department of Applied Chemistry, College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, P. R. China

Received Date: 2 August 2012
Available Online: 9 October 2012

The composite Ni-P/(LaNi₅+Al) coating was plated by the composite electro-deposition. Then, the porous composite Ni-P/LaNi₅ coating was successfully prepared by dissolution Al with the concentrated alkali solution. The composition and structure of the coating were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray (EDS), and X-ray diffraction (XRD). In 20% (w) NaOH solution, the electro-catalytic and stable properties for hydrogen evolution reaction (HER) of the porous composite Ni-P/LaNi₅ electrode were evaluated by electrochemical linear voltammetric scanning (LSV), constant potential electrolysis, and electrochemical impedance spectroscopy (EIS). As a result, the porous composite electrode exhibits a lower over-potential for HER, a higher specific surface area, and a better stabilization than that of the porous Ni-P electrode. The apparent activation energy for HER on the porous composite Ni-P/LaNi₅ electrodes is 35.44 kJ·mol^-1, which is lower than that of the porous Ni-P (50.91 kJ· mol^-1).
- Electro-deposition,
- Ni-P/LaNi₅,
- Hydrogen evolution reaction,
- Electro-catalysis,
- Porous composite electrode
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Electro-Deposition of the Porous Composite Ni-P/LaNi5 Electrode and Its Electro-Catalytic Performance toward Hydrogen Evolution Reaction

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通讯作者: 陈斌, bchen63@163.com

Electro-Deposition of the Porous Composite Ni-P/LaNi₅ Electrode and Its Electro-Catalytic Performance toward Hydrogen Evolution Reaction