Citation: YUAN Wen-Hui, LIU Xiao-Chen, LI Li. Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 151-156. doi: 10.3866/PKU.WHXB201210093 shu

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China;
2 College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China

Received Date: 9 August 2012
Available Online: 9 October 2012
Fund Project: 国家自然科学基金(20976057)资助项目 (20976057)

A series of Co-doped ZnIn₂S₄ photocatalysts were prepared via a solvothermal synthesis method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-visible (UV-Vis) diffuse reflectance spectroscopy. The results indicated that the Co was successfully incorporated into the ZnIn₂S₄ lattice as confirmed by XRD and XPS. With increasing Co concentration, the absorption edge of the samples shifted to longer wavelength, while the morphology of ZnIn₂S₄ was gradually destroyed. Photocatalytic results demonstrated that Co²⁺ doping could greatly enhance the photocatalytic activity of ZnIn₂S₄. The optimal amount of Co doping for the ZnIn2S4 photocatalyst was 0.3%(w), which displayed the highest photocatalytic activity. The possible photocatalytic mechanism was discussed.
- Photocatalyst,
- Doping,
- Visible light,
- Hydrogen generation,
- Water splitting
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn2S4 under Visible Light

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通讯作者: 陈斌, bchen63@163.com

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light