Citation: YUAN Wen-Hui, LIU Xiao-Chen, LI Li. Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 151-156. doi: 10.3866/PKU.WHXB201210093 shu

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light

1.
School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China;
2 College of Environmental Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, P.R.China

Received Date: 9 August 2012
Available Online: 9 October 2012
Fund Project: 国家自然科学基金(20976057)资助项目 (20976057)

A series of Co-doped ZnIn₂S₄ photocatalysts were prepared via a solvothermal synthesis method. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and UV-visible (UV-Vis) diffuse reflectance spectroscopy. The results indicated that the Co was successfully incorporated into the ZnIn₂S₄ lattice as confirmed by XRD and XPS. With increasing Co concentration, the absorption edge of the samples shifted to longer wavelength, while the morphology of ZnIn₂S₄ was gradually destroyed. Photocatalytic results demonstrated that Co²⁺ doping could greatly enhance the photocatalytic activity of ZnIn₂S₄. The optimal amount of Co doping for the ZnIn2S4 photocatalyst was 0.3%(w), which displayed the highest photocatalytic activity. The possible photocatalytic mechanism was discussed.
- Photocatalyst,
- Doping,
- Visible light,
- Hydrogen generation,
- Water splitting
1. [1]
  
  (1) Kato, H.; Asakura, K.; Kudo, A. J. Am. Chem. Soc. 2003, 125 (10), 3082. doi: 10.1021/ja027751g
2. [2]
  (2) Kim, H. G.; Hwang, D.W.; Bae, S.W.; Jung, J. H.; Lee, J. S.Catal. Lett. 2003, 91 (3-4), 193.
3. [3]
  (3) Chen,W.; Dong, X. F.; Chen, Z. S.; Chen, S. Z.; Lin,W. M.Acta Phys. -Chim. Sin. 2009, 25 (6), 1107. [陈威, 董新法,陈之善, 陈胜洲, 林维明. 物理化学学报, 2009, 25 (6), 1107.]doi: 10.3866/PKU.WHXB20090624
4. [4]
  (4) Huang, L. H.; Chan, Q. Z.; Zhang, B.;Wu, X. J.; Gao, P.; Jiao,Z. B.; Liu, Y. L. Chin. J. Catal. 2011, 32 (11-12), 1822. doi: 10.1016/S1872-2067(10)60286-0
5. [5]
  (5) Zou, Z.; Ye, J.; Arakawa, H.; Sayama, K. Nature 2001, 414 (6864), 625. doi: 10.1038/414625a
6. [6]
  (6) Kim, H. G.; Hwang, D.W.; Lee, J. S. J. Am. Chem. Soc. 2004,126 (29), 8912. doi: 10.1021/ja049676a
7. [7]
  (7) Maeda, K.; Teramura, K.; Lu, D. L.; Takata, T.; Saito, N.; Inoue,Y.; Domen, K. Nature 2006, 440 (7082), 295. doi: 10.1038/440295a
8. [8]
  (8) Ritterskamp, P.; Kuklya, A.;Wustkamp, M. A.; Kerpen, K.;Weidenthaler, C.; Demuth, M. Angew. Chem. Int. Edit. 2007, 46 (41), 7770.
9. [9]
  (9) Chaudhari, N. S.; Bhirud, A. P.; Sonawane, R. S.; Nikam, L. K.;Warule, S. S.; Rane, V. H.; Kale, B. B. Green Chem. 2011, 13 (9), 2500. doi: 10.1039/c1gc15515f
10. [10]
  (10) Tsuji, I.; Kato, H.; Kobayashi, H.; Kudo, A. J. Phys. Chem. B2005, 109 (15), 7323. doi: 10.1021/jp044722e
11. [11]
  (11) Tsuji, I.; Kato, H.; Kobayashi, H.; Kudo, A. J. Am. Chem. Soc.2004, 126 (41), 13406. doi: 10.1021/ja048296m
12. [12]
  (12) Tsuji, I.; Kato, H.; Kudo, A. Chem. Mater. 2006, 18 (7), 1969.doi: 10.1021/cm0527017
13. [13]
  (13) Romeo, N.; Dallaturca, A.; Braglia, R.; Sberveglieri, G. Appl. Phys. Lett. 1973, 22 (1), 21. doi: 10.1063/1.1654457
14. [14]
  (14) Castro, S. L.; Bailey, S. G.; Raffaelle, R. P.; Banger, K. K.;Hepp, A. F. Chem. Mater. 2003, 15 (16), 3142. doi: 10.1021/cm034161o
15. [15]
  (15) Seo,W. S.; Otsuka, R.; Okuno, H.; Ohta, M.; Koumoto, K.J. Mater. Res. 1999, 14 (11), 4176. doi: 10.1557/JMR.1999.0565
16. [16]
  (16) Lei, Z.; You,W.; Liu, M.; Zhou, G.; Takata, T.; Hara, M.;Domen, K.; Li, C. Chem. Commun. 2003, 2142.
17. [17]
  (17) Shen, S. H.; Zhao, L.; Guo, L. J. J. Phys. Chem. Solids 2008, 69 (10), 2426. doi: 10.1016/j.jpcs.2008.04.035
18. [18]
  (18) Shen, S. H.; Zhao, L.; Guo, L. J. Int. J. Hydrog. Energy 2008,33 (17), 4501. doi: 10.1016/j.ijhydene.2008.05.043
19. [19]
  (19) Shen, S. H.; Zhao, L.; Guo, L. J. Mater. Res. Bull. 2009, 44 (1),100. doi: 10.1016/j.materresbull.2008.03.027
20. [20]
  (20) Lu, Y. C.; Lin, Y. H.;Wang, D. J.;Wang, L. L.; Xie, T. F.; Jiang,T. F. Nano Res. 2011, 4 (11), 1144. doi: 10.1007/s12274-011-0163-4
21. [21]
  (21) Bai, X. F.; Li, J. S. Mater. Res. Bull. 2011, 46 (7), 1028. doi: 10.1016/j.materresbull.2011.03.012
22. [22]
  (22) Peng, S. J.; Zhu, P. N.; Thavasi, V.; Mhaisalkar, S. G.;Ramakrishna, S. Nanoscale 2011, 3, 2602. doi: 10.1039/c0nr00955e
23. [23]
  (23) Cai,W.; Zhao, Y. S.; Hu, J.; Zhong, J. S.; Xiang,W. D. J. Mater. Sci. Technol. 2011, 27 (6), 559. doi: 10.1016/S1005-0302(11)60108-4
24. [24]
  (24) Dubey, N.; Labhsetwar, K.; Devotta, S.; Rayalu, S. Catal. Today2007, 129 (3-4), 428. doi: 10.1016/j.cattod.2006.09.041
25. [25]
  (25) Jing, D.W.; Liu, M. C.; Guo, L. J. Catal. Lett. 2010, 140 (3-4),167. doi: 10.1007/s10562-010-0442-9
26. [26]
  (26) Shen, S. H.; Zhao, L.; Guo, L. J. J. Phys. Chem. C 2008, 112 (41), 16148. doi: 10.1021/jp804525q
27. [27]
  (27) Zhang, X.; Jing, D.; Liu, M.; Guo, L. J. Catal. Commun. 2008, 9 (8), 1720. doi: 10.1016/j.catcom.2008.01.032
28. [28]
  (28) Wang, B. Q.; Xia, C. H.; Iqbal, J.; Tang, N. J.; Sun, Z. R.; Lv, Y.;Wu, L. Solid State Sci. 2009, 11 (8), 1419. doi: 10.1016/j.solidstatesciences.2009.04.024
29. [29]
  (29) Jing, D.W.; Zhang, Y.; Guo, L. J. Chem. Phys. Lett. 2005, 415 (1-3), 74. doi: 10.1016/j.cplett.2005.08.080
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn2S4 under Visible Light

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通讯作者: 陈斌, bchen63@163.com

Improving Photocatalytic Performance for Hydrogen Generation over Co-Doped ZnIn₂S₄ under Visible Light