Citation: CAO Jian-Yu, TANG Jia-Li, SONG Ling-Zheng, XU Juan, WANG Wen-Chang, Chen Zhi-Dong. Functionalization of Activated Carbon with EDTA and Its Effect on Electrocatalytic Performance of Carbon Supported Pd Catalysts[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 144-150. doi: 10.3866/PKU.WHXB201210092 shu

Functionalization of Activated Carbon with EDTA and Its Effect on Electrocatalytic Performance of Carbon Supported Pd Catalysts

CAO Jian-Yu ^1,2 ,
TANG Jia-Li ¹ ,
SONG Ling-Zheng ¹ ,
XU Juan ^1,2 ,
WANG Wen-Chang ^1,2 ,
Chen Zhi-Dong ^1,2,3,

1.
1 School of Petrochemical Engineering, Changzhou University, Changzhou 213164, Jiangsu Province, P. R. China;
2 Key Laboratory for Solar Cells and Energy Storage Technology of Jiangsu Province, Changzhou 213164, Jiangsu Province, P. R. China;
3 Qualtec Co. Ltd., Osaka 590-0906, Japan

Received Date: 16 July 2012
Available Online: 9 October 2012
Fund Project: 国家自然科学基金(21003015, 21103014) (21003015, 21103014) 江苏省自然科学基金(BE201113, 2011Z0062) (BE201113, 2011Z0062)江苏高校优势学科建设工程(PAPD)资助项目 (PAPD)

The effect of functionalization of activated carbon with ethylenediamine tetraacetic acid (EDTA) on surface functional groups, the structure of carbon-supported Pd nanoparticles, and the electrocatalytic performance of Pd catalysts were investigated. Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) indicate that N-containing groups are introduced to the carbon surface via EDTA treatment. X-ray powder diffraction (XRD) spectra, transmission electron microscopy (TEM), and electrochemical measurements demonstrate that the electrocatalytic activity and stability for carbon-supported Pd catalysts were substantially enhanced when the carbon support was treated with EDTA, although the Pd particles size increased slightly. The improved electrocatalytic performance may be due to enhanced interactions between the Pd particles and the carbon support, resulting in an improved Pd utilization. Electrochemical impedance spectrum analysis further reveals that the Pd catalyst on EDTA-treated carbon (Pd/C-E) displayed a lower charge-transfer resistance for the electro-oxidation reaction of formic acid.
- Carbon supported palladium catalyst,
- Ethylenediamine tetraacetic acid,
- Electrocatalysis,
- Formic acid oxidation,
- Electrochemical impedance spectrum
1. [1]
  
  (1) Cabiac, A.; Delahay, G.; Durand, R.; Durand, R.; Trens, P.; Coq,B.; Plée, D. Carbon 2007, 45 (1), 3. doi: 10.1016/j.carbon.2006.08.016
2. [2]
  (2) Yin, S. B.; Shen, P. K.; Song, S. Q.; Song, S. Q.; Jiang, S. P.Electrochim. Acta 2009, 54 (27), 6954. doi: 10.1016/j.electacta.2009.07.009
3. [3]
  (3) Zhao, J. Y.; Zhou, Y. M.;Wu, Y. S.; Tang, Y.W.; Chen, Y.; Lu, T.H. Acta Chim. Sin. 2011, 69 (10), 1179. [赵佳越, 周益明, 吴云胜, 唐亚文, 陈煜, 陆天虹. 化学学报, 2011, 69 (10), 1179.]
4. [4]
  (4) Wang, Z. B.; Yin, G. P.; Shi, P. F. Acta Chim. Sin. 2005, 63 (19),1813. [王振波, 尹鸽平, 史鹏飞. 化学学报, 2005, 63 (19),1813.]
5. [5]
  (5) Antonucci, P. L.; Alderucci, V.; Giordano, N.; Cocke, D. L.;Kim, H. J. Appl. Electrochem. 1994, 24 (1), 58.
6. [6]
  (6) Kumar, S. M. S.; Herrero, J. S.; Irusta, S.; Scott, K.J. Electroanal. Chem. 2010, 647 (2), 211. doi: 10.1016/j.jelechem.2010.05.021
7. [7]
  (7) Jaramillo, J.; Álvarez, P. M.; Gómez-Serrano, V. Fuel Process. Technol. 2010, 91 (11), 1768. doi: 10.1016/j.fuproc.2010.07.018
8. [8]
  (8) Poh, C. K.; Lim, S. H.; Pan, H.; Lin, J. Y.; Lee, J. Y. J. Power Sources 2008, 176 (1), 70. doi: 10.1016/j.jpowsour.2007.10.049
9. [9]
  (9) Ye, J. L.; Liu, J. G.; Zhou, Y.; Zou, Z. G.; Gu, J.; Yu, T. J. Power Sources 2009, 194 (2), 683. doi: 10.1016/j.jpowsour.2009.06.032
10. [10]
  (10) Jafri, R. I.; Rajalakshmi, N.; Ramaprabhu, S. J. Power Sources2010, 195 (24), 8080. doi: 10.1016/j.jpowsour.2010.06.109
11. [11]
  (11) Shao, Y.; Sui, J.; Yin, G.; Gao, Y. Appl. Catal. B 2008, 79 (1),89. doi: 10.1016/j.apcatb.2007.09.047
12. [12]
  (12) Kouvetakis, J.; Todd, M.;Wilkens, B.; Bandari, A.; Cave, N.Chem. Mater. 1994, 6 (6), 811. doi: 10.1021/cm00042a018
13. [13]
  (13) Yin, L.W.; Bando, Y.; Li, M. S.; Liu, Y. X.; Qi, Y. X. Adv. Mater. 2003, 15 (21), 1840.
14. [14]
  (14) Oku, T.; Kawaguchi, M. Diamond Relat. Mater. 2000, 9 (3-6),906. doi: 10.1016/S0925-9635(99)00359-3
15. [15]
  (15) Guo, Q. X.; Xie, Y.;Wang, X. J.; Zhang, S. Y.; Hou, T.; Lv, S. C.Chem. Commun. 2004, No. 1, 26.
16. [16]
  (16) Jiang, Y.; Zhang, J.; Qin, Y. H.; Niu, D. F.; Zhang, X. S.; Niu,L.; Zhou, X. G.; Lu, T. H.; Yuan,W. K. J. Power Sources 2011,196 (22), 9356. doi: 10.1016/j.jpowsour.2011.07.036
17. [17]
  (17) Ding, L. X.;Wang, S. R.; Zheng, X. L.; Chen, Y.; Lu, T. H.;Cao, D. X.; Tang, Y.W. Acta Phys. -Chim. Sin. 2010, 26 (5),1311. [丁良鑫, 王士瑞, 郑小龙, 陈煜, 陆天虹, 曹殿学, 唐亚文. 物理化学学报, 2005, 26 (5), 1311.] doi: 10.3866/PKU.WHXB20100521
18. [18]
  (18) Mawhinney, D. B.; Yates, J. T, Jr. Carbon 2001, 39 (8), 1167.doi: 10.1016/S0008-6223(00)00238-4
19. [19]
  (19) Meng, Y.; Gu, D.; Zhang, F. Q.; Shi, Y. F.; Cheng, L.; Feng, D.;Wu, Z. X.; Chen, Z. X.;Wan, Y.; Stein, A.; Zhao, D. Y. Chem. Mater. 2006, 18 (18), 4447. doi: 10.1021/cm060921u
20. [20]
  (20) Song, X. L.; Liu, H. Y.; Cheng, L.; Qu, Y. X. Desalination 2010,255 (1-3), 78. doi: 10.1016/j.desal.2010.01.011
21. [21]
  (21) Shin, S.; Jang, J.; Yoon, S. H.; Mochida, I. Carbon 1997, 35 (12), 1739. doi: 10.1016/S0008-6223(97)00132-2
22. [22]
  (22) Geng, D. S.; Yang, S. L.; Zhang, Y.; Yang, J. L.; Liu, J.; Li, R.Y.; Sham, T. K.; Sun, X. L.; Ye, S. Y.; Knights, S. Appl. Surf. Sci. 2011, 257 (21), 9193. doi: 10.1016/j.apsusc.2011.05.131
23. [23]
  (23) rgulho, H. F.; ncalves, F.; Pereira, M. F. R.; Figueiredo, J.L. Carbon 2009, 47 (8), 2032. doi: 10.1016/j.carbon.2009.03.050
24. [24]
  (24) Radmilovi?, V.; Gasteiger, H. A.; Ross, P. N. J. Catal. 1995, 154 (1), 98. doi: 10.1006/jcat.1995.1151
25. [25]
  (25) Lundgren, E.; Kresse, G.; Klein, C.; Borg, M.; Andersen, J. N.;Santis, M. D.; Gauthier, Y.; Konvicka, C.; Schmid, M.; Varga, P.Phys. Rev. Lett. 2002, 88 (24), 246103. doi: 10.1103/PhysRevLett.88.246103
26. [26]
  (26) Zhou,W. P.; Lewera, A.; Larsen, R.; Masel, R. I.; Bagus, P. S.;Wieckowski, A. J. Phys. Chem. B 2006, 110 (27), 13393. doi: 10.1021/jp061690h
27. [27]
  (27) Qiu, L. M.; Liu, F.; Zhao, L. Z.; Yang,W. S.; Yao, J. N.Langmuir 2006, 22 (10), 4480. doi: 10.1021/la053071q
28. [28]
  (28) Zhu, Y.; Kang, Y. Y.; Zou, Z. Q.; Zhou, Q.; Zheng, J.W.; Xia, B.J.; Yang, H. Electrochem. Commun. 2008, 10 (5), 802. doi: 10.1016/j.elecom.2008.02.038
1. [1]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
2. [2]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
3. [3]
  Xiuyun Wang , Jiashuo Cheng , Yiming Wang , Haoyu Wu , Yan Su , Yuzhuo Gao , Xiaoyu Liu , Mingyu Zhao , Chunyan Wang , Miao Cui , Wenfeng Jiang . Improvement of Sodium Ferric Ethylenediaminetetraacetate (NaFeEDTA) Iron Supplement Preparation Experiment. University Chemistry, 2024, 39(2): 340-346. doi: 10.3866/PKU.DXHX202308067
4. [4]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
5. [5]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
6. [6]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
7. [7]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
8. [8]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
9. [9]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
10. [10]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
11. [11]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
12. [12]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
13. [13]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
14. [14]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
15. [15]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
18. [18]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
19. [19]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
20. [20]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421

Get Citation

PDF

XML

Metrics

PDF Downloads(871)
Abstract views(2206)
HTML views(13)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142