Citation: LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, ZHANG Zeng-Chang, CHEN Mei-Hua, LI Zai-Fang, HE Ping. Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210091 shu

Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte

1.
1 Research Center for Materials Science & Engineering, Hubei University of Arts and Science, Xiangyang 441053, P. R. China;
2 State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiao Tong University, Xi'an 710049, P. R. China;
3 Key Laboratory of Green Processing and Functional Textiles of New Textile Materials, Ministry of Education, Wuhan Textile University, Wuhan 430073, P. R. China

Received Date: 18 June 2012
Available Online: 9 October 2012
Fund Project: 国家自然科学基金(51003082) (51003082) 教育部科学技术研究重点项目(208089) (208089)湖北省自然科学基金(2011CDC062)资助 (2011CDC062)

A quasi-solid-state three-dimensionally crosslinked poly(citric acid-ethylene glycol) (PCE)/ LiI/I₂ polymer electrolyte has been prepared using biodegradable PCE synthesized via a crosslinking reaction between citric acid (CA) and oli -polyethylene glycol (PEG) (average molecular weight M_w= 200, 400, 1000, 2000) as a matrix. The molecular structure of the PCE matrix, micro-morphology of polymer electrolyte, and the state of conductive ion-pairs in the electrolyte were characterized by infrared (IR) spectrum, 1H nuclear magnetic resonance (1H-NMR), and Raman spectroscopy, as well as scanning electron microscopy (SEM). The ionic diffusion coefficient and conductivity of polymer electrolytes and the output current-voltage (I-V) properties of the cells were investigated via linear sweep voltammetry. The results reveal that PEG molecular weights influence the mesh morphology and the absorbent properties of the PCE matrix, which influences the polymer electrolyte ionic conductive performance and the photoelectric performance of the cells. As PEG molecular weights increased from 200, 400, 1000 to 2000, the PCE matrix mesh structure became looser, the liquid electrolyte uptake of the matrix increased, and the transition activation energies of I₃^- in the swollen PCE matrix decreased, which led to an increase in the electrolyte conductivity and the short circuit photocurrent densities of the cells accordingly. The photoelectric conversion efficiencies of the cells assembled by the four polymer electrolytes above were 3.26%, 3.34%, 4.26%, and 4.89%, respectively, under an incident light intensity of 60 mW·cm^-2.
- Polymer electrolyte,
- Polyethylene glycol molecular weight,
- Cross-linking,
- Absorbent property,
- Ionic conductivity
1. [1]
  
  (1) Oregan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Yella, A.; Lee, H.W.; Tsao, H. N.; Yi, C. Y.; Chandiran, A. K.;Nazeeruddin, M. K.; Diau, E.W. G.; Yeh, C. Y.; Zakeeruddin, S.M.; Grätzel, M. Science 2011, 334, 629. doi: 10.1126/science.1209688
3. [3]
  (3) Xia, J.; Masaki, N.; Lira-Cantu, M.; Kim,Y.; Jiang, K.;Yanagida,S. J. Am. Chem. Soc. 2008, 130, 1258. doi: 10.1021/ja075704o
4. [4]
  (4) Jung, K. S.; Lee, S. B.; Kim, Y. K.; Seo, M. H.; Hwang,W. P.;Jang, Y.W.; Park, H.W.; Jin, B. R.; Kim, M. R.; Lee, J. K.J. Photochem. Photobiol. A-Chem. 2012, 231, 64. doi: 10.1016/j.jphotochem.2012.01.005
5. [5]
  (5) Leijtens, T.; Ding, I. K.; Giovenzana, T.; Bloking, J. T.;McGehee, M. D.; Sellinger, A. ACS Nano 2012, 6, 1455. doi: 10.1021/nn204296b
6. [6]
  (6) Caramori, S.; Cazzanti, S.; Marchini, L.; Argazzi, R.; Bignozzi,C. A.; Martineau, D.; Gros, P. C.; Beley, M. Inorg. Chim. Acta2008, 361, 627. doi: 10.1016/j.ica.2007.04.016
7. [7]
  (7) Kim, J.; Koh, J. K.; Kim, B.; Ahn, S. H.; Ahn, H.; Ryu, D. Y.;Kim, J. H.; Kim, E. Adv. Funct. Mater. 2011, 21, 4633. doi: 10.1002/adfm.v21.24
8. [8]
  (8) Zhang,W.; Cheng, Y. M.; Yin, X.; Liu, B. Macromol. Chem. Phys. 2011, 212, 15. doi: 10.1002/macp.v212.1
9. [9]
  (9) Chung, I.; Lee, B.; He, J. Q.; Chang, R. P. H.; Kanatzidis, M. G.Nature 2012, 485, 486. doi: 10.1038/nature11067
10. [10]
  (10) Natu, G.; Huang, Z. J.; Ji, Z. Q.;Wu, Y. Y. Langmuir 2012, 28,950. doi: 10.1021/la203534s
11. [11]
  (11) Prakash, T.; Ramasamy, S. Sci. Adv. Mater. 2012, 4, 29. doi: 10.1166/sam.2012.1247
12. [12]
  (12) Yu, M. Z.; Natu, G.; Ji, Z. Q.;Wu, Y. Y. J. Phys. Chem. Lett.2012, 3, 1074. doi: 10.1021/jz3003603
13. [13]
  (13) Guo, X. Y.; Yi, P. F.;Wang,W. J.; Yang, Y. Acta Phys. -Chim. Sin. 2012, 28, 585. [郭学益, 易鹏飞, 王惟嘉, 杨英. 物理化学学报, 2012, 28, 585.] doi: 10.3866/PKU.WHXB201112302
14. [14]
  (14) Benedetti, J. E.; Correa, A. A.; Carmello, M.; Almeida, L. C. P.; ncalves, A. S.; Nogueira, A. F. J. Power Sources 2012, 208,263. doi: 10.1016/j.jpowsour.2012.01.147
15. [15]
  (15) Rachod, B.; Jutarat, S.; Nuttachai, P.; Pisorn, S. H.; Chaiyuth, S.K.; Pasit, P. Mater. Chem. Phys. 2012, 132, 993. doi: 10.1016/j.matchemphys.2011.12.048
16. [16]
  (16) Zhang, G. Q.; Ma, L.;Wu, Z. J.; Zhang, H. Y.; Ni, P. Acta Phys. -Chim. Sin. 2009, 25, 555. [张国庆, 马莉, 吴忠杰,张海燕, 倪佩. 物理化学学报, 2009, 25, 555.] doi: 10.3866/PKU.WHXB20090326
17. [17]
  (17) Stephan, A. M. Eur. Polym. J. 2006, 42, 21. doi: 10.1016/j.eurpolymj.2005.09.017
18. [18]
  (18) Pitawala, H. M. J. C.; Dissanayake, M. A. K. L.; Seneviratne, V.A. Solid State Ionics 2007, 178, 885. doi: 10.1016/j.ssi.2007.04.008
19. [19]
  (19) Lee, R. H.; Cheng, T. F.; Chang, J.W.; Ho, J. H. Colloid Polym. Sci. 2011, 289, 817. doi: 10.1007/s00396-011-2397-9
20. [20]
  (20) Zhang, D.W.; Li, X. D.; Huang, S. M.;Wang, Z. A.; Shi, J. H.;Sun, Z.; Yin, X. J. International Journal of Nanoscience 2010,9, 257. doi: 10.1142/S0219581X10006764
21. [21]
  (21) Basak, P.; Manorama, S. V. Eur. Polym. J. 2004, 40, 1155. doi: 10.1016/j.eurpolymj.2004.01.013
22. [22]
  (22) Kuo, P. L.; Hou, S. S.; Lin, C. Y.; Chen, C. C.;Wen, T. C.J. Polym. Sci. Pol. Chem. 2004, 42, 2051. doi: 10.1002/pola.20056
23. [23]
  (23) Kumar, M.; Sekhon, S. S. Eur. Polym. J. 2002, 38, 1297. doi: 10.1016/S0014-3057(01)00310-X
24. [24]
  (24) Han, H.W.; Liu,W.; Zhang, J.; Zhao, X. Z. Adv. Funct. Mater.2005, 15, 1940. doi: 10.1002/adfm.200500159
25. [25]
  (25) Zhou, Y. F.; Xiang,W. C.; Chen, S.; Fang, S. B.; Zhou, X.W.;Zhang, J. B.; Lin, Y. Chem. Commun. 2009, 3895.
26. [26]
  (26) Liang, G. J.; Xu, J.; Xu,W. L.; Shen, X. L.; Zhang, H.; Yao, M.Polym. Compos. 2011, 32, 511. doi: 10.1002/pc.v32.4
27. [27]
  (27) Cui, J. F.; Han, P. L.; Guo, J. H.; Yang, B. P.; Zhang, Z. L. China Synthetic Rubber Industry 2009, 32, 22. [崔锦峰, 韩培亮,郭军红, 杨保平, 张志立. 合成橡胶工业, 2009, 32, 22.]
28. [28]
  (28) Liang, G. J.; Xu,W. L.; Xu, J.; Shen, X. L.; Yao, M. InfluenceofWeight Ratio of Citric Acid Cross Linker on the Structureand Conductivity of the Crosslinked Polymer Electrolytes.In Advanced Materials Research, International Symposium onChemical Engineering and Material Properties, Shenyang,China, Nov 4-6, 2011; Zhang, H. M.,Wu, B., Eds.; Trans TechPublications Ltd: Switzerland, 2011; pp 391-392.
29. [29]
  (29) Liang, G. J.; Xu,W. L.; Shen, X. L.; Yang, H. J. Acta Energiae Solaris Sinica 2008, 29, 933. [梁桂杰, 徐卫林, 沈小林, 杨红军. 太阳能学报, 2008, 29, 933.]
30. [30]
  (30) Yu, M. X.; Shi, Q.; Zhou, X.; Yan, Y. S.;Wan, C. R. Acta Polym. Sin. 2001, 5, 665. [于明昕, 石桥, 周啸, 严玉顺, 万春荣.高分子学报, 2001, 5, 665.]
31. [31]
  (31) Liang, G. J.; Xu, J.; Xu,W. L.; Shen, X. L.; Bai, Z. K.; Yao, M.Polym. Eng. Sci. 2011, 51, 2526. doi: 10.1002/pen.v51.12
32. [32]
  (32) Kang, M. S.; Kim, J. H.;Won, J.; Kang, Y. S. J. Photochem. Photobiol. A-Chem. 2006, 183, 15. doi: 10.1016/j.jphotochem.2006.02.013
1. [1]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309019
2. [2]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240189
3. [3]
  Xinhao Yan , Guoliang Hu , Ruixi Chen , Hongyu Liu , Qizhi Yao , Jiao Li , Lingling Li . Polyethylene Glycol-Ammonium Sulfate-Nitroso R Salt System for the Separation of Cobalt (II). University Chemistry, doi: 10.3866/PKU.DXHX202310073
4. [4]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, doi: 10.3866/PKU.DXHX202311084
5. [5]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, doi: 10.3866/PKU.DXHX202308094
6. [6]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20250023
7. [7]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202308048
8. [8]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry,
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202408007
10. [10]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, doi: 10.3866/PKU.DXHX202308057
11. [11]
  Zhongxin YU , Wei SONG , Yang LIU , Yuxue DING , Fanhao MENG , Shuju WANG , Lixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240304
12. [12]
  Bao Jia , Yunzhe Ke , Shiyue Sun , Dongxue Yu , Ying Liu , Shuaishuai Ding . Innovative Experimental Teaching for the Preparation and Modification of Conductive Organic Polymer Thin Films in Undergraduate Courses. University Chemistry, doi: 10.12461/PKU.DXHX202404121
13. [13]
  Xiao SANG , Qi LIU , Jianping LANG . Synthesis, structure, and fluorescence properties of Zn(Ⅱ) coordination polymers containing tetra-alkenylpyridine ligands. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240158
14. [14]
  Xingchao Zhao , Xiaoming Li , Ming Liu , Zijin Zhao , Kaixuan Yang , Pengtian Liu , Haolan Zhang , Jintai Li , Xiaoling Ma , Qi Yao , Yanming Sun , Fujun Zhang . 倍增型全聚合物光电探测器及其在光电容积描记传感器上的应用. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202311021
15. [15]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, doi: 10.12461/PKU.DXHX202405141
16. [16]
  Zhuoming Liang , Ming Chen , Zhiwen Zheng , Kai Chen . Multidimensional Studies on Ketone-Enol Tautomerism of 1,3-Diketones By ¹H NMR. University Chemistry, doi: 10.3866/PKU.DXHX202311029
17. [17]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202406027
18. [18]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, doi: 10.12461/PKU.DXHX202404141
19. [19]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, doi: 10.12461/PKU.DXHX202402017
20. [20]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240326

Get Citation

PDF

XML

Metrics

PDF Downloads(812)
Abstract views(2017)
HTML views(4)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com