Citation: LIANG Gui-Jie, ZHONG Zhi-Cheng, XU Jie, ZHANG Zeng-Chang, CHEN Mei-Hua, LI Zai-Fang, HE Ping. Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201210091 shu

Quasi-Solid State Dye-Sensitized Solar Cells Based on the Novel Crosslinked Polymer Electrolyte

1.
1 Research Center for Materials Science & Engineering, Hubei University of Arts and Science, Xiangyang 441053, P. R. China;
2 State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiao Tong University, Xi'an 710049, P. R. China;
3 Key Laboratory of Green Processing and Functional Textiles of New Textile Materials, Ministry of Education, Wuhan Textile University, Wuhan 430073, P. R. China

Received Date: 18 June 2012
Available Online: 9 October 2012
Fund Project: 国家自然科学基金(51003082) (51003082) 教育部科学技术研究重点项目(208089) (208089)湖北省自然科学基金(2011CDC062)资助 (2011CDC062)

A quasi-solid-state three-dimensionally crosslinked poly(citric acid-ethylene glycol) (PCE)/ LiI/I₂ polymer electrolyte has been prepared using biodegradable PCE synthesized via a crosslinking reaction between citric acid (CA) and oli -polyethylene glycol (PEG) (average molecular weight M_w= 200, 400, 1000, 2000) as a matrix. The molecular structure of the PCE matrix, micro-morphology of polymer electrolyte, and the state of conductive ion-pairs in the electrolyte were characterized by infrared (IR) spectrum, 1H nuclear magnetic resonance (1H-NMR), and Raman spectroscopy, as well as scanning electron microscopy (SEM). The ionic diffusion coefficient and conductivity of polymer electrolytes and the output current-voltage (I-V) properties of the cells were investigated via linear sweep voltammetry. The results reveal that PEG molecular weights influence the mesh morphology and the absorbent properties of the PCE matrix, which influences the polymer electrolyte ionic conductive performance and the photoelectric performance of the cells. As PEG molecular weights increased from 200, 400, 1000 to 2000, the PCE matrix mesh structure became looser, the liquid electrolyte uptake of the matrix increased, and the transition activation energies of I₃^- in the swollen PCE matrix decreased, which led to an increase in the electrolyte conductivity and the short circuit photocurrent densities of the cells accordingly. The photoelectric conversion efficiencies of the cells assembled by the four polymer electrolytes above were 3.26%, 3.34%, 4.26%, and 4.89%, respectively, under an incident light intensity of 60 mW·cm^-2.
- Polymer electrolyte,
- Polyethylene glycol molecular weight,
- Cross-linking,
- Absorbent property,
- Ionic conductivity
1. [1]
  
  (1) Oregan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
2. [2]
  (2) Yella, A.; Lee, H.W.; Tsao, H. N.; Yi, C. Y.; Chandiran, A. K.;Nazeeruddin, M. K.; Diau, E.W. G.; Yeh, C. Y.; Zakeeruddin, S.M.; Grätzel, M. Science 2011, 334, 629. doi: 10.1126/science.1209688
3. [3]
  (3) Xia, J.; Masaki, N.; Lira-Cantu, M.; Kim,Y.; Jiang, K.;Yanagida,S. J. Am. Chem. Soc. 2008, 130, 1258. doi: 10.1021/ja075704o
4. [4]
  (4) Jung, K. S.; Lee, S. B.; Kim, Y. K.; Seo, M. H.; Hwang,W. P.;Jang, Y.W.; Park, H.W.; Jin, B. R.; Kim, M. R.; Lee, J. K.J. Photochem. Photobiol. A-Chem. 2012, 231, 64. doi: 10.1016/j.jphotochem.2012.01.005
5. [5]
  (5) Leijtens, T.; Ding, I. K.; Giovenzana, T.; Bloking, J. T.;McGehee, M. D.; Sellinger, A. ACS Nano 2012, 6, 1455. doi: 10.1021/nn204296b
6. [6]
  (6) Caramori, S.; Cazzanti, S.; Marchini, L.; Argazzi, R.; Bignozzi,C. A.; Martineau, D.; Gros, P. C.; Beley, M. Inorg. Chim. Acta2008, 361, 627. doi: 10.1016/j.ica.2007.04.016
7. [7]
  (7) Kim, J.; Koh, J. K.; Kim, B.; Ahn, S. H.; Ahn, H.; Ryu, D. Y.;Kim, J. H.; Kim, E. Adv. Funct. Mater. 2011, 21, 4633. doi: 10.1002/adfm.v21.24
8. [8]
  (8) Zhang,W.; Cheng, Y. M.; Yin, X.; Liu, B. Macromol. Chem. Phys. 2011, 212, 15. doi: 10.1002/macp.v212.1
9. [9]
  (9) Chung, I.; Lee, B.; He, J. Q.; Chang, R. P. H.; Kanatzidis, M. G.Nature 2012, 485, 486. doi: 10.1038/nature11067
10. [10]
  (10) Natu, G.; Huang, Z. J.; Ji, Z. Q.;Wu, Y. Y. Langmuir 2012, 28,950. doi: 10.1021/la203534s
11. [11]
  (11) Prakash, T.; Ramasamy, S. Sci. Adv. Mater. 2012, 4, 29. doi: 10.1166/sam.2012.1247
12. [12]
  (12) Yu, M. Z.; Natu, G.; Ji, Z. Q.;Wu, Y. Y. J. Phys. Chem. Lett.2012, 3, 1074. doi: 10.1021/jz3003603
13. [13]
  (13) Guo, X. Y.; Yi, P. F.;Wang,W. J.; Yang, Y. Acta Phys. -Chim. Sin. 2012, 28, 585. [郭学益, 易鹏飞, 王惟嘉, 杨英. 物理化学学报, 2012, 28, 585.] doi: 10.3866/PKU.WHXB201112302
14. [14]
  (14) Benedetti, J. E.; Correa, A. A.; Carmello, M.; Almeida, L. C. P.; ncalves, A. S.; Nogueira, A. F. J. Power Sources 2012, 208,263. doi: 10.1016/j.jpowsour.2012.01.147
15. [15]
  (15) Rachod, B.; Jutarat, S.; Nuttachai, P.; Pisorn, S. H.; Chaiyuth, S.K.; Pasit, P. Mater. Chem. Phys. 2012, 132, 993. doi: 10.1016/j.matchemphys.2011.12.048
16. [16]
  (16) Zhang, G. Q.; Ma, L.;Wu, Z. J.; Zhang, H. Y.; Ni, P. Acta Phys. -Chim. Sin. 2009, 25, 555. [张国庆, 马莉, 吴忠杰,张海燕, 倪佩. 物理化学学报, 2009, 25, 555.] doi: 10.3866/PKU.WHXB20090326
17. [17]
  (17) Stephan, A. M. Eur. Polym. J. 2006, 42, 21. doi: 10.1016/j.eurpolymj.2005.09.017
18. [18]
  (18) Pitawala, H. M. J. C.; Dissanayake, M. A. K. L.; Seneviratne, V.A. Solid State Ionics 2007, 178, 885. doi: 10.1016/j.ssi.2007.04.008
19. [19]
  (19) Lee, R. H.; Cheng, T. F.; Chang, J.W.; Ho, J. H. Colloid Polym. Sci. 2011, 289, 817. doi: 10.1007/s00396-011-2397-9
20. [20]
  (20) Zhang, D.W.; Li, X. D.; Huang, S. M.;Wang, Z. A.; Shi, J. H.;Sun, Z.; Yin, X. J. International Journal of Nanoscience 2010,9, 257. doi: 10.1142/S0219581X10006764
21. [21]
  (21) Basak, P.; Manorama, S. V. Eur. Polym. J. 2004, 40, 1155. doi: 10.1016/j.eurpolymj.2004.01.013
22. [22]
  (22) Kuo, P. L.; Hou, S. S.; Lin, C. Y.; Chen, C. C.;Wen, T. C.J. Polym. Sci. Pol. Chem. 2004, 42, 2051. doi: 10.1002/pola.20056
23. [23]
  (23) Kumar, M.; Sekhon, S. S. Eur. Polym. J. 2002, 38, 1297. doi: 10.1016/S0014-3057(01)00310-X
24. [24]
  (24) Han, H.W.; Liu,W.; Zhang, J.; Zhao, X. Z. Adv. Funct. Mater.2005, 15, 1940. doi: 10.1002/adfm.200500159
25. [25]
  (25) Zhou, Y. F.; Xiang,W. C.; Chen, S.; Fang, S. B.; Zhou, X.W.;Zhang, J. B.; Lin, Y. Chem. Commun. 2009, 3895.
26. [26]
  (26) Liang, G. J.; Xu, J.; Xu,W. L.; Shen, X. L.; Zhang, H.; Yao, M.Polym. Compos. 2011, 32, 511. doi: 10.1002/pc.v32.4
27. [27]
  (27) Cui, J. F.; Han, P. L.; Guo, J. H.; Yang, B. P.; Zhang, Z. L. China Synthetic Rubber Industry 2009, 32, 22. [崔锦峰, 韩培亮,郭军红, 杨保平, 张志立. 合成橡胶工业, 2009, 32, 22.]
28. [28]
  (28) Liang, G. J.; Xu,W. L.; Xu, J.; Shen, X. L.; Yao, M. InfluenceofWeight Ratio of Citric Acid Cross Linker on the Structureand Conductivity of the Crosslinked Polymer Electrolytes.In Advanced Materials Research, International Symposium onChemical Engineering and Material Properties, Shenyang,China, Nov 4-6, 2011; Zhang, H. M.,Wu, B., Eds.; Trans TechPublications Ltd: Switzerland, 2011; pp 391-392.
29. [29]
  (29) Liang, G. J.; Xu,W. L.; Shen, X. L.; Yang, H. J. Acta Energiae Solaris Sinica 2008, 29, 933. [梁桂杰, 徐卫林, 沈小林, 杨红军. 太阳能学报, 2008, 29, 933.]
30. [30]
  (30) Yu, M. X.; Shi, Q.; Zhou, X.; Yan, Y. S.;Wan, C. R. Acta Polym. Sin. 2001, 5, 665. [于明昕, 石桥, 周啸, 严玉顺, 万春荣.高分子学报, 2001, 5, 665.]
31. [31]
  (31) Liang, G. J.; Xu, J.; Xu,W. L.; Shen, X. L.; Bai, Z. K.; Yao, M.Polym. Eng. Sci. 2011, 51, 2526. doi: 10.1002/pen.v51.12
32. [32]
  (32) Kang, M. S.; Kim, J. H.;Won, J.; Kang, Y. S. J. Photochem. Photobiol. A-Chem. 2006, 183, 15. doi: 10.1016/j.jphotochem.2006.02.013
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