Citation: HAN Ying, ZHU Lu, SHEN Ming, LI Heng-Heng. Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic ld Nanoparticles with High Monodispersity[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 131-138. doi: 10.3866/PKU.WHXB201210082 shu

Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic ld Nanoparticles with High Monodispersity

1.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received Date: 14 August 2012
Available Online: 8 October 2012
Fund Project: 国家自然科学基金(21172190, 21273194) (21172190, 21273194)

3,4-Didodecyloxybenzylamine (DDOBA), a novel surfactant with two alkyl tail chains, was designed and synthesized. DDOBA-capped hydrophobic ld nanoparticles were successfully fabricated using formic acid as a reducing agent in a DDOBA/n-butanol/n-heptane/formic acid/HAuCl₄·4H₂O water/oil (W/O) microemulsion system under microwave irradiation. DDOBA-stabilized ld nanoparticles were characterized by ultraviolet-visible (UV-Vis) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), and X-ray diffraction (XRD). The experimental results showed that DDOBA not only participated in the formation of a stable W/O microemulsion system, but also became a od protecting agent for ld nanoparticles. Within an appropriate concentration range of components in the W/O microemulsion system, hydrophobic ld nanoparticles with high monodispersity can be obtained using this experimental method and automatically form large areas of ordered monolayer built with DDOBA-capped ld nanoparticles at the air/water interface.
- 3,4-Didodecyloxybenzylamine,
- Surfactant,
- W/O microemulsion,
- Hydrophobic ld nanoparticle,
- Formic acid,
- Microwave irradiation
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