Citation: HAN Ying, ZHU Lu, SHEN Ming, LI Heng-Heng. Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic ld Nanoparticles with High Monodispersity[J]. Acta Physico-Chimica Sinica, ;2013, 29(01): 131-138. doi: 10.3866/PKU.WHXB201210082 shu

Synthesis of a Novel Surfactant with Two Alkyl Tail-Chains (DDOBA) and Fabrication of Hydrophobic ld Nanoparticles with High Monodispersity

1.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China

Received Date: 14 August 2012
Available Online: 8 October 2012
Fund Project: 国家自然科学基金(21172190, 21273194) (21172190, 21273194)

3,4-Didodecyloxybenzylamine (DDOBA), a novel surfactant with two alkyl tail chains, was designed and synthesized. DDOBA-capped hydrophobic ld nanoparticles were successfully fabricated using formic acid as a reducing agent in a DDOBA/n-butanol/n-heptane/formic acid/HAuCl₄·4H₂O water/oil (W/O) microemulsion system under microwave irradiation. DDOBA-stabilized ld nanoparticles were characterized by ultraviolet-visible (UV-Vis) spectroscopy, transmission electron microscopy (TEM), high resolution transmission electron microscopy (HR-TEM), and X-ray diffraction (XRD). The experimental results showed that DDOBA not only participated in the formation of a stable W/O microemulsion system, but also became a od protecting agent for ld nanoparticles. Within an appropriate concentration range of components in the W/O microemulsion system, hydrophobic ld nanoparticles with high monodispersity can be obtained using this experimental method and automatically form large areas of ordered monolayer built with DDOBA-capped ld nanoparticles at the air/water interface.
- 3,4-Didodecyloxybenzylamine,
- Surfactant,
- W/O microemulsion,
- Hydrophobic ld nanoparticle,
- Formic acid,
- Microwave irradiation
1. [1]
  
  (1) Cortie, M. B.; McDonagh, A. M. Chem. Rev. 2011, 111, 3713.doi: 10.1021/cr1002529
2. [2]
  (2) Ke, S. L.; Kan, C. X.; Mo, B.; Cong, B.; Zhu, J. J. Acta Phys. -Chim. Sin. 2012, 28 (6), 1275. [柯善林, 阚彩侠,莫博, 从博, 朱杰君. 物理化学学报, 2012, 28 (6), 1275.]doi: 10.3866/PKU.WHXB201203162
3. [3]
  (3) Zhang, Y.; Cui, X. J.; Shi, F.; Deng, Y. Q. Chem. Rev. 2012, 112,2467. doi: 10.1021/cr200260m
4. [4]
  (4) Corma, A.; Garcia, H. Chem. Soc. Rev. 2008, 37 (9), 2096. doi: 10.1039/b707314n
5. [5]
  (5) Yen, C.W.; El-Sayed, M. A. J. Phys. Chem. C 2009, 113, 19585.doi: 10.1021/jp905186g
6. [6]
  (6) Herne, T. M.; Tarlov, M. J. J. Am. Chem. Soc. 1997, 119, 8916.doi: 10.1021/ja9719586
7. [7]
  (7) Rosi, N. L.; Mirkin, C. A. Chem. Rev. 2005, 105, 1547. doi: 10.1021/cr030067f
8. [8]
  (8) Chen, Y.; Gu, X.; Nie, C. G.; Jiang, Z. Y.; Xie, Z. X.; Lin, C. J.Chem. Commun. 2005, 4181.
9. [9]
  (9) Grzelczak, M.; Pérez-Juste, J.; Mulvaney, P.; Liz-Marzán, L. M.Chem. Soc. Rev. 2008, 37, 1783. doi: 10.1039/b711490g
10. [10]
  (10) Wang, C.; Daimon, H.; Onodera, T.; Koda, T.; Sun, S. H. Angew. Chem. Int. Edit. 2008, 47 (19), 3588.
11. [11]
  (11) Kochkar, H.; Aouine, M.; Ghorbel, A.; Berhault, G. J. Phys. Chem. C 2011, 115 (23), 11364. doi: 10.1021/jp200662j
12. [12]
  (12) Collier, C. P.; Saykally, R. J.; Shiang, J. J.; Henrichs, S. E.;Heath, J. R. Science 1997, 277, 1978. doi: 10.1126/science.277.5334.1978
13. [13]
  (13) Pena, S. R. N.; Raina, S.; odrich, G. P.; Fedoroff, N. V.;Keating, C. D. J. Am. Chem. Soc. 2002, 124 (25), 7314. doi: 10.1021/ja0177915
14. [14]
  (14) Brust, M.;Walker, M.; Bethell, D.; Schriffrin, D. J.; Whyman,R. J. Chem. Soc. Chem. Commun. 1994, 7, 801.
15. [15]
  (15) Fan, C. Y.; Jiang, L. Langmuir 1997, 13, 3059. doi: 10.1021/la960150g
16. [16]
  (16) Song, J.; Kim, D.; Lee, D. Langmuir 2011, 27, 13854. doi: 10.1021/la203113r
17. [17]
  (17) Shen, M.; Du, Y. K.; Hua, N. P.; Yang, P. Powder Tech. 2006,162, 64. doi: 10.1016/j.powtec.2005.09.007
18. [18]
  (18) Shen, M.; Du, Y. K.; Yang, P.; Jiang, L. J. Phys. Chem. Solids2005, 66, 1628. doi: 10.1016/j.jpcs.2005.05.078
19. [19]
  (19) Han, Y.; Li, H. H.; Shen, M.; Li, L.; Xu, G. Y. Acta Chimica Sinica 2010, 68 (18), 1813. [韩莹, 李恒恒, 沈明,李亮, 徐桂英. 化学学报, 2010, 68 (18), 1813.]
20. [20]
  (20) Yang, G. J.; Qu, X. L.; Shen, M.;Wang, C. Y.; Qu, Q. S.; Hu, X.Y. Sensors and Actuators B 2007, 128, 258. doi: 10.1016/j.snb.2007.06.005
21. [21]
  (21) Qu, Q. S.; Shen, F.; Shen, M.; Hu, X. Y.; Yang, G. J.;Wang, C.Y.; Yan, C.; Zhang, Y. K. Analytic Chimica Acta 2008, 609, 76.doi: 10.1016/j.aca.2007.12.031
22. [22]
  (22) Zhang, Y.W.; Zhou, H.; Liu, X. F.;Wang, J. F.; Shen, Z. X.Chinese Journal of Applied Chemistry 2003, 20 (1), 98. [张雅文, 周华, 刘小峰, 王建非, 沈宗旋. 应用化学, 2003, 20 (1),98.]
23. [23]
  (23) Norman, T. J.; Grant, C. D.; Magana, D.; Zhang, J. Z.; Liu, J.;Cao, D. L.; Bridges, F.; Buuren, A. V. J. Phys. Chem. B 2002,106, 7005. doi: 10.1021/jp0204197
24. [24]
  (24) Shen, M.; Yao, Y. F.; Zhang, J. G. Journal of Jiangsu University2010, 31 (4), 422. [沈明, 姚玉峰, 张金贵. 江苏大学学报,2010, 31 (4), 422.]
25. [25]
  (25) Aslan, K.; Perez-Luna, V. H. Langmuir 2002, 18, 6059. doi: 10.1021/la025795x
26. [26]
  (26) Nehl, C. L.; Liao, H.; Hafner, J. H. Nano Lett. 2006, 6, 683. doi: 10.1021/nl052409y
27. [27]
  (27) Bain, C. D.; Evall, J.; Whitesides, G. M. J. Am. Chem. Soc.1989, 111, 7155. doi: 10.1021/ja00200a039
28. [28]
  (28) Shen, M.; Du, Y. K.; Rong, H. L.; Li, J. R.; Jiang, L. Colloids and Surfaces A 2005, 257-258, 439.
1. [1]
  Yukai Jiang , Yihan Wang , Yunkai Zhang , Yunping Wei , Ying Ma , Na Du . Characterization and Phase Diagram of Surfactant Lyotropic Liquid Crystal. University Chemistry, 2024, 39(4): 114-118. doi: 10.3866/PKU.DXHX202309033
2. [2]
  Congying Lu , Fei Zhong , Zhenyu Yuan , Shuaibing Li , Jiayao Li , Jiewen Liu , Xianyang Hu , Liqun Sun , Rui Li , Meijuan Hu . Experimental Improvement of Surfactant Interface Chemistry: An Integrated Design for the Fusion of Experiment and Simulation. University Chemistry, 2024, 39(3): 283-293. doi: 10.3866/PKU.DXHX202308097
3. [3]
  Yongmin Zhang , Shuang Guo , Mingyue Zhu , Menghui Liu , Sinong Li . Design and Improvement of Physicochemical Experiments Based on Problem-Oriented Learning: a Case Study of Liquid Surface Tension Measurement. University Chemistry, 2024, 39(2): 21-27. doi: 10.3866/PKU.DXHX202307026
4. [4]
  Hexing SONG , Zan SUN . Synthesis, crystal structure, Hirshfeld surface analysis, and fluorescent sensing for Fe³⁺ of an Mn(Ⅱ) complex based on 1-naphthalic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 885-892. doi: 10.11862/CJIC.20240402
5. [5]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
6. [6]
  Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
7. [7]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
8. [8]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . Femtosecond transient absorption spectroscopy investigation on ultrafast electron transfer in S-scheme ZnO/CdIn₂S₄ photocatalyst for H₂O₂ production and benzylamine oxidation. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-0. doi: 10.1016/j.actphy.2025.100064
9. [9]
  Yahui HAN , Jinjin ZHAO , Ning REN , Jianjun ZHANG . Synthesis, crystal structure, thermal decomposition mechanism, and fluorescence properties of benzoic acid and 4-hydroxy-2, 2′: 6′, 2″-terpyridine lanthanide complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 969-982. doi: 10.11862/CJIC.20240395
10. [10]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
11. [11]
  Juan Guo , Mingyuan Fang , Qingsong Liu , Xiao Ren , Yongqiang Qiao , Mingju Chao , Erjun Liang , Qilong Gao . Zero thermal expansion in Cs₂W₃O₁₀. Chinese Chemical Letters, 2024, 35(7): 108957-. doi: 10.1016/j.cclet.2023.108957
12. [12]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
13. [13]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
14. [14]
  Min LI , Xianfeng MENG . Preparation and microwave absorption properties of ZIF-67 derived Co@C/MoS₂ nanocomposites. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1932-1942. doi: 10.11862/CJIC.20240065
15. [15]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
16. [16]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
17. [17]
  Yan ZHAO , Jiaxu WANG , Zhonghu LI , Changli LIU , Xingsheng ZHAO , Hengwei ZHOU , Xiaokang JIANG . Gd³⁺-doped Sc₂W3O₁₂: Eu³⁺ red phosphor: Preparation and luminescence performance. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 461-468. doi: 10.11862/CJIC.20240316
18. [18]
  Jianding LI , Junyang FENG , Huimin REN , Gang LI . Proton conductive properties of a Hf(Ⅳ)-based metal-organic framework built by 2,5-dibromophenyl-4,6-dicarboxylic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1094-1100. doi: 10.11862/CJIC.20240464
19. [19]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
20. [20]
  Wei Li , Guoqiang Feng , Ze Chang . Teaching Reform of X-ray Diffraction Using Synchrotron Radiation in Materials Chemistry. University Chemistry, 2024, 39(3): 29-35. doi: 10.3866/PKU.DXHX202308060

Get Citation

PDF

XML

Metrics

PDF Downloads(809)
Abstract views(3386)
HTML views(16)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142