Citation: YU Zhi-Hui, SU Ting-Ting, REN Cui-Hua, LI Fan, XIA Ding-Guo, CHENG Shui-Yuan. Direct Electrochemistry and Immobilization of Glucose Oxidase on Nano-Carbon Aerogels[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209201 shu

Direct Electrochemistry and Immobilization of Glucose Oxidase on Nano-Carbon Aerogels

1.
1 College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, P. R. China;
2 College of Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 23 July 2012
Available Online: 20 September 2012
Fund Project: 国家自然科学基金(50974006) (50974006)北京市教委科研计划面上项目(KM201210005008) (KM201210005008)北京市人才强教深化计划-创新团队(PHR201007105)资助 (PHR201007105)

Nano-carbon aerogels (CA) were prepared by the reaction between resorcinol and formaldehyde in alkaline conditions. The morphology and microstructure of the CA was investigated by scanning electron microscopy and transmission electron microscopy. The specific area and the pore size distribution were calculated from the N₂ adsorption-desorption isotherm. Glucose oxidase ( D)/CA/ glassy carbon (GC) electrodes were prepared by immobilizing D on the surface of nano-carbon aerogels. The electrocatalytic properties of D/CA/GC electrodes were characterized by cyclic voltammetry in phosphate buffer medium (0.1 mol·L^-1). The results showed that D can be immobilized on the nano-carbon aerogels, and that the biological activation of D was retained. The D/CA/GC electrode exhibits od direct electrochemical and electro-catalytic performance without electron mediators.
- Carbon aerogel,
- Glucose oxidase,
- Direct electrochemistry
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沈阳化工大学材料科学与工程学院沈阳 110142