Citation: CHEN Wen-Long, LIU Hai-Chao. Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2315-2326. doi: 10.3866/PKU.WHXB201209146 shu

Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Green Chemistry Center, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 4 September 2012
Available Online: 14 September 2012
Fund Project: 国家自然科学基金(20825310, 20973011) (20825310, 20973011)国家重点基础研究发展规划项目(973) (2011CB201400, 2011CB808700)资助 (973) (2011CB201400, 2011CB808700)

Methanol is an important platform molecule for the production of energy and chemicals. For its efficient utilization, it is of critical significance to clarify the relationship between the structures of the catalysts and their performance as well as the corresponding reaction mechanisms. In this review, we summarized some recent progress in the understanding of the active structures of several metal oxide-based catalysts and the reaction mechanism, and the consequent tuning of their redox and acid sites for the selective oxidation of methanol. The catalysts included supported molybdenum oxides, supported vanadium oxides, and heteropolyacids with Keggin structures as well as rhenium oxides and ruthenium oxides recently explored for the methanol oxidation. Such progress provides insights into the design of novel catalysts more efficient for the oxidative conversion of methanol towards the targeted products.
- Methanol,
- Selective oxidation,
- Redox site,
- Acid site,
- Structure-activity relationship
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