Citation: CHEN Wen-Long, LIU Hai-Chao. Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2315-2326. doi: 10.3866/PKU.WHXB201209146 shu

Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Methanol

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Green Chemistry Center, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 4 September 2012
Available Online: 14 September 2012
Fund Project: 国家自然科学基金(20825310, 20973011) (20825310, 20973011)国家重点基础研究发展规划项目(973) (2011CB201400, 2011CB808700)资助 (973) (2011CB201400, 2011CB808700)

Methanol is an important platform molecule for the production of energy and chemicals. For its efficient utilization, it is of critical significance to clarify the relationship between the structures of the catalysts and their performance as well as the corresponding reaction mechanisms. In this review, we summarized some recent progress in the understanding of the active structures of several metal oxide-based catalysts and the reaction mechanism, and the consequent tuning of their redox and acid sites for the selective oxidation of methanol. The catalysts included supported molybdenum oxides, supported vanadium oxides, and heteropolyacids with Keggin structures as well as rhenium oxides and ruthenium oxides recently explored for the methanol oxidation. Such progress provides insights into the design of novel catalysts more efficient for the oxidative conversion of methanol towards the targeted products.
- Methanol,
- Selective oxidation,
- Redox site,
- Acid site,
- Structure-activity relationship
1. [1]
  
  (1) Olah, G. A.; Molnár, Á. Hydrocarbon Chemistry, 2nd ed.; JohnWiley & Sons: Hoboken, New Jersey, 2003; pp 114-117.
2. [2]
  (2) Xu, X. D.; Moulijn, J. A. Energy & Fuels 1996, 10, 305. doi: 10.1021/ef9501511
3. [3]
  (3) Hamelinck, C. N.; Faaij, A. P. C. J. Power Sources 2002, 111, 1.doi: 10.1016/S0378-7753(02)00220-3
4. [4]
  (4) Olah, G. A.; eppert, A.; Prakash, G. K. S. Beyond Oil and Gas: The Methanol Economy;Wiley-VCH:Weinheim, 2009; pp168-173.
5. [5]
  (5) Deo, G.;Wachs, I. E. J. Catal. 1994, 146, 323. doi: 10.1006/jcat.1994.1071
6. [6]
  (6) Hu, H. C.;Wachs, I. E. J. Phys. Chem. 1995, 99, 10911. doi: 10.1021/j100027a035
7. [7]
  (7) Yuan, Y. Z.; Iwasawa, Y. J. Phys. Chem. B 2002, 106, 4441. doi: 10.1021/jp013770l
8. [8]
  (8) Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2005, 109, 2155. doi: 10.1021/jp0401980
9. [9]
  (9) Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2003, 107, 10840. doi: 10.1021/jp0301554
10. [10]
  (10) Tatibouet, J. M. Appl. Catal. A-Gen. 1997, 148, 213. doi: 10.1016/S0926-860X(96)00236-0
11. [11]
  (11) Badlani, M.;Wachs, I. E. Catal. Lett. 2001, 75, 137. doi: 10.1023/A:1016715520904
12. [12]
  (12) Wachs, I. E. Catal. Today 2005, 100, 79. doi: 10.1016/j.cattod.2004.12.019
13. [13]
  (13) Oyama, S. T.; Radhakrishnan, R.; Seman, M.; Kondo, J. N.;Domen, K.; Asakura, K. J. Phys. Chem. B 2003, 107, 1845. doi: 10.1021/jp0220276
14. [14]
  (14) Vitry, D.; Morikawa, Y.; Dubois, J. L.; Ueda,W. Appl. Catal. A-Gen. 2003, 251, 411. doi: 10.1016/S0926-860X(03)00381-8
15. [15]
  (15) Cavani, F.; Trifiro, F. Catal. Today 1995, 24, 307. doi: 10.1016/0920-5861(95)00051-G
16. [16]
  (16) Chen, K. D.; Xie, S. B.; Bell, A. T.; Iglesia, E. J. Catal. 2001,198, 232. doi: 10.1006/jcat.2000.3125
17. [17]
  (17) Tsilomelekis, G.; Boghosian, S. J. Phys. Chem. C 2011, 115,2146. doi: 10.1021/jp1098987
18. [18]
  (18) Chempath, S.; Zhang, Y. H.; Bell, A. T. J. Phys. Chem. C 2007,111, 1291. doi: 10.1021/jp064741j
19. [19]
  (19) Lee, E. L.;Wachs, I. E. J. Phys. Chem. C 2007, 111, 14410. doi: 10.1021/jp0735482
20. [20]
  (20) Tsilomelekis, G.; Boghosian, S. Phys. Chem. Chem. Phys. 2012,14, 2216.
21. [21]
  (21) Handzlik, J.; Sautet, P. J. Phys. Chem. C 2008, 112, 14456. doi: 10.1021/jp802372e
22. [22]
  (22) Liu, H. C.; Cheung, P.; Iglesia, E. J. Catal. 2003, 217, 222.
23. [23]
  (23) Christodoulakis, A.; Heracleous, E.; Lemonidou, A. A.;Boghosian, S. J. Catal. 2006, 242, 16. doi: 10.1016/j.jcat.2006.05.024
24. [24]
  (24) Li,W. Z.; Huang, H.; Li, H. J.; Zhang,W.; Liu, H. C. Langmuir2008, 24, 8358. doi: 10.1021/la800370r
25. [25]
  (25) Hamraoui, K.; Cristol, S.; Payen, E.; Paul, J. F. J. Mol. Struct. - Theochem 2009, 903, 73. doi: 10.1016/j.theochem.2008.09.044
26. [26]
  (26) Chen, K. D.; Bell, A. T.; Iglesia, E. J. Catal. 2002, 209, 35. doi: 10.1006/jcat.2002.3620
27. [27]
  (27) Liu, H. C.; Cheung, P.; Iglesia, E. J. Phys. Chem. B 2003, 107,4118. doi: 10.1021/jp0221744
28. [28]
  (28) Brandhorst, M.; Cristol, S.; Capron, M.; Dujardin, C.; Vezin, H.;Le bourdon, G.; Payen, E. Catal. Today 2006, 113, 34. doi: 10.1016/j.cattod.2005.11.008
29. [29]
  (29) Aritani, H.; Fukuda, O.; Miyaji, A.; Hasegawa, S. Appl. Surf. Sci. 2001, 180, 261. doi: 10.1016/S0169-4332(01)00366-X
30. [30]
  (30) Tsilomelekis, G.; Christodoulakis, A.; Boghosian, S. Catal. Today 2007, 127, 139. doi: 10.1016/j.cattod.2007.03.026
31. [31]
  (31) Zhang, S. H.; Zhang, H. P.; Li,W. Z.; Zhang,W.; Huang, H.;Liu, H. C. Acta Phys. -Chim. Sin. 2010, 26, 1879. [张胜红,张鸿鹏, 李为臻, 张伟, 黄华, 刘海超. 物理化学学报,2010, 26, 1879.] doi: 10.3866/PKU.WHXB20100732
32. [32]
  (32) Shannon, I. J.; Maschmeyer, T.; Oldroyd, R. D.; Sankar, G.;Thomas, J. M.; Pernot, H.; Balikdjian, J. P.; Che, M. J. Chem. Soc. Faraday Trans. 1998, 94, 1495. doi: 10.1039/a800054i
33. [33]
  (33) Grabowski, R.; Grzybowska, B.; Haber, J.; Sloczynski, J. React. Kinet. Catal. Lett. 1975, 2, 81. doi: 10.1007/BF02060956
34. [34]
  (34) Wachs, I. E.; Saleh, R. Y.; Chan, S. S.; Chersich, C. C. Appl. Catal. 1985, 15, 339. doi: 10.1016/S0166-9834(00)81848-5
35. [35]
  (35) Blasco, T.; Lopez-Nieto, J. M. Appl. Catal. A-Gen. 1997, 157,117. doi: 10.1016/S0926-860X(97)00029-X
36. [36]
  (36) Cavalli, P.; Cavani, F.; Manenti, I.; Trifiro, F. Catal. Today 1987,1, 245. doi: 10.1016/0920-5861(87)80043-3
37. [37]
  (37) Kumar, C. P.; Reddy, K. R.; Rao, V. V.; Chary, K. V. R. Green Chem. 2002, 4, 513. doi: 10.1039/b206581a
38. [38]
  (38) Olthof, B.; Khodakov, A.; Bell, A. T.; Iglesia, E. J. Phys. Chem. B 2000, 104, 1516. doi: 10.1021/jp9921248
39. [39]
  (39) Bronkema, J. L.; Leo, D. C.; Bell, A. T. J. Phys. Chem. C 2007,111, 14530. doi: 10.1021/jp073826x
40. [40]
  (40) Bronkema, J. L.; Bell, A. T. J. Phys. Chem. C 2008, 112, 6404.doi: 10.1021/jp7110692
41. [41]
  (41) Tanaka, T.; Yamashita, H.; Tsuchitani, R.; Funabiki, T.; Yoshida,S. J. Chem. Soc. Faraday Trans. 1988, 84, 2987. doi: 10.1039/f19888402987
42. [42]
  (42) Eckert, H.;Wachs, I. E. J. Phys. Chem. 1989, 93, 6796. doi: 10.1021/j100355a043
43. [43]
  (43) Weckhuysen, B. M.; Jehng, J. M.;Wachs, I. E. J. Phys. Chem. B2000, 104, 7382. doi: 10.1021/jp000055n
44. [44]
  (44) Busca, G. J. Mol. Catal. 1989, 50, 241.
45. [45]
  (45) Gao, X. T.; Bare, S. R.;Weckhuysen, B. M.;Wachs, I. E.J. Phys. Chem. B 1998, 102, 10842. doi: 10.1021/jp9826367
46. [46]
  (46) Shapovalov, V.; Metiu, H. J. Phys. Chem. C 2007, 111, 14179.doi: 10.1021/jp074481l
47. [47]
  (47) Vining,W. C.; Strunk, J.; Bell, A. T. J. Catal. 2012, 285, 160.doi: 10.1016/j.jcat.2011.09.024
48. [48]
  (48) Ganduglia-Pirovano, M. V.; Popa, C.; Sauer, J.; Abbott, H.; Uhl,A.; Baron, M.; Stacchiola, D.; Bondarchuk, O.; Shaikhutdinov,S.; Freund, H. J. J. Am. Chem. Soc. 2010, 132, 2345. doi: 10.1021/ja910574h
49. [49]
  (49) Burcham, L. J.;Wachs, I. E. Catal. Today 1999, 49, 467. doi: 10.1016/S0920-5861(98)00442-8
50. [50]
  (50) Burcham, L. J.; Badlani, M.;Wachs, I. E. J. Catal. 2001, 203,104. doi: 10.1006/jcat.2001.3312
51. [51]
  (51) Bronkema, J. L.; Bell, A. T. J. Phys. Chem. C 2007, 111, 420.doi: 10.1021/jp0653149
52. [52]
  (52) odrow, A.; Bell, A. T. J. Phys. Chem. C 2007, 111, 14753.doi: 10.1021/jp072627a
53. [53]
  (53) Vining,W. C.; Strunk, J.; Bell, A. T. J. Catal. 2011, 281, 222.doi: 10.1016/j.jcat.2011.05.001
54. [54]
  (54) Weber, R. S. J. Phys. Chem. 1994, 98, 2999. doi: 10.1021/j100062a042
55. [55]
  (55) Kim, H. Y.; Lee, H. M.; Pala, R. G. S.; Metiu, H. J. Phys. Chem. C 2009, 113, 16083. doi: 10.1021/jp903298w
56. [56]
  (56) Abbott, H. L.; Uhl, A.; Baron, M.; Lei, Y.; Meyer, R. J.;Stacchiola, D. J.; Bondarchuk, O.; Shaikhutdinov, S.; Freund,H. J. J. Catal. 2010, 272, 82. doi: 10.1016/j.jcat.2010.03.009
57. [57]
  (57) Gao, X. T.;Wachs, I. E. Top. Catal. 2002, 18, 243. doi: 10.1023/A:1013842722877
58. [58]
  (58) odrow, A.; Bell, A. T. J. Phys. Chem. C 2008, 112, 13204.doi: 10.1021/jp801339q
59. [59]
  (59) Holstein,W. L.; Machiels, C. J. J. Catal. 1996, 162, 118. doi: 10.1006/jcat.1996.0265
60. [60]
  (60) Jackson, S. D.; Hargreaves, J. S. J. Metal Oxide Catalysis;Wiley-VCH:Weinheim, 2009; pp 487-498.
61. [61]
  (61) Khaliullin, R. Z.; Bell, A. T. J. Phys. Chem. B 2002, 106, 7832.doi: 10.1021/jp014695h
62. [62]
  (62) Dobler, J.; Pritzsche, M.; Sauer, J. J. Am. Chem. Soc. 2005, 127,10861. doi: 10.1021/ja051720e
63. [63]
  (63) Gao, X. T.; Bare, S. R.; Fierro, J. L. G.;Wachs, I. E. J. Phys. Chem. B 1999, 103, 618. doi: 10.1021/jp983357m
64. [64]
  (64) Gao, X. T.; Fierro, J. L. G.;Wachs, I. E. Langmuir 1999, 15,3169. doi: 10.1021/la981254p
65. [65]
  (65) Gao, X. T.;Wachs, I. E. J. Catal. 2000, 192, 18. doi: 10.1006/jcat.2000.2822
66. [66]
  (66) Fubini, B.; Bolis, V.; Cavena , A.; Garrone, E.; Uglien , P.Langmuir 1993, 9, 2712. doi: 10.1021/la00034a034
67. [67]
  (67) Feng, T.; Vohs, J. M. J. Catal. 2004, 221, 619. doi: 10.1016/j.jcat.2003.10.002
68. [68]
  (68) Zhanpeisov, N. U.; Fukumura, H. J. Phys. Chem. C 2007, 111,16941. doi: 10.1021/jp074869g
69. [69]
  (69) Eder, D.; Kramer, R. Phys. Chem. Chem. Phys. 2003, 5, 1314.
70. [70]
  (70) Strunk, J.; Vining,W. C.; Bell, A. T. J. Phys. Chem. C 2010,114, 16937. doi: 10.1021/jp100104d
71. [71]
  (71) Kim, H. Y.; Lee, H. M.; Metiu, H. J. Phys. Chem. C 2010, 114,13736. doi: 10.1021/jp103361v
72. [72]
  (72) Vining,W. C.; odrow, A.; Strunk, J.; Bell, A. T. J. Catal.2010, 270, 163. doi: 10.1016/j.jcat.2009.12.017
73. [73]
  (73) Ross-Medgaarden, E. I.;Wachs, I. E.; Knowles,W. V.; Burrows,A.; Kiely, C. J.;Wong, M. S. J. Am. Chem. Soc. 2009, 131, 680.doi: 10.1021/ja711456c
74. [74]
  (74) Masamoto, J.; Iwaisako, T.; Chohno, M.; Kawamura, M.;Ohtake, J.; Matsuzaki, K. J. Appl. Polym. Sci. 1993, 50, 1299.doi: 10.1002/app.1993.070500801
75. [75]
  (75) Zhang, Q. D.; Tan, Y. S.; Yang, C. H.; Han, Y. Z. J. Mol. Catal. A-Chem. 2007, 263, 149. doi: 10.1016/j.molcata.2006.08.044
76. [76]
  (76) Lambiotte, G. New Process for Continuous Production ofMethylal. CH Patent 688041, 1997.
77. [77]
  (77) Satoh, S.; Tanigawa, Y. Process for Producing Methylal. USPatent 6 379 507, 2002.
78. [78]
  (78) Yuan, Y. Z.; Liu, H. C.; Imoto, H.; Shido, T.; Iwasawa, Y.J. Catal. 2000, 195, 51. doi: 10.1006/jcat.2000.2990
79. [79]
  (79) Yuan, Y. Z.; Shido, T.; Iwasawa, Y. Chem. Commun. 2000, No.15, 1421.
80. [80]
  (80) Zhang, Y. H.; Drake, I. J.; Briggs, D. N.; Bell, A. T. J. Catal.2006, 244, 219. doi: 10.1016/j.jcat.2006.09.002
81. [81]
  (81) Royer, S.; Secordel, X.; Brandhorst, M.; Dumeignil, F.; Cristol,S.; Dujardin, C.; Capron, M.; Payena, E.; Dubois, J. L. Chem. Commun. 2008, No. 7, 865.
82. [82]
  (82) rnay, J.; Secordel, X.; Tesquet, G.; de Menorval, B.; Cristol,S.; Fongarland, P.; Capron, M.; Duhamel, L.; Payen, E.;Dubois, J. L.; Dumeignil, F. Green Chem. 2010, 12, 1722. doi: 10.1039/c0gc00194e
83. [83]
  (83) Fu, Y. C.; Shen, J. Y. Chem. Commun. 2007, No. 21, 2172.
84. [84]
  (84) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. J. Catal. 2010,272, 176. doi: 10.1016/j.jcat.2010.02.028
85. [85]
  (85) Zhao, H. Y.; Bennici, S.; Cai, J. X.; Shen, J. Y.; Auroux, A.J. Catal. 2010, 274, 259. doi: 10.1016/j.jcat.2010.07.011
86. [86]
  (86) Dunn, J. P.; Jehng, J. M.; Kim, D. S.; Briand, L. E.; Stenger, H.G.;Wachs, I. E. J. Phys. Chem. B 1998, 102, 6212. doi: 10.1021/jp9814247
87. [87]
  (87) Guo, H. Q.; Li, D. B.; Jiang, D.; Li,W. H.; Sun, Y. H. Catal. Commun. 2010, 11, 396. doi: 10.1016/j.catcom.2009.11.009
88. [88]
  (88) Lu, X. L.; Qin, Z. F.; Dong, M.; Zhu, H. Q.;Wang, G. F.;Zhao, Y. B.; Fan,W. B.;Wang, J. G. Fuel 2011, 90, 1335. doi: 10.1016/j.fuel.2011.01.007
89. [89]
  (89) Chen, S.;Wang, S. P.; Ma, X. B.; ng, J. L. Chem. Commun.2011, No. 47, 9345.
90. [90]
  (90) Sun, Q.; Liu, J.W.; Cai, J. X.; Fu, Y. C.; Shen, J. Y. Catal. Commun. 2009, 11, 47. doi: 10.1016/j.catcom.2009.08.010
91. [91]
  (91) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. Appl. Catal. A-Gen. 2010, 385, 224. doi: 10.1016/j.apcata.2010.07.017
92. [92]
  (92) Zhao, H. Y.; Bennici, S.; Shen, J. Y.; Auroux, A. J. Therm. Anal. Calorim. 2010, 99, 843. doi: 10.1007/s10973-009-0499-0
93. [93]
  (93) Misono, M. Chem. Commun. 2001, No. 13, 1141.
94. [94]
  (94) Okuhara, T.; Mizuno, N.; Misono, M. Appl. Catal. A-Gen.2001, 222, 63. doi: 10.1016/S0926-860X(01)00830-4
95. [95]
  (95) Damyanova, S.; Cubeiro, M. L.; Fierro, J. L. G. J. Mol. Catal. A-Chem. 1999, 142, 85. doi: 10.1016/S1381-1169(98)00279-9
96. [96]
  (96) Liu, H. C.; Bayat, N.; Iglesia, E. Angew. Chem. Int. Edit. 2003,42, 5072. doi: 10.1002/(ISSN)1521-3773
97. [97]
  (97) Liu, H. C.; Iglesia, E. J. Catal. 2004, 223, 161.
98. [98]
  (98) Guo, H. Q.; Li, D. B.; Xiao, H. C.; Zhang, J. L.; Li,W. H.;Sun, Y. H. Kor. J. Chem. Eng. 2009, 26, 902. doi: 10.1007/s11814-009-0151-5
99. [99]
  (99) Nakka, L.; Molinari, J. E.;Wachs, I. E. J. Am. Chem. Soc.2009, 131, 15544. doi: 10.1021/ja904957d
100. [100]
  (100) Molinari, J. E.; Nakka, L.; Kim, T.;Wachs, I. E. ACS Catal.2011, 1, 1536. doi: 10.1021/cs2001362
101. [101]
  (101) Mol, J. C. Catal. Today 1999, 51, 289. doi: 10.1016/S0920-5861(99)00051-6
102. [102]
  (102) Liu, H. C.; Gaigneaux, E. M.; Imoto, H.; Shido, T.; Iwasawa,Y. Appl. Catal. A-Gen. 2000, 202, 251. doi: 10.1016/S0926-860X(00)00539-1
103. [103]
  (103) Wachs, I. E.; Deo, G.; Andreini, A.; Vuurman, M. A.; deBoer,M. J. Catal. 1996, 160, 322. doi: 10.1006/jcat.1996.0152
104. [104]
  (104) Yuan, Y. Z.; Tsai, K. R.; Liu, H. C.; Iwasawa, Y. Top. Catal.2003, 22, 9. doi: 10.1023/A:1021451309465
105. [105]
  (105) Lee, E. L.;Wachs, I. E. J. Phys. Chem. C 2008, 112, 6487. doi: 10.1021/jp076485w
106. [106]
  (106) Lacheen, H. S.; Cordeiro, P. J.; Iglesia, E. J. Am. Chem. Soc.2006, 128, 15082. doi: 10.1021/ja065832x
107. [107]
  (107) Lacheen, H. S.; Cordeiro, P. J.; Iglesia, E. Chem.-Eur. J. 2007,13, 3048. doi: 10.1002/(ISSN)1521-3765
108. [108]
  (108) Nikonova, O. A.; Capron, M.; Fang, G.; Faye, J.; Mamede, A.S.; Jalowiecki-Duhamel, L.; Dumeignil, F.; Seisenbaeva, G. A.J. Catal. 2011, 279, 310. doi: 10.1016/j.jcat.2011.01.028
109. [109]
  (109) Tougerti, A.; Cristol, S.; Berrier, E.; Briois, V.; La Fontaine, C.;Villain, F.; Joly, Y. Phys. Rev. B 2012, 85 (12), 125136. doi: 10.1103/PhysRevB.85.125136
110. [110]
  (110) Yang, T. J.; Lunsford, J. H. J. Catal. 1987, 103, 55. doi: 10.1016/0021-9517(87)90092-3
111. [111]
  (111) Chan, A. S. Y.; Chen,W. H.;Wang, H.; Rowe, J. E.; Madey, T.E. J. Phys. Chem. B 2004, 108, 14643. doi: 10.1021/jp040168x
112. [112]
  (112) Liu, J. L.; Zhan, E. S.; Cai,W. J.; Li, J.; Shen,W. J. Catal. Lett.2008, 120, 274. doi: 10.1007/s10562-007-9280-9
113. [113]
  (113) Hardcastle, F. D.;Wachs, I. E.; Horsley, J. A.; Via, G. H.J. Mol. Catal. 1988, 46, 15. doi: 10.1016/0304-5102(88)85081-8
114. [114]
  (114) Albonetti, S.; Cavani, F.; Trifiro, F. Catal. Rev.-Sci. Eng. 1996,38, 413. doi: 10.1080/01614949608006463
115. [115]
  (115) Secordel, X.; Yoboue, A.; Cristol, S.; Lancelot, C.; Capron, M.;Paul, J. F.; Berrier, E. J. Solid State Chem. 2011, 184, 2806.doi: 10.1016/j.jssc.2011.08.002
116. [116]
  (116) Zang, L.; Kisch, H. Angew. Chem. Int. Edit. 2000, 39, 3921.doi: 10.1002/(ISSN)1521-3773
117. [117]
  (117) Zhan, B. Z.; White, M. A.; Sham, T. K.; Pincock, J. A.; Doucet,R. J.; Rao, K. V. R.; Robertson, K. N.; Cameron, T. S. J. Am. Chem. Soc. 2003, 125, 2195. doi: 10.1021/ja0282691
118. [118]
  (118) Zhan, B. Z.; White, M. A.; Pincock, J. A.; Robertson, K. N.;Cameron, T. S.; Sham, T. K. Can. J. Chem. -Rev. Can. Chim.2003, 81, 764. doi: 10.1139/v03-060
119. [119]
  (119) Li,W. Z.; Liu, H. C.; Iglesia, E. J. Phys. Chem. B 2006, 110,23337. doi: 10.1021/jp0648689
120. [120]
  (120) Lee, J. S.; Kim, J. C.; Kim, Y. G. Appl. Catal. 1990, 57, 1. doi: 10.1016/S0166-9834(00)80720-4
121. [121]
  (121) Jenner, G. Appl. Catal. A-Gen. 1995, 121, 25.
122. [122]
  (122) Huang, H.; Li,W. Z.; Liu, H. C. Catal. Today 2012, 183, 58.doi: 10.1016/j.cattod.2011.05.021
123. [123]
  (123) Lichtenberger, J.; Lee, D.; Iglesia, E. Phys. Chem. Chem. Phys.2007, 9, 4902.
124. [124]
  (124) Wittstock, A.; Zielasek, V.; Biener, J.; Friend, C. M.; Baumer,M. Science 2010, 327, 319. doi: 10.1126/science.1183591
125. [125]
  (125) Zhan, B. Z.; Iglesia, E. Angew. Chem. Int. Edit. 2007, 46, 3697.doi: 10.1002/(ISSN)1521-3773
126. [126]
  (126) Yu, H.; Zeng, K.; Fu, X. B.; Zhang, Y.; Peng, F.;Wang, H. J.;Yang, J. J. Phys. Chem. C 2008, 112, 11875. doi: 10.1021/jp804003g
1. [1]
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