Citation:
JIAO Shu-Hong, XU Dong-Sheng, XU Li-Fen, ZHANG Xiao-Guang. Recent Progress in Electrochemical Synthesis and Morphological Control of Metal Oxide Nanostructures[J]. Acta Physico-Chimica Sinica,
;2012, 28(10): 2436-2446.
doi:
10.3866/PKU.WHXB201209145
-
There has been considerable focus on the synthesis of metal oxide nanostructures because of their extensive structures, unique properties, and wide applications. The morphological control of metal oxide nanostructures is of interest for tuning their performance and expanding their range of applications. Electrochemical methods have become a common way of controlling the morphologies of metal oxides, owing to their simple operation, ease of control, and flexible modes. This paper presents a brief overview of our research in the electrochemical synthesis and morphological control of metal oxide nanostructures. We will also discuss the crystal growth mechanism and the morphology control of different metal oxides during the electrochemical deposition process, which lays the foundation for orientation design and fabrication of functional materials.
-
-
-
[1]
(1) Wang, Z. L. Nanowires and Nanobelts: Materials, Properties and Devices; Kluwer: Dordrecht, 2003.
-
[2]
(2) Nalwa, H. S. Encyclopedia of Nanoscience and Nanotechnology; American Scientific Publishers: New York,2004.
-
[3]
(3) Alivisatos, A. P. Science 1996, 271, 933. doi: 10.1126/science.271.5251.933
-
[4]
(4) Xia, Y.; Yang, P.; Sun, Y.;Wu, Y.; Mayers, B.; Gates, B.; Yin, Y.;Kim, F.; Yan, H. Adv. Mater. 2003, 15, 353. doi: 10.1002/adma.200390087
-
[5]
(5) El-Sayed, M. A. Accounts Chem. Res. 2001, 34, 257. doi: 10.1021/ar960016n
-
[6]
(6) Jun, Y.W.; Choi, J. S.; Cheon, J.W. Angew. Chem. Int. Edit.2006, 45, 3414. doi: 10.1002/(ISSN)1521-3773
-
[7]
(7) Jiang, P.; Bertone, J. F.; Colvin, V. L. Science 2001, 291, 453.doi: 10.1126/science.291.5503.453
-
[8]
(8) Huang, Y.; Duan, X.; Cui, Y.; Lauhon, L.; Kim, K.; Lieber, C.M. Science 2001, 294, 1313. doi: 10.1126/science.1066192
-
[9]
(9) Duan, X.; Huang, Y.; Lieber, C. M. Nano Lett. 2002, 2, 487. doi: 10.1021/nl025532n
-
[10]
(10) Duan, M.; Lai, X.; odman, D.W. Science 1998, 281, 1647.doi: 10.1126/science.281.5383.1647
-
[11]
(11) Sun, S.; Murray, C. B.;Weller, D.; Folks, L.; Moser, A. Science2000, 287, 1989. doi: 10.1126/science.287.5460.1989
-
[12]
(12) Jiao, S. H.; Xu, L. F.; Jiang, K.; Xu, D. S. Adv. Mater. 2006, 18,1174. doi: 10.1002/(ISSN)1521-4095
-
[13]
(13) Liang, Y. Q.; Zhen, C. G.; Zou, D. C.; Xu, D. S. J. Am. Chem. Soc. 2004, 126, 16338. doi: 10.1021/ja044545v
-
[14]
(14) Yu,W. D.; Li, X. M.; Gao, X. D. Appl. Phys. Lett. 2004, 84,2658. doi: 10.1063/1.1695097
-
[15]
(15) Fan,W. L.; Song, X. Y.; Bu, Y. X.; Sun, S. X.; Zhao, X. J. Phys. Chem. B 2006, 110, 23247. doi: 10.1021/jp0646832
-
[16]
(16) Miao, Z.; Xu, D. S.; Ouyang, J. H.; Guo, G. L.; Zhao, X. S.;Tang, Y. Q. Nano Lett. 2002, 2, 717. doi: 10.1021/nl025541w
-
[17]
(17) Takahashi, K.; Limmer, S. J.;Wang, Y.; Cao, G. Z. J. Phys. Chem. B 2004, 108, 9795. doi: 10.1021/jp0491820
-
[18]
(18) Yang, J. H.; Liu, G. M.; Lu, J.; Qiu, Y. F.; Yang, S. H. Appl. Phys. Lett. 2007, 90, 103109. doi: 10.1063/1.2711532
-
[19]
(19) She, G.W.; Zhang, X. H.; Shi,W. S.; Fan, X.; Chang, J. C.Electrochem. Commun. 2007, 9, 2784. doi: 10.1016/j.elecom.2007.09.019
-
[20]
(20) Siegfried, M. J.; Choi, K. S. Angew. Chem. Int. Edit. 2005, 44,3218. doi: 10.1002/(ISSN)1521-3773
-
[21]
(21) Guo, S. J.; Fang, Y. X.; Dong, S. J.;Wang, E. K. Inorg. Chem.2007, 46, 9539.
-
[22]
(22) Xu, L. F.; Chen, Q.W.; Xu, D. S. J. Phys. Chem. C 2007, 111,11560. doi: 10.1021/jp071536a
-
[23]
(23) Li, X.; Jiang, Y.; Shi, Z.W.; Xu, Z. Chem. Mater. 2007, 19,5424. doi: 10.1021/cm071180f
-
[24]
(24) Cha, Q. X. Introduction to Electrode Kinetics, 3rd ed.; ScientificPublishers: Beijing, 2007; pp 301-315. [查全性. 电极过程动力学导论, 第三版. 北京: 科学出版社, 2007: 301-315.]
-
[25]
(25) Tian, Z.W. Electrochemical Research Methods, 1st ed.;Scientific Publishers: Beijing, 1984. [田昭武. 电化学研究方法, 第一版. 北京: 科学出版社, 1984.]
-
[26]
(26) Han, D. G.; Gao, Z. D.; Gao, P. L. Physical Chemistry, 1st ed.;Higher Education Press: Beijing, 2001; pp 645-656. [韩德刚,高执棣, 高盘良. 物理化学, 第一版. 北京: 高等教育出版社,2001: 645-656.]
-
[27]
(27) Wang, Z. L.; Kong, X. Y.; Ding, Y. Adv. Funct. Mater. 2004, 14,943. doi: 10.1002/(ISSN)1616-3028
-
[28]
(28) Mann, S. Nature 1993, 265, 499.
-
[29]
(29) Lao, J. Y.;Wen, J. G.; Ren, Z. F. Nano Lett. 2002, 2, 1287. doi: 10.1021/nl025753t
-
[30]
(30) Liu, J.; Zhang, Y.; Qi, J. J. Mater. Lett. 2006, 60, 2623. doi: 10.1016/j.matlet.2006.01.051
-
[31]
(31) Huang, L.;Wright, S.; Yang, S. J. Phys. Chem. B 2004, 108,19901. doi: 10.1021/jp045556d
-
[32]
(32) Izaki, M.; Omi, T. Appl. Phys. Lett. 1996, 68, 2439. doi: 10.1063/1.116160
-
[33]
(33) Peulon, S.; Lincot, D. J. Electrochem. Soc. 1998, 145, 864. doi: 10.1149/1.1838359
-
[34]
(34) Pauprte, T.; Lincot, D. Electrochim. Acta 2000, 45, 3345. doi: 10.1016/S0013-4686(00)00405-9
-
[35]
(35) Liu, R.; Vertegel, A. A.; Bohannan, E.W.; Sorenson, T. A.;Switzer, J. A. Chem. Mater. 2001, 13, 508. doi: 10.1021/cm000763l
-
[36]
(36) Xu, L. F.; Guo, Y.; Liao, Q.; Zhang, J. P.; Xu, D. S. J. Phys. Chem. B 2005, 109, 13519. doi: 10.1021/jp051007b
-
[37]
(37) Ray, S. C. Sol. Energy Mat. Sol. Cells 2001, 68, 307. doi: 10.1016/S0927-0248(00)00364-0
-
[38]
(38) Ghijsen, J.; Tjeng, L. H.; van Elp, J.; Eskes, H.;Westerink, J.;Sawatzky, G. A.; Czyzyk, M. T. Phys. Rev. B 1998, 38, 11322.
-
[39]
(39) Hara, M.; Kondo, T.; Komoda, M.; Ikeda, S.; Shinohara, K.;Tanaka, A.; Kondo, J. N.; Domen, K. Chem. Commun. 1998,357.
-
[40]
(40) Ikeda, S.; Takata, T.; Kondo, T.; Hitoki, G.; Hara, M.; Kondo, J.N.; Domen, K.; Hosono, H.; Kawazoeb, H.; Tanakac, A. Chem. Commun. 1998, 2185.
-
[41]
(41) Li, X.; Gao, H.; Murphy, C. J.; u, L. Nano Lett. 2004, 4,1903. doi: 10.1021/nl048941n
-
[42]
(42) Liu, R.; Kulp, E. A.; Oba, F.; Bohannan, E.W.; Ernst, F.;Switzer, J. A. Chem. Mater. 2005, 17, 725. doi: 10.1021/cm048296l
-
[43]
(43) Chang, Y.; Teo, J. J.; Zeng, H. C. Langmuir 2005, 21, 1074. doi: 10.1021/la047671l
-
[44]
(44) Sunagawa, I. Crystals: Growth, Morphology & Perfection;Cambridge University Press: Cambridge, UK, 2005.
-
[45]
(45) Wang, Z. L. J. Phys. Chem. B 2000, 104, 1153. doi: 10.1021/jp993593c
-
[46]
(46) Shi, E.W.; Chen, Z. Z.; Yuan, R. L.; Zheng, Y. Q. Hydrothermal Crystallography, 1st ed.; Scientific Publishers: Beijing, 2004.[施尔畏, 陈之战, 元如林, 郑燕青. 水热结晶学, 第一版. 北京:科学出版社, 2004.]
-
[47]
(47) Zhong,W. Z.; Hua, S. K. Crystal Growth Morphology;Scientific Publishers: Beijing, 1999. [仲维卓, 华素坤. 晶体生长形态学. 北京: 科学出版社, 1999.]
-
[48]
(48) Zhou, Y. C.; Switzer, J. A. Mater. Res. Innovations 1998, 2, 22.doi: 10.1007/s100190050056
-
[49]
(49) Switzer, J. A.; Kothari, H. M.; Bohannan, E.W. J. Phys. Chem. B 2002, 106, 4027.
-
[50]
(50) Liu, R.; Bohannan, E.W.; Switzer, J. A.; Oba, F.; Ernst, F. Appl. Phys. Lett. 1994, 83, 1944.
-
[51]
(51) Liu, R.; Oba, F.; Bohannan, E.W.; Ernst, F.; Switzer, J. A.Chem. Mater. 2003, 15, 4882. doi: 10.1021/cm034807c
-
[52]
(52) Siegfried, M. J.; Choi, K. S. Adv. Mater. 2004, 16, 1743. doi: 10.1002/(ISSN)1521-4095
-
[53]
(53) Brown, K. E. R.; Choi, K. S. Chem. Commun. 2006, 3311.
-
[54]
(54) Xu, L. F. Electrochemical Synthesis, Morphological Control andPerformance of Semiconductor Materials. Ph. D. Dissertation,Peking University, Beijing, 2007. [许荔芬. 半导体材料的电化学制备、形貌调控和性能研究[D]. 北京: 北京大学, 2007.]
-
[55]
(55) Jiao, S. H.; Jiang, K.; Zhang, Y. H.; Xiao, M.; Xu, L. F.; Xu, D.S. J. Phys. Chem. C 2008, 112, 3358. doi: 10.1021/jp710145a
-
[56]
(56) Cornell, R. M.; Schwertmann, U. The Iron Oxides, 2nd ed.;Wiley-VCH:Weinheim, Germany, 2004.
-
[57]
(57) Sone, E. D.;Weiner, S.; Addadi, L. Cryst. Growth Des. 2005, 5,2131. doi: 10.1021/cg050171l
-
[58]
(58) Lowenstam, H. A. Science 1971, 171, 487. doi: 10.1126/science.171.3970.487
-
[59]
(59) Mazeina, L.; Alexandra, N. Chem. Mater. 2007, 19, 825. doi: 10.1021/cm0623817
-
[60]
(60) Leibenguth, J. L.; Cohen, M. J. Electrochem. Soc. 1972, 119,987. doi: 10.1149/1.2404424
-
[61]
(61) Jiao, S. H.; Xu, L. F.; Hu, K. L.; Li, J. J.; Gao, S.; Xu, D. S.J. Phys. Chem. C 2010, 114, 269. doi: 10.1021/jp909072m
-
[62]
(62) Cheng, J. P.; Guo, R. Y.;Wang, Q. M. Appl. Phys. Lett. 2004,85, 5140. doi: 10.1063/1.1825067
-
[63]
(63) Jeong, J. S.; Lee, J. Y.; Cho, J. H. Chem. Mater. 2005, 17, 2752.doi: 10.1021/cm049387l
-
[64]
(64) Wu, G. S.; Xie, T.; Yuan, X. Y.; Li, Y.; Yang, L.; Xiao, Y. H.;Zhang, L. D. Solid State Commun. 2005, 134, 485. doi: 10.1016/j.ssc.2005.02.015
-
[65]
(65) Xu, L. F.; Liao, Q.; Zhang, J. P.; Ai, X. C.; Xu, D. S. J. Phys. Chem. C 2007, 111, 4549. doi: 10.1021/jp068485m
-
[66]
(66) Lao, J. Y.; Huang, J. Y.;Wang, D. Z.; Ren, Z. F. J. Mater. Chem.2004, 14, 770. doi: 10.1039/b311639e
-
[67]
(67) Park, J. H.; Park, J. G. Appl. Phys. A 2005, 80, 43. doi: 10.1007/s00339-004-2936-z
-
[68]
(68) Law, M.; Greene, L. E.; Johnson, J. C.; Saykally, R.; Yang, P. D.Nat. Mater. 2005, 4, 455. doi: 10.1038/nmat1387
-
[69]
(69) Zhang, T. R.; Dong,W. J.; Brewer, M. K.; Konar, D. J.; Njabon,R. N.; Tian, Z. R. J. Am. Chem. Soc. 2006, 128, 10960. doi: 10.1021/ja0631596
-
[70]
(70) Li, C.; Fang, G. J.; Su, F. H.; Li, G. H.;Wu, X. G.; Zhao, X. Z.Cryst. Growth Des. 2006, 6, 2588. doi: 10.1021/cg050357k
-
[71]
(71) Liu, J. P.; Huang, X. T.; Li, Y. Y.; Sulieman, K. M.; He, X.; Sun,F. L. J. Phys. Chem. B 2006, 110, 21865. doi: 10.1021/jp064487v
-
[72]
(72) Shen, G. Z.; Chen, D.; Lee, C. J. J. Phys. Chem. B 2006, 110,15689. doi: 10.1021/jp0630119
-
[73]
(73) Zhang, D. F.; Sun, L. D.; Jia, C. J.; Yan, Z. G.; You, L. P.; Yan,C. H. J. Am. Chem. Soc. 2005, 127, 13492. doi: 10.1021/ja054771k
-
[74]
(74) Gao, P. X.;Wang, Z. L. Appl. Phys. Lett. 2004, 84, 2883. doi: 10.1063/1.1702137
-
[75]
(75) Qin, Y.;Wang, X. D.;Wang, Z. L. Nature 2008, 451, 809. doi: 10.1038/nature06601
-
[1]
-
-
-
[1]
Pei Li , Yuenan Zheng , Zhankai Liu , An-Hui Lu . Boron-Containing MFI Zeolite: Microstructure Control and Its Performance of Propane Oxidative Dehydrogenation. Acta Physico-Chimica Sinica, 2025, 41(4): 100034-. doi: 10.3866/PKU.WHXB202406012
-
[2]
Jiahui YU , Jixian DONG , Yutong ZHAO , Fuping ZHAO , Bo GE , Xipeng PU , Dafeng ZHANG . The morphology control and full-spectrum photodegradation tetracycline performance of microwave-hydrothermal synthesized BiVO4:Yb3+,Er3+ photocatalyst. Journal of Fuel Chemistry and Technology, 2025, 53(3): 348-359. doi: 10.1016/S1872-5813(24)60514-1
-
[3]
Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl0.08Mn1.92O4 single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
-
[4]
Bing Shen , Tongwei Yuan , Wenshuang Zhang , Yang Chen , Jiaqiang Xu . Complex shell Fe-ZnO derived from ZIF-8 as high-quality acetone MEMS sensor. Chinese Chemical Letters, 2024, 35(11): 109490-. doi: 10.1016/j.cclet.2024.109490
-
[5]
Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo2O4/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
-
[6]
Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
-
[7]
Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS2 Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
-
[8]
Bing WEI , Jianfan ZHANG , Zhe CHEN . Research progress in fine tuning of bimetallic nanocatalysts for electrocatalytic carbon dioxide reduction. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 425-439. doi: 10.11862/CJIC.20240201
-
[9]
Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
-
[10]
Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
-
[11]
Lubing Qin , Fang Sun , Meiyin Li , Hao Fan , Likai Wang , Qing Tang , Chundong Wang , Zhenghua Tang . 原子精确的(AgPd)27团簇用于硝酸盐电还原制氨:一种配体诱导策略来调控金属核. Acta Physico-Chimica Sinica, 2025, 41(1): 2403008-. doi: 10.3866/PKU.WHXB202403008
-
[12]
Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co3O4 as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
-
[13]
Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
-
[14]
Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
-
[15]
Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
-
[16]
Yi DING , Peiyu LIAO , Jianhua JIA , Mingliang TONG . Structure and photoluminescence modulation of silver(Ⅰ)-tetra(pyridin-4-yl)ethene metal-organic frameworks by substituted benzoates. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 141-148. doi: 10.11862/CJIC.20240393
-
[17]
Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
-
[18]
Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
-
[19]
Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017
-
[20]
Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
-
[1]
Metrics
- PDF Downloads(1416)
- Abstract views(3317)
- HTML views(22)