Citation: WANG Yu, CHEN Jing, LIAO Qing, SUN Wei, LI Jianlong, ZHANG Jianping, WU Kai. Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2500-2506. doi: 10.3866/PKU.WHXB201209113 shu

Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach

WANG Yu ¹ ,
CHEN Jing ¹ ,
LIAO Qing ² ,
SUN Wei ¹ ,
LI Jianlong ^1, ,
ZHANG Jianping ³ ,
WU Kai ^1,

1.
1 Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2 Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R.China;
3 Department of Chemistry, ReminUnversity of China, Beijing 100872, P. R.China

Received Date: 28 August 2012
Available Online: 11 September 2012
Fund Project: 国家自然科学基金(20827002, 20911130229) (20827002, 20911130229)国家重点基础研究发展规划项目(973) (2009CB929403, 2011CB808702)资助 (973) (2009CB929403, 2011CB808702)

This paper reports the preparation in large quantity of bifilar helix-like nanobelts of single crystalline Zn₂SnO₄, a face-centered cubic spinel and transparent semiconductor that possesses wide applications in photovoltaic devices and sensors for humidity and combustible gases, by using a unique approach that combines chemical vapor deposition, aluminothermal reaction, vapor-liquid-solid growth, mergence of polar planes, and kinetic control by steady-state turbulent flow. The bifilar helix-like nanobelt was formed by the twisting and merging of two independent Zn₂SnO₄ nanobelts, as analyzed by scanning electron microscopy, transmission electron microscopy, electron diffraction, X-ray diffraction, Raman spectroscopy, and photoluminescence. It had a periodicity along the axial direction and hence, is actually a super-lattice material. The photoluminescence measurements showed a strong light emission at 326.1 nm from the as-prepared sample with a line width of about 1.5 nm. The combined approach used in this study, in particular its aluminothermal reaction and steady-state turbulent gas flow perturbation steps, may be helpful in preparing other similar materials.
- Bifilar helix-like nanobelt,
- Zn₂SnO₄,
- Aluminothermal reaction approach,
- Photoluminescence
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Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach