Citation: WANG Yu, CHEN Jing, LIAO Qing, SUN Wei, LI Jianlong, ZHANG Jianping, WU Kai. Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2500-2506. doi: 10.3866/PKU.WHXB201209113 shu

Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach

WANG Yu ¹ ,
CHEN Jing ¹ ,
LIAO Qing ² ,
SUN Wei ¹ ,
LI Jianlong ^1, ,
ZHANG Jianping ³ ,
WU Kai ^1,

1.
1 Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2 Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R.China;
3 Department of Chemistry, ReminUnversity of China, Beijing 100872, P. R.China

Received Date: 28 August 2012
Available Online: 11 September 2012
Fund Project: 国家自然科学基金(20827002, 20911130229) (20827002, 20911130229)国家重点基础研究发展规划项目(973) (2009CB929403, 2011CB808702)资助 (973) (2009CB929403, 2011CB808702)

This paper reports the preparation in large quantity of bifilar helix-like nanobelts of single crystalline Zn₂SnO₄, a face-centered cubic spinel and transparent semiconductor that possesses wide applications in photovoltaic devices and sensors for humidity and combustible gases, by using a unique approach that combines chemical vapor deposition, aluminothermal reaction, vapor-liquid-solid growth, mergence of polar planes, and kinetic control by steady-state turbulent flow. The bifilar helix-like nanobelt was formed by the twisting and merging of two independent Zn₂SnO₄ nanobelts, as analyzed by scanning electron microscopy, transmission electron microscopy, electron diffraction, X-ray diffraction, Raman spectroscopy, and photoluminescence. It had a periodicity along the axial direction and hence, is actually a super-lattice material. The photoluminescence measurements showed a strong light emission at 326.1 nm from the as-prepared sample with a line width of about 1.5 nm. The combined approach used in this study, in particular its aluminothermal reaction and steady-state turbulent gas flow perturbation steps, may be helpful in preparing other similar materials.
- Bifilar helix-like nanobelt,
- Zn₂SnO₄,
- Aluminothermal reaction approach,
- Photoluminescence
1. [1]
  
  (1) Wang, Z. L. Dekker Encyclopedia of Nanoscience and Nanotechnology 2004, 1773.
2. [2]
  (2) Chen, J. Y.; Benjamin,W.; Joseph, M.; Xiong, Y. J.; Li, Z. Y.;Xia, Y. N. Nano Lett. 2005, 5, 2058. doi: 10.1021/nl051652u
3. [3]
  (3) Kuang, Q.; Jiang, Z. Y.; Xie, Z. X.; Lin, S. C.; Lin, Z.W.; Xie,S. Y.; Huang, R. B.; Zheng, L. S. J. Am. Chem. Soc. 2005, 127,11777. doi: 10.1021/ja052259t
4. [4]
  (4) Benjamin, D. Y.; David, O. Z.; Peter, J. P.; He, R. R.; Yang, P. D.Angew. Chem. Int. Edit. 2006, 45, 420. doi: 10.1002/(ISSN)1521-3773
5. [5]
  (5) Zhang, H. F.;Wang, C. M.;Wang, L. S. Nano Lett. 2002, 2, 941.doi: 10.1021/nl025667t
6. [6]
  (6) Zhang, D. Q.; Abdullah, A.; Han, H. G.; Hasan, M.; McIlroy, D.N. Nano Lett. 2003, 3, 983. doi: 10.1021/nl034288c
7. [7]
  (7) Vardhan, B.; Dai, L. M.; Toshiyuki, O. J. Am. Chem. Soc. 2004,126, 5070. doi: 10.1021/ja031738u
8. [8]
  (8) Zhang, G. Y.; Jiang, X.;Wang, E. G. Appl. Phys. Lett. 2004, 84,2646. doi: 10.1063/1.1695198
9. [9]
  (9) Gao, R. P.;Wang, Z. L.; Fan, S. S. J. Phys. Chem. B 2000, 104,1227. doi: 10.1021/jp9937611
10. [10]
  (10) Tang, Y. H.; Zhang, Y. F.;Wang, N.; Lee, C. S.; Han, X. D.;Bello, I.; Lee, S. T. J. Appl. Phys. 1999, 85, 7981. doi: 10.1063/1.369389
11. [11]
  (11) Duan, J. H.; Yang, S. G.; Liu, H.W.; ng, J. F.; Huang, H. B.;Zhao, X. N.; Zhang, R.; Du, Y.W. J. Am. Chem. Soc. 2005, 127,6180. doi: 10.1021/ja042748d
12. [12]
  (12) Yang, R. S.; Ding, Y.;Wang, Z. L. Nano Lett. 2004, 4, 1309.doi: 10.1021/nl049317d
13. [13]
  (13) Bae, S. Y.; Lee, J. Y.; Jung, H. S.; Park, J. H.; Ahn, J. P. J. Am. Chem. Soc. 2005, 127, 10802. doi: 10.1021/ja0534102
14. [14]
  (14) Zhan, J. H.; Bando, Y.; Hu, J. Q.; Xu, F. F.; lberg, D. Small2005, 1, 883. doi: 10.1002/(ISSN)1613-6829
15. [15]
  (15) Zarur, A. J.; Ying, J. Y. Nature 2000, 403, 65. doi: 10.1038/47450
16. [16]
  (16) Shen, S. C.; Kus, H.; Liya, E. Y.; Sibudjing, K. Adv. Mater.2004, 16, 541. doi: 10.1002/(ISSN)1521-4095
17. [17]
  (17) Chen, Y. C.; Chang, Y. H.; Tsai, B. S. Mater. Trans. 2004, 45,1684. doi: 10.2320/matertrans.45.1684
18. [18]
  (18) vander Laaga, N. J.; Snela, M. D.; Magusinb, P. C. M. M.; deWith, G. J. Eur. Cer. Soc. 2004, 24, 2417. doi: 10.1016/j.jeurceramsoc.2003.06.001
19. [19]
  (19) Lou, Z. D.; Hao, J. H. Thin Solid Films 2004, 450, 334. doi: 10.1016/j.tsf.2003.11.294
20. [20]
  (20) Zawadzki, M.;Wrzyszcz, J.; Strek,W.; Hreniak, D. J. Alloy. Compd. 2001, 323-324, 279.
21. [21]
  (21) Yu, J. F.;Wang, F.;Wang, Y.; Gao, H.; Li, J. L.;Wu, K. Chem. Soc. Rev. 2010, 39, 1513. doi: 10.1039/b812787p
22. [22]
  (22) Wang, Y.;Wu, K. J. Am. Chem. Soc. 2005, 127, 9686. doi: 10.1021/ja0505402
23. [23]
  (23) Wang, Y.; Liao, Q.; Lei, H.; Zhang, X. P.; Ai, X. C.; Zhang, J. P.;Wu, K. Adv. Mater. 2006, 18, 943. doi: 10.1002/(ISSN)1521-4095
24. [24]
  (24) Liao, Q.;Wang, Y.; Li, J. L.;Wu, K.; Ai, X. C.; Zhang, J. P.Appl. Phys. Lett. 2007, 91, 041103. doi: 10.1063/1.2759473
25. [25]
  (25) Palmer, G. B.; Poeppelmeier, K. R. Solid State Sci. 2002, 4, 317.doi: 10.1016/S1293-2558(01)01258-4
26. [26]
  (26) Coutts, T. J.; Young, D. L.; Li, X.; Mulligan,W. P.;Wu, X.J. Vac. Sci. Technol. A 2000, 18, 2646.
27. [27]
  (27) Stambolova, I.; Konstantinov, K.; Kovacheva, D.; Peshev, P.;Donchev, T. J. Solid State Chem. 1997, 128, 305. doi: 10.1006/jssc.1996.7174
28. [28]
  (28) Yamada, Y.; Seno, Y.; Masuoka, Y.; Yamashita, K. Sens. Actua. B-Chem. 1998, 49, 248. doi: 10.1016/S0925-4005(98)00135-X
29. [29]
  (29) Stambolova, I.; Konstantinov, K.; Khristova, M.; Peshev, P.Phys. Status Solid.-Appl. Res. 1998, 167, R11.
30. [30]
  (30) Jie, J. S.;Wang, G. Z.; Han, X. H.; Fang, J. P.; Yu, Q. X.; Liao,Y.; Xu, B.;Wang, Q. T.; Hou, J. G. J. Phys. Chem. B 2004, 108,8249. doi: 10.1021/jp049230g
31. [31]
  (31) Chen, H. Y.;Wang, J. X.; Yu, H. C.; Yang, H. X.; Xie, S. S.; Li,J. Q. J. Phys. Chem. B 2005, 109, 2573. doi: 10.1021/jp046125y
32. [32]
  (32) Wang, J. X.; Xie, S. S.; Gao, Y.; Yan, X. Q.; Liu, D. F.; Yuan, H.J.; Zhou, Z. P.; Song, L.; Liu, L. F.; Zhou,W. Y.;Wang, E. G.J. Cryst. Growth 2004, 267, 177.
33. [33]
  (33) Kim, H. S.; Hwang, S. O.; Myung, Y.; Park, J.; Bae, S. Y.; Ahn,J. P. Nano Lett. 2008, 8, 551. doi: 10.1021/nl072829i
34. [34]
  (34) Yu, J. F.;Wang, Y.;Wen,W.; Yang, D. H.; Huang, B.; Li, J. L.;Wu, K. Adv. Mater. 2010, 22, 1479. doi: 10.1002/adma.200903656
35. [35]
  (35) Kong, X. Y.; Ding, Y.; Yang, R. S.;Wang, Z. L. Science 2004,303, 1348. doi: 10.1126/science.1092356
36. [36]
  (36) Gates, B.; Mayers, B.; Cattle, B.; Xia, Y. N. Adv. Funct. Mater.2002, 12, 219. doi: 10.1002/1616-3028(200203)12:3<219::AID-ADFM219>3.0.CO;2-U
37. [37]
  (37) Joo, J.; Son, J. S.; Kwon, S. G.; Yu, J. H.; Hyeon, T. J. Am. Chem. Soc. 2006, 128, 5632. doi: 10.1021/ja0601686
38. [38]
  (38) odwin, T. J.; Leppert, V. J.; Risbud, S. H.; Kennedy, I. M.;Lee, H.W. H. Appl. Phys. Lett. 1997, 70, 3122. doi: 10.1063/1.119109
39. [39]
  (39) Ramyall, P.; Tanaka, S.; Nomura, S.; Riblet, P.; Aoyagi, Y. Appl. Phys. Lett. 1998, 73, 1104. doi: 10.1063/1.122098
40. [40]
  (40) Hu, P. A.; Liu, Y. Q.; Fu, L.; Cao, L. C.; Zhu, D. B. J. Phys. Chem. B 2004, 108, 936.
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Bifilar Helix-Like Nanobelt of Single Crystalline Zn₂SnO₄ Fabricated by Aluminothermal Reaction Approach