Citation: LI Zhen-Hu, MA Yu-Rong, QI Li-Min. Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2493-2499. doi: 10.3866/PKU.WHXB201209071 shu

Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles

1.
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P.R. China

Received Date: 31 July 2012
Available Online: 7 September 2012
Fund Project: 国家自然科学基金(50902002, 51121091) (50902002, 51121091) 高等学校博士学科点专项科研基金(20090001120015)资助项目 (20090001120015)

Uniform sphere-like Co-doped iron oxide nanoparticles were synthesized by the thermolysis of iron oleate and cobalt oleate precursors in octadecene in the presence of oleic acid. The Co/Fe mole ratios in the final Co-doped iron oxide can be controlled by changing their ratios in the reaction precursors. With the increase of Co/Fe mole ratios from 0.024 to 0.156 in the final iron oxide nanoparticles, the magnetic saturation values of the nanoparticles slightly decreased from 39 to 30 emu·g^-1, while their coercivity values increased from 0 to 190 Oe. The sizes of the Co-doped iron oxide nanoparticles increased from 7 to 14 nm when the thermolysis time was increased from 0.5 to 3 h with a thermolysis temperature 305℃. Generally, with increasing thermolysis time the metal elements in the final nanoparticles were partially reduced. The domain polymorph of the final nanoparticles was magnetite with a very small amount of ferrous oxide for thermolysis time less than 1 h, while the phases were a mixture of magnetite and wüstite ferrous oxide for thermolysis time longer than 2 h. Further increasing thermolysis time to 3 h, except Fe₃O₄ and FeO, CoFe alloys appear too. It indicates that the iron (cobalt) elements were reduced from trivalence to bivalence, and finally to zero valence. The sizes of the iron oxide nanoparticles increased and more ferrous oxide appeared in the final products with increasing the thermolysis temperature.
- Cobalt-doping,
- Magnetism,
- Iron oxide, Controlled synthesis,
- Thermolysis
  ,
1. [1]
  
  (1) Xie, J.; Huang, J.; Li, X.; Sun, S.; Chen, X. Curr. Med. Chem.2009, 16, 1278. doi: 10.2174/092986709787846604
2. [2]
  (2) Ho, D.; Sun, X.; Sun, S. Accounts Chem. Res. 2011, 44, 875.doi: 10.1021/ar200090c
3. [3]
  (3) Gupta, A. K.; Gupta, M. Biomaterials 2005, 26, 3995. doi: 10.1016/j.biomaterials.2004.10.012
4. [4]
  (4) Qiao, R. R.; Zeng, J. F.; Jia, Q. J.; Du, J.; Shen, L.; Gao, M. Y.Acta Phys. -Chim. Sin. 2012, 28, 993. [乔瑞瑞, 曾剑峰, 贾巧娟, 杜军, 沈琳, 高明远. 物理化学学报, 2012, 28, 993.]doi: 10.3866/PKU.WHXB201203023
5. [5]
  (5) Yang, C.;Wu, J.; Hou, Y. Chem. Commun. 2011, 47, 5130. doi: 10.1039/c0cc05862a
6. [6]
  (6) Sun, S.; Zeng, H. J. Am. Chem. Soc. 2002, 124, 8204. doi: 10.1021/ja026501x
7. [7]
  (7) Park, J.; An, K.; Hwang, Y.; Park, J. G.; Noh, H. J.; Kim, J. Y.;Park, J. H.; Hwang, N. M.; Hyeon, T. Nat. Mater. 2004, 3, 891.doi: 10.1038/nmat1251
8. [8]
  (8) Kovalenko, M. V.; Bodnarchuk, M. I.; Lechner, R. T.; Hesser,G.; Schäffler, F.; Heiss,W. J. Am. Chem. Soc. 2007, 129, 6352.doi: 10.1021/ja0692478
9. [9]
  (9) De Silva, C. R.; Smith, S.; Shim, I.; Pyun, J.; Gutu, T.; Jiao, J.;Zheng, Z. J. Am. Chem. Soc. 2009, 131, 6336. doi: 10.1021/ja9014277
10. [10]
  (10) Lee, J. H.; Huh, Y. M.; Jun, Y.W.; Seo, J.W.; Jang, J. T.; Song,H. T.; Kim, S.; Cho, E. J.; Yoon, H. G.; Suh, J. S.; Cheon, J.Nat. Med. 2007, 13, 95. doi: 10.1038/nm1467
11. [11]
  (11) Staniland, S.;Williams,W.; Telling, N.; van der Laan, G.;Harrison, A.;Ward, B. Nat. Nano 2008, 3, 158. doi: 10.1038/nnano.2008.35
12. [12]
  (12) Coker, V. S.; Telling, N. D.; van der Laan, G.; Pattrick, R. A. D.;Pearce, C. I.; Arenholz, E.; Tuna, F.;Winpenny, R. E. P.; Lloyd,J. R. ACS Nano 2009, 3, 1922. doi: 10.1021/nn900293d
13. [13]
  (13) Song, Q.; Zhang, Z. J. J. Am. Chem. Soc. 2004, 126, 6164. doi: 10.1021/ja049931r
14. [14]
  (14) Sun, S.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.;Wang, S. X.; Li, G. J. Am. Chem. Soc. 2003, 126, 273.
15. [15]
  (15) Bao, N.; Shen, L.;Wang, Y.; Padhan, P.; Gupta, A. J. Am. Chem. Soc. 2007, 129, 12374. doi: 10.1021/ja074458d
16. [16]
  (16) Ayyappan, S.; Mahadevan, S.; Chandramohan, P.; Srinivasan,M. P.; Philip, J.; Raj, B. J. Phy. Chem. C 2010, 114, 6334. doi: 10.1021/jp911966p
17. [17]
  (17) Junior, A. F.; Zapf, V.; Egan, P. J. Appl. Phys. 2007, 101,09M506.
18. [18]
  (18) Tackett, R.; Sudakar, C.; Naik, R.; Lawes, G.; Rablau, C.;Vaishnava, P. P. J. Magn. Magn. Mater. 2008, 320, 2755. doi: 10.1016/j.jmmm.2008.06.006
19. [19]
  (19) Naka mi, F.; da Silva, S.W.; Garg, V. K.; Oliveira, A. C.;Morais, P. C.; Junior, A. F.; Lima, E. C. D. J. Appl. Phys. 2007,101, 09M514.
20. [20]
  (20) Caruntu, G.; Newell, A.; Caruntu, D.; O'Connor, C. J. J. Appl. Phys. 2007, 434-435, 637.
21. [21]
  (21) Stefanescu, M.; Stoia, M.; Caizer, C.; Dippong, T.; Barvinschi,P. J. Therm. Anal. Calorim. 2009, 97, 245. doi: 10.1007/s10973-009-0250-x
22. [22]
  (22) Hu, L.; de Montferrand, C.; Lalatonne, Y.; Motte, L.; Brioude,A. J. Phys. Chem. C 2012, 116, 4349.
23. [23]
  (23) Chakrabarti, S.; Mandal, S. K.; Chaudhuri, S. Nanotechnology2005, 16, 506. doi: 10.1088/0957-4484/16/4/029
24. [24]
  (24) Chalasani, R.; Vasudevan, S. J. Phys. Chem. C 2011, 115,18088. doi: 10.1021/jp204697f
25. [25]
  (25) Tzitzios, V. J. Appl. Phys. 2011, 109, 07A313.
26. [26]
  (26) Nam, K. M.; Shim, J. H.; Ki, H.; Choi, S. I.; Lee, G.; Jang, J. K.;Jo, Y.; Jung, M. H.; Song, H.; Park, J. T. Angew. Chem. Int. Edit.2008, 47, 9504. doi: 10.1002/anie.v47:49
27. [27]
  (27) Seo,W. S.; Lee, J. H.; Sun, X.; Suzuki, Y.; Mann, D.; Liu, Z.;Terashima, M.; Yang, P. C.; McConnell, M. V.; Nishimura, D.G.; Dai, H. Nat. Mater. 2006, 5, 971. doi: 10.1038/nmat1775
28. [28]
  (28) Chen, C. J.; Chiang, R. K.; Lai, H. Y.; Lin, C. R. J. Phys. Chem. C 2010, 114, 4258. doi: 10.1021/jp908153y
29. [29]
  (29) Huang, C. C.; Chang, C. N.; Yeh, C. S. Nanoscale 2011, 3,4254. doi: 10.1039/c1nr10701a
1. [1]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
5. [5]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
6. [6]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
7. [7]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
10. [10]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
11. [11]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
12. [12]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
13. [13]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
14. [14]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
15. [15]
  Yuanpei ZHANG , Jiahong WANG , Jinming HUANG , Zhi HU . Preparation of magnetic mesoporous carbon loaded nano zero-valent iron for removal of Cr(Ⅲ) organic complexes from high-salt wastewater. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1731-1742. doi: 10.11862/CJIC.20240077
16. [16]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
17. [17]
  Qianqian Zhong , Yucui Hao , Guotao Yu , Lijuan Zhao , Jingfu Wang , Jian Liu , Xiaohua Ren . Comprehensive Experimental Design for the Preparation of the Magnetic Adsorbent Based on Enteromorpha Prolifera and Its Utilization in the Purification of Heavy Metal Ions Wastewater. University Chemistry, 2024, 39(8): 184-190. doi: 10.3866/PKU.DXHX202312013
18. [18]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051
19. [19]
  Yongpo Zhang , Xinfeng Li , Yafei Song , Mengyao Sun , Congcong Yin , Chunyan Gao , Jinzhong Zhao . Synthesis of Chlorine-Bridged Binuclear Cu(I) Complexes Based on Conjugation-Driven Cu(II) Oxidized Secondary Amines. University Chemistry, 2024, 39(5): 44-51. doi: 10.3866/PKU.DXHX202309092
20. [20]
  Yang Lv , Yingping Jia , Yanhua Li , Hexiang Zhong , Xinping Wang . Integrating the Ideological Elements with the “Chemical Reaction Heat” Teaching. University Chemistry, 2024, 39(11): 44-51. doi: 10.12461/PKU.DXHX202402059

Get Citation

PDF

XML

Metrics

PDF Downloads(918)
Abstract views(2065)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142