Citation: LI Zhen-Hu, MA Yu-Rong, QI Li-Min. Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2493-2499. doi: 10.3866/PKU.WHXB201209071 shu

Controlled Synthesis of Cobalt-Doped Magnetic Iron Oxide Nanoparticles

1.
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P.R. China

Received Date: 31 July 2012
Available Online: 7 September 2012
Fund Project: 国家自然科学基金(50902002, 51121091) (50902002, 51121091) 高等学校博士学科点专项科研基金(20090001120015)资助项目 (20090001120015)

Uniform sphere-like Co-doped iron oxide nanoparticles were synthesized by the thermolysis of iron oleate and cobalt oleate precursors in octadecene in the presence of oleic acid. The Co/Fe mole ratios in the final Co-doped iron oxide can be controlled by changing their ratios in the reaction precursors. With the increase of Co/Fe mole ratios from 0.024 to 0.156 in the final iron oxide nanoparticles, the magnetic saturation values of the nanoparticles slightly decreased from 39 to 30 emu·g^-1, while their coercivity values increased from 0 to 190 Oe. The sizes of the Co-doped iron oxide nanoparticles increased from 7 to 14 nm when the thermolysis time was increased from 0.5 to 3 h with a thermolysis temperature 305℃. Generally, with increasing thermolysis time the metal elements in the final nanoparticles were partially reduced. The domain polymorph of the final nanoparticles was magnetite with a very small amount of ferrous oxide for thermolysis time less than 1 h, while the phases were a mixture of magnetite and wüstite ferrous oxide for thermolysis time longer than 2 h. Further increasing thermolysis time to 3 h, except Fe₃O₄ and FeO, CoFe alloys appear too. It indicates that the iron (cobalt) elements were reduced from trivalence to bivalence, and finally to zero valence. The sizes of the iron oxide nanoparticles increased and more ferrous oxide appeared in the final products with increasing the thermolysis temperature.
- Cobalt-doping,
- Magnetism,
- Iron oxide, Controlled synthesis,
- Thermolysis
  ,
1. [1]
  
  (1) Xie, J.; Huang, J.; Li, X.; Sun, S.; Chen, X. Curr. Med. Chem.2009, 16, 1278. doi: 10.2174/092986709787846604
2. [2]
  (2) Ho, D.; Sun, X.; Sun, S. Accounts Chem. Res. 2011, 44, 875.doi: 10.1021/ar200090c
3. [3]
  (3) Gupta, A. K.; Gupta, M. Biomaterials 2005, 26, 3995. doi: 10.1016/j.biomaterials.2004.10.012
4. [4]
  (4) Qiao, R. R.; Zeng, J. F.; Jia, Q. J.; Du, J.; Shen, L.; Gao, M. Y.Acta Phys. -Chim. Sin. 2012, 28, 993. [乔瑞瑞, 曾剑峰, 贾巧娟, 杜军, 沈琳, 高明远. 物理化学学报, 2012, 28, 993.]doi: 10.3866/PKU.WHXB201203023
5. [5]
  (5) Yang, C.;Wu, J.; Hou, Y. Chem. Commun. 2011, 47, 5130. doi: 10.1039/c0cc05862a
6. [6]
  (6) Sun, S.; Zeng, H. J. Am. Chem. Soc. 2002, 124, 8204. doi: 10.1021/ja026501x
7. [7]
  (7) Park, J.; An, K.; Hwang, Y.; Park, J. G.; Noh, H. J.; Kim, J. Y.;Park, J. H.; Hwang, N. M.; Hyeon, T. Nat. Mater. 2004, 3, 891.doi: 10.1038/nmat1251
8. [8]
  (8) Kovalenko, M. V.; Bodnarchuk, M. I.; Lechner, R. T.; Hesser,G.; Schäffler, F.; Heiss,W. J. Am. Chem. Soc. 2007, 129, 6352.doi: 10.1021/ja0692478
9. [9]
  (9) De Silva, C. R.; Smith, S.; Shim, I.; Pyun, J.; Gutu, T.; Jiao, J.;Zheng, Z. J. Am. Chem. Soc. 2009, 131, 6336. doi: 10.1021/ja9014277
10. [10]
  (10) Lee, J. H.; Huh, Y. M.; Jun, Y.W.; Seo, J.W.; Jang, J. T.; Song,H. T.; Kim, S.; Cho, E. J.; Yoon, H. G.; Suh, J. S.; Cheon, J.Nat. Med. 2007, 13, 95. doi: 10.1038/nm1467
11. [11]
  (11) Staniland, S.;Williams,W.; Telling, N.; van der Laan, G.;Harrison, A.;Ward, B. Nat. Nano 2008, 3, 158. doi: 10.1038/nnano.2008.35
12. [12]
  (12) Coker, V. S.; Telling, N. D.; van der Laan, G.; Pattrick, R. A. D.;Pearce, C. I.; Arenholz, E.; Tuna, F.;Winpenny, R. E. P.; Lloyd,J. R. ACS Nano 2009, 3, 1922. doi: 10.1021/nn900293d
13. [13]
  (13) Song, Q.; Zhang, Z. J. J. Am. Chem. Soc. 2004, 126, 6164. doi: 10.1021/ja049931r
14. [14]
  (14) Sun, S.; Zeng, H.; Robinson, D. B.; Raoux, S.; Rice, P. M.;Wang, S. X.; Li, G. J. Am. Chem. Soc. 2003, 126, 273.
15. [15]
  (15) Bao, N.; Shen, L.;Wang, Y.; Padhan, P.; Gupta, A. J. Am. Chem. Soc. 2007, 129, 12374. doi: 10.1021/ja074458d
16. [16]
  (16) Ayyappan, S.; Mahadevan, S.; Chandramohan, P.; Srinivasan,M. P.; Philip, J.; Raj, B. J. Phy. Chem. C 2010, 114, 6334. doi: 10.1021/jp911966p
17. [17]
  (17) Junior, A. F.; Zapf, V.; Egan, P. J. Appl. Phys. 2007, 101,09M506.
18. [18]
  (18) Tackett, R.; Sudakar, C.; Naik, R.; Lawes, G.; Rablau, C.;Vaishnava, P. P. J. Magn. Magn. Mater. 2008, 320, 2755. doi: 10.1016/j.jmmm.2008.06.006
19. [19]
  (19) Naka mi, F.; da Silva, S.W.; Garg, V. K.; Oliveira, A. C.;Morais, P. C.; Junior, A. F.; Lima, E. C. D. J. Appl. Phys. 2007,101, 09M514.
20. [20]
  (20) Caruntu, G.; Newell, A.; Caruntu, D.; O'Connor, C. J. J. Appl. Phys. 2007, 434-435, 637.
21. [21]
  (21) Stefanescu, M.; Stoia, M.; Caizer, C.; Dippong, T.; Barvinschi,P. J. Therm. Anal. Calorim. 2009, 97, 245. doi: 10.1007/s10973-009-0250-x
22. [22]
  (22) Hu, L.; de Montferrand, C.; Lalatonne, Y.; Motte, L.; Brioude,A. J. Phys. Chem. C 2012, 116, 4349.
23. [23]
  (23) Chakrabarti, S.; Mandal, S. K.; Chaudhuri, S. Nanotechnology2005, 16, 506. doi: 10.1088/0957-4484/16/4/029
24. [24]
  (24) Chalasani, R.; Vasudevan, S. J. Phys. Chem. C 2011, 115,18088. doi: 10.1021/jp204697f
25. [25]
  (25) Tzitzios, V. J. Appl. Phys. 2011, 109, 07A313.
26. [26]
  (26) Nam, K. M.; Shim, J. H.; Ki, H.; Choi, S. I.; Lee, G.; Jang, J. K.;Jo, Y.; Jung, M. H.; Song, H.; Park, J. T. Angew. Chem. Int. Edit.2008, 47, 9504. doi: 10.1002/anie.v47:49
27. [27]
  (27) Seo,W. S.; Lee, J. H.; Sun, X.; Suzuki, Y.; Mann, D.; Liu, Z.;Terashima, M.; Yang, P. C.; McConnell, M. V.; Nishimura, D.G.; Dai, H. Nat. Mater. 2006, 5, 971. doi: 10.1038/nmat1775
28. [28]
  (28) Chen, C. J.; Chiang, R. K.; Lai, H. Y.; Lin, C. R. J. Phys. Chem. C 2010, 114, 4258. doi: 10.1021/jp908153y
29. [29]
  (29) Huang, C. C.; Chang, C. N.; Yeh, C. S. Nanoscale 2011, 3,4254. doi: 10.1039/c1nr10701a
1. [1]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
2. [2]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Ning LI , Siyu DU , Xueyi WANG , Hui YANG , Tao ZHOU , Zhimin GUAN , Peng FEI , Hongfang MA , Shang JIANG . Preparation and efficient catalysis for olefins epoxidation of a polyoxovanadate-based hybrid. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 799-808. doi: 10.11862/CJIC.20230372
5. [5]
  Yueyue WEI , Xuehua SUN , Hongmei CHAI , Wanqiao BAI , Yixia REN , Loujun GAO , Gangqiang ZHANG , Jun ZHANG . Two Ln-Co (Ln=Eu, Sm) metal-organic frameworks: Structures, magnetism, and fluorescent sensing sulfasalazine and glutaraldehyde. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2475-2485. doi: 10.11862/CJIC.20240193
6. [6]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
7. [7]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
8. [8]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Zhenhua Wang , Haoyang Feng , Xiaoyang Shao , Wenru Fan . Vitamins in Solid Propellants: Controlled Synthesis of Neutral Macromolecular Bonding Agents. University Chemistry, 2025, 40(4): 1-9. doi: 10.3866/PKU.DXHX202401007
11. [11]
  Xiangyu CAO , Jiaying ZHANG , Yun FENG , Linkun SHEN , Xiuling ZHANG , Juanzhi YAN . Synthesis and electrochemical properties of bimetallic-doped porous carbon cathode material. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 509-520. doi: 10.11862/CJIC.20240270
12. [12]
  Hong CAI , Jiewen WU , Jingyun LI , Lixian CHEN , Siqi XIAO , Dan LI . Synthesis of a zinc-cobalt bimetallic adenine metal-organic framework for the recognition of sulfur-containing amino acids. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 114-122. doi: 10.11862/CJIC.20240382
13. [13]
  Yan LIU , Jiaxin GUO , Song YANG , Shixian XU , Yanyan YANG , Zhongliang YU , Xiaogang HAO . Exclusionary recovery of phosphate anions with low concentration from wastewater using a CoNi-layered double hydroxide/graphene electronically controlled separation film. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1775-1783. doi: 10.11862/CJIC.20240043
14. [14]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
15. [15]
  Siyi ZHONG , Xiaowen LIN , Jiaxin LIU , Ruyi WANG , Tao LIANG , Zhengfeng DENG , Ao ZHONG , Cuiping HAN . Targeting imaging and detection of ovarian cancer cells based on fluorescent magnetic carbon dots. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1483-1490. doi: 10.11862/CJIC.20240093
16. [16]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
17. [17]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
18. [18]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
20. [20]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005

Get Citation

PDF

XML

Metrics

PDF Downloads(918)
Abstract views(2124)
HTML views(23)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142