Citation: HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei. Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2269-2275. doi: 10.3866/PKU.WHXB201209061 shu

Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor

1.
Jiangsu Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China

Received Date: 3 July 2012
Available Online: 6 September 2012
Fund Project: 国家重大科学研究计划项目(2009CB930600, 2012CB933301) (2009CB930600, 2012CB933301) 国家自然科学基金(20833002, 20903057, 20905038, 20974046) (20833002, 20903057, 20905038, 20974046) 教育部创新团队(IRT1148) (IRT1148) 江苏省优势学科, 国际合作重点项目(BZ2010043) (BZ2010043) 江苏省自然科学基金(BK2010525, BK2011750)资助项目 (BK2010525, BK2011750)

Carbon microtubes (CMTs) were prepared by the carbonization of poplar catkins according to their natural microtubular structure. The CMTs were then used as the substrate for growing carbon nanotubes (CNTs) by chemical vapor deposition. The prepared three-dimensional CMT/CNT composites were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy. Two-electrode supercapacitor cells constructed with the CMT/CNT showed a specific capacitance of 77 F·g^-1 with 1 mol·L^-1Li₂SO₄ electrolyte, which is much higher than that for CMTs (23 F·g^-1).
- Carbon microtube,
- Carbon nanotube,
- Poplar catkin,
- Biomass,
- Supercapacitor
1. [1]
  
  (1) Yang, Z.; Yao, Z.; Li, G. F.; Fang, G. Y.; Nie, H. G.; Liu, Z.;Zhou, X. M.; Chen, X.; Huang, S. M. ACS Nano 2012, 6, 205.doi: 10.1021/nn203393d
2. [2]
  (2) Wang, Z. J.; Jia, R. R.; Zheng, J. F.; Zhao, J. G.; Li, L.; Song, J.L.; Zhu, Z. P. ACS Nano 2011, 5, 1677. doi: 10.1021/nn1030127
3. [3]
  (3) Zhang, M. H.; Yuan, R.; Chai, Y. Q.; Chen, S. H.; Zhong, X.;Zhong, H. A.;Wang, C. RSC Adv. 2012, 2, 4639. doi: 10.1039/c2ra20374j
4. [4]
  (4) Yoo, J. J.; Balakrishnan, K.; Huang, J. S.; Meunier, V.; Sumpter,B. G.; Srivastava, A.; Conway, M.; Reddy, A. L. M.; Yu, J.;Vajtai, R.; Ajayan, P. M. Nano Lett. 2011, 11, 1423. doi: 10.1021/nl200225j
5. [5]
  (5) Masarapu, C.; Zeng, H. F.; Hung, K. H.;Wei, B. Q. ACS Nano2009, 3, 2199. doi: 10.1021/nn900500n
6. [6]
  (6) Zhang, L.; Shi, G. Q. J. Phys. Chem. C 2011, 115, 17206. doi: 10.1021/jp204036a
7. [7]
  (7) Vinayan, B. P.; Nagar, R.; Raman, V.; Rajalakshmi, N.;Dhathathreyan, K. S.; Ramaprabhu, S. J. Mater. Chem. 2012,22, 9949. doi: 10.1039/c2jm16294f
8. [8]
  (8) Woo, S.; Kim, Y. R.; Chung, T. D.; Piao, Y.; Kim, H.Electrochim. Acta 2012, 59, 509. doi: 10.1016/j.electacta.2011.11.012
9. [9]
  (9) Li, J. J.; Ma, Y.W.; Jiang, X.; Feng, X. M.; Fan, Q. L.; Huang,W. IEEE Trans. Nanotechnol. 2012, 11, 3. doi: 10.1109/TNANO.2011.2158236
10. [10]
  (10) Yun, Y. S.; Kim, D.; Tak, Y.; Jin, H. J. Synth. Met. 2011, 161, 21.
11. [11]
  (11) Dujardin, E.; Ebbesen, T.W.; Hiura, H.; Tanigaki, K. Science1994, 265, 1850. doi: 10.1126/science.265.5180.1850
12. [12]
  (12) Pan, X. L.; Fan, Z. L.; Chen,W.; Ding, Y. J.; Luo, H. Y.; Bao, X.H. Nat. Mater. 2007, 6, 507. doi: 10.1038/nmat1916
13. [13]
  (13) Meduri, P.; Kim, J. H.; Russell, H. B.; Jasinski, J.;Sumanasekera, G. U.; Sunkara, M. K. J. Phys. Chem. C 2010,114, 10621. doi: 10.1021/jp100422f
14. [14]
  (14) Yu, Y.; Gu, L.; Zhu, C. B.; van Aken, P. A.; Maier, J. J. Am. Chem. Soc. 2009, 131, 15984. doi: 10.1021/ja906261c
15. [15]
  (15) Hummer, G.; Rasaiah, J. C.; Noworyta, J. P. Nature 2001, 414,188. doi: 10.1038/35102535
16. [16]
  (16) Supple, S.; Quirke, N. Phys. Rev. Lett. 2003, 90, 214501.
17. [17]
  (17) Pint, C. L.; Nicholas, N.W.; Xu, S.; Sun, Z. Z.; Tour, J. M.;Schmidt, H. K.; rdon, R. G.; Hauge, R. H. T. Carbon 2011,49, 4890. doi: 10.1016/j.carbon.2011.07.011
18. [18]
  (18) Lu,W.; Qu, L. T.; Henry, K.; Dai, L. M. J. Power Sources 2009,189, 1270. doi: 10.1016/j.jpowsour.2009.01.009
19. [19]
  (19) Ma, Y.W.; Sun, L. Y.; Huang,W.; Zhang, L. R.; Zhao, J.; Fan,Q. L.; Huang,W. J. Phys. Chem. C 2011, 115, 24592. doi: 10.1021/jp207736h
20. [20]
  (20) Ma, Y.W.; Zhao, J.; Zhang, L. R.; Zhao, Y.; Fan, Q. L.; Li, X.A.; Hu, Z.; Huang,W. Carbon 2011, 49, 5292. doi: 10.1016/j.carbon.2011.07.049
21. [21]
  (21) Ma, Y.W.; Xiong, C. Y.; Huang,W.; Zhao, J. Chin. J. Inorg. Chem. 2012, 28, 546. [马延文, 熊传银, 黄雯, 赵进, 李兴螯, 范曲立, 黄维. 无机化学学报, 2012, 28, 546.]
22. [22]
  (22) Han, C. C.; Lee, J. T.; Yang, R.W.; Chang, H.; Han, C. H.Chem. Mater. 1999, 11, 1806. doi: 10.1021/cm990032p
23. [23]
  (23) Dresselhaus, M. S.; Dresselhaus, G.; Saito, R.; Jorio, A. Phys. Rep. 2005, 409, 47. doi: 10.1016/j.physrep.2004.10.006
24. [24]
  (24) Hsieh, C. T.; Chou, Y.W.; Chen,W. Y. J. Solid State Electrochem. 2008, 12, 663. doi: 10.1007/s10008-007-0399-9
25. [25]
  (25) Chen,W.; Rakhi, R. B.; Hu, L. B.; Xie, X.; Cui, Y.; Alshareef,H. N. Nano Lett. 2011, 11, 5165. doi: 10.1021/nl2023433
26. [26]
  (26) Zhang, L. L.; Zhao, S. Y.; Tian, X. N.; Zhao, X. S. Langmuir2010, 26, 17624. doi: 10.1021/la103413s
27. [27]
  (27) Liu, C. G.; Yu, Z. N.; Neff, D.; Zhamu, A.; Jang, B. Z. Nano Lett. 2010, 10, 4863. doi: 10.1021/nl102661q
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
3. [3]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
4. [4]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
5. [5]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
6. [6]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
7. [7]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
8. [8]
  Qiqi Li , Su Zhang , Yuting Jiang , Linna Zhu , Nannan Guo , Jing Zhang , Yutong Li , Tong Wei , Zhuangjun Fan . 前驱体机械压实制备高密度活性炭及其致密电容储能性能. Acta Physico-Chimica Sinica, 2025, 41(3): 2406009-. doi: 10.3866/PKU.WHXB202406009
9. [9]
  Guanghui SUI , Yanyan CHENG . Application of rice husk-based activated carbon-loaded MgO composite for symmetric supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 521-530. doi: 10.11862/CJIC.20240221
10. [10]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
11. [11]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
12. [12]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
13. [13]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
14. [14]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
15. [15]
  Min LUO , Xiaonan WANG , Yaqin ZHANG , Tian PANG , Fuzhi LI , Pu SHI . Porous spherical MnCo₂S₄ as high-performance electrode material for hybrid supercapacitors. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 413-424. doi: 10.11862/CJIC.20240205
16. [16]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
17. [17]
  Jinghan ZHANG , Guanying CHEN . Progress in the application of rare-earth-doped upconversion nanoprobes in biological detection. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2335-2355. doi: 10.11862/CJIC.20240249
18. [18]
  Meiqing Yang , Lu Wang , Haozi Lu , Yaocheng Yang , Song Liu . Recent Advances of Functional Nanomaterials for Screen-Printed Photoelectrochemical Biosensors. Acta Physico-Chimica Sinica, 2025, 41(2): 100018-. doi: 10.3866/PKU.WHXB202310046
19. [19]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
20. [20]
  Ziheng Zhuang , Xiao Xu , Kin Shing Chan . Superdrugs for Superbugs. University Chemistry, 2024, 39(9): 128-133. doi: 10.3866/PKU.DXHX202309040

Get Citation

PDF

XML

Metrics

PDF Downloads(925)
Abstract views(2295)
HTML views(51)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142