Citation: HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei. Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2269-2275. doi: 10.3866/PKU.WHXB201209061 shu

Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor

1.
Jiangsu Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China

Received Date: 3 July 2012
Available Online: 6 September 2012
Fund Project: 国家重大科学研究计划项目(2009CB930600, 2012CB933301) (2009CB930600, 2012CB933301) 国家自然科学基金(20833002, 20903057, 20905038, 20974046) (20833002, 20903057, 20905038, 20974046) 教育部创新团队(IRT1148) (IRT1148) 江苏省优势学科, 国际合作重点项目(BZ2010043) (BZ2010043) 江苏省自然科学基金(BK2010525, BK2011750)资助项目 (BK2010525, BK2011750)

Carbon microtubes (CMTs) were prepared by the carbonization of poplar catkins according to their natural microtubular structure. The CMTs were then used as the substrate for growing carbon nanotubes (CNTs) by chemical vapor deposition. The prepared three-dimensional CMT/CNT composites were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy. Two-electrode supercapacitor cells constructed with the CMT/CNT showed a specific capacitance of 77 F·g^-1 with 1 mol·L^-1Li₂SO₄ electrolyte, which is much higher than that for CMTs (23 F·g^-1).
- Carbon microtube,
- Carbon nanotube,
- Poplar catkin,
- Biomass,
- Supercapacitor
1. [1]
  
  (1) Yang, Z.; Yao, Z.; Li, G. F.; Fang, G. Y.; Nie, H. G.; Liu, Z.;Zhou, X. M.; Chen, X.; Huang, S. M. ACS Nano 2012, 6, 205.doi: 10.1021/nn203393d
2. [2]
  (2) Wang, Z. J.; Jia, R. R.; Zheng, J. F.; Zhao, J. G.; Li, L.; Song, J.L.; Zhu, Z. P. ACS Nano 2011, 5, 1677. doi: 10.1021/nn1030127
3. [3]
  (3) Zhang, M. H.; Yuan, R.; Chai, Y. Q.; Chen, S. H.; Zhong, X.;Zhong, H. A.;Wang, C. RSC Adv. 2012, 2, 4639. doi: 10.1039/c2ra20374j
4. [4]
  (4) Yoo, J. J.; Balakrishnan, K.; Huang, J. S.; Meunier, V.; Sumpter,B. G.; Srivastava, A.; Conway, M.; Reddy, A. L. M.; Yu, J.;Vajtai, R.; Ajayan, P. M. Nano Lett. 2011, 11, 1423. doi: 10.1021/nl200225j
5. [5]
  (5) Masarapu, C.; Zeng, H. F.; Hung, K. H.;Wei, B. Q. ACS Nano2009, 3, 2199. doi: 10.1021/nn900500n
6. [6]
  (6) Zhang, L.; Shi, G. Q. J. Phys. Chem. C 2011, 115, 17206. doi: 10.1021/jp204036a
7. [7]
  (7) Vinayan, B. P.; Nagar, R.; Raman, V.; Rajalakshmi, N.;Dhathathreyan, K. S.; Ramaprabhu, S. J. Mater. Chem. 2012,22, 9949. doi: 10.1039/c2jm16294f
8. [8]
  (8) Woo, S.; Kim, Y. R.; Chung, T. D.; Piao, Y.; Kim, H.Electrochim. Acta 2012, 59, 509. doi: 10.1016/j.electacta.2011.11.012
9. [9]
  (9) Li, J. J.; Ma, Y.W.; Jiang, X.; Feng, X. M.; Fan, Q. L.; Huang,W. IEEE Trans. Nanotechnol. 2012, 11, 3. doi: 10.1109/TNANO.2011.2158236
10. [10]
  (10) Yun, Y. S.; Kim, D.; Tak, Y.; Jin, H. J. Synth. Met. 2011, 161, 21.
11. [11]
  (11) Dujardin, E.; Ebbesen, T.W.; Hiura, H.; Tanigaki, K. Science1994, 265, 1850. doi: 10.1126/science.265.5180.1850
12. [12]
  (12) Pan, X. L.; Fan, Z. L.; Chen,W.; Ding, Y. J.; Luo, H. Y.; Bao, X.H. Nat. Mater. 2007, 6, 507. doi: 10.1038/nmat1916
13. [13]
  (13) Meduri, P.; Kim, J. H.; Russell, H. B.; Jasinski, J.;Sumanasekera, G. U.; Sunkara, M. K. J. Phys. Chem. C 2010,114, 10621. doi: 10.1021/jp100422f
14. [14]
  (14) Yu, Y.; Gu, L.; Zhu, C. B.; van Aken, P. A.; Maier, J. J. Am. Chem. Soc. 2009, 131, 15984. doi: 10.1021/ja906261c
15. [15]
  (15) Hummer, G.; Rasaiah, J. C.; Noworyta, J. P. Nature 2001, 414,188. doi: 10.1038/35102535
16. [16]
  (16) Supple, S.; Quirke, N. Phys. Rev. Lett. 2003, 90, 214501.
17. [17]
  (17) Pint, C. L.; Nicholas, N.W.; Xu, S.; Sun, Z. Z.; Tour, J. M.;Schmidt, H. K.; rdon, R. G.; Hauge, R. H. T. Carbon 2011,49, 4890. doi: 10.1016/j.carbon.2011.07.011
18. [18]
  (18) Lu,W.; Qu, L. T.; Henry, K.; Dai, L. M. J. Power Sources 2009,189, 1270. doi: 10.1016/j.jpowsour.2009.01.009
19. [19]
  (19) Ma, Y.W.; Sun, L. Y.; Huang,W.; Zhang, L. R.; Zhao, J.; Fan,Q. L.; Huang,W. J. Phys. Chem. C 2011, 115, 24592. doi: 10.1021/jp207736h
20. [20]
  (20) Ma, Y.W.; Zhao, J.; Zhang, L. R.; Zhao, Y.; Fan, Q. L.; Li, X.A.; Hu, Z.; Huang,W. Carbon 2011, 49, 5292. doi: 10.1016/j.carbon.2011.07.049
21. [21]
  (21) Ma, Y.W.; Xiong, C. Y.; Huang,W.; Zhao, J. Chin. J. Inorg. Chem. 2012, 28, 546. [马延文, 熊传银, 黄雯, 赵进, 李兴螯, 范曲立, 黄维. 无机化学学报, 2012, 28, 546.]
22. [22]
  (22) Han, C. C.; Lee, J. T.; Yang, R.W.; Chang, H.; Han, C. H.Chem. Mater. 1999, 11, 1806. doi: 10.1021/cm990032p
23. [23]
  (23) Dresselhaus, M. S.; Dresselhaus, G.; Saito, R.; Jorio, A. Phys. Rep. 2005, 409, 47. doi: 10.1016/j.physrep.2004.10.006
24. [24]
  (24) Hsieh, C. T.; Chou, Y.W.; Chen,W. Y. J. Solid State Electrochem. 2008, 12, 663. doi: 10.1007/s10008-007-0399-9
25. [25]
  (25) Chen,W.; Rakhi, R. B.; Hu, L. B.; Xie, X.; Cui, Y.; Alshareef,H. N. Nano Lett. 2011, 11, 5165. doi: 10.1021/nl2023433
26. [26]
  (26) Zhang, L. L.; Zhao, S. Y.; Tian, X. N.; Zhao, X. S. Langmuir2010, 26, 17624. doi: 10.1021/la103413s
27. [27]
  (27) Liu, C. G.; Yu, Z. N.; Neff, D.; Zhamu, A.; Jang, B. Z. Nano Lett. 2010, 10, 4863. doi: 10.1021/nl102661q
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沈阳化工大学材料科学与工程学院沈阳 110142