Citation: HUANG Wen, ZHAO Jin, KANG Qi, XU Kaichen, YU Zhen, WANG Jian, MA Yan-Wen, HUANG Wei. Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2269-2275. doi: 10.3866/PKU.WHXB201209061 shu

Preparation of Three-Dimensional Carbon Microtube/Carbon Nanotube Composites and Their Application in Supercapacitor

1.
Jiangsu Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, P. R. China

Received Date: 3 July 2012
Available Online: 6 September 2012
Fund Project: 国家重大科学研究计划项目(2009CB930600, 2012CB933301) (2009CB930600, 2012CB933301) 国家自然科学基金(20833002, 20903057, 20905038, 20974046) (20833002, 20903057, 20905038, 20974046) 教育部创新团队(IRT1148) (IRT1148) 江苏省优势学科, 国际合作重点项目(BZ2010043) (BZ2010043) 江苏省自然科学基金(BK2010525, BK2011750)资助项目 (BK2010525, BK2011750)

Carbon microtubes (CMTs) were prepared by the carbonization of poplar catkins according to their natural microtubular structure. The CMTs were then used as the substrate for growing carbon nanotubes (CNTs) by chemical vapor deposition. The prepared three-dimensional CMT/CNT composites were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy. Two-electrode supercapacitor cells constructed with the CMT/CNT showed a specific capacitance of 77 F·g^-1 with 1 mol·L^-1Li₂SO₄ electrolyte, which is much higher than that for CMTs (23 F·g^-1).
- Carbon microtube,
- Carbon nanotube,
- Poplar catkin,
- Biomass,
- Supercapacitor
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