Citation: LUO Wen-Li, SU Ya-Qiong, TIAN Xiang-Dong, ZHAO Liu-Bin, WU De-Yin, TIAN Zhong-Qun. Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201209052 shu

Reaction of p-Chloronitrobenzene Adsorbed on Silver Nanoparticles

1.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Received Date: 25 July 2012
Available Online: 5 September 2012
Fund Project: 国家自然科学基金(20973143, 91027009, 21021002) (20973143, 91027009, 21021002) 国家重点基础研究发展规划项目(973)(2009CB930703) (973)(2009CB930703)厦门大学(2010121020)资助 (2010121020)

Surface-enhanced Raman spectroscopy (SERS) on silver nanoparticles is highly sensitive because of surface plasmon resonance. We have studied the structures and photoinduced chemical reactions of p-chloronitrobenzene (PCNB) molecules adsorbed on silver nanoparticles using a combination of SERS and density functional theory (DFT) calculations. When the PCNB molecules are adsorbed to the surface of silver nanoparticles in alkaline solution, the SERS spectra are very different from the normal Raman spectra of PCNB. Comparison of the DFT simulated Raman spectra of PCNB and p,p'-dichloroazobenzene (DCAB) indicates that the new peaks in the SERS spectrum of PCNB adsorbed on silver nanoparticles arise from the azo (C－N＝N－C) group of DCAB.
- Surface-enhanced Raman spectroscopy,
- Density functional theory,
- p-Chloronitrobenzene,
- p,p'-Dichloroazobenzene,
- Silver nanoparticle
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