Citation: GAO Ji-Ning, ZHAO Hua-Bo, QI Li-Min. Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2487-2492. doi: 10.3866/PKU.WHXB201209031 shu

Synthesis of Silver Sulfide Hollow Sphere-Silver Nanoparticle Heterostructures Based on Reactive Templates

1.
Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 17 July 2012
Available Online: 3 September 2012
Fund Project: 国家自然科学基金(21173010, 21073005, 51121091)资助项目 (21173010, 21073005, 51121091)

Silver sulfide hollow sphere-silver nanoparticle heterostructures were prepared by the simultaneous cation exchange and oxidation-reduction reactions of Cu₂S hollow spheres with Ag⁺ ions in aqueous solution. The obtained Ag₂S-Ag hybrid hollow spheres consisted of Ag₂S hollow spheres about 600 nm in diameter and 20-30 nm in thickness with a single Ag nanoparticle attached to the outer surface of each Ag₂S hollow sphere. The products were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and energy dispersive X-ray spectroscopy (EDS). When CuS hollow spheres were used as the reactive template instead of Cu₂S hollow spheres, Ag₂S hollow spheres were the predominant product under similar reaction conditions, indicating that the Cu(I) in the Cu₂S hollow spheres served as a reductant for reducing Ag⁺ ions to metallic Ag, and hence played a key role in the formation of the Ag₂S-Ag hybrid hollow spheres. Furthermore, secondary deposition of Ag on the Ag₂S-Ag hybrid hollow spheres resulted in the formation of larger Ag₂S-Ag hybrid hollow spheres consisting of Ag₂S hollow spheres with around a half of the surface coated by a Ag film.
- Silver sulfide,
- Hollow sphere,
- Silver nanoparticle,
- Heterostructure,
- Reactive template,
- Chemical transformation,
- Cuprous sulfide
1. [1]
  
  (1) Costi, R.; Saunders, A. E.; Banin, U. Angew. Chem. Int. Edit.2010, 49, 4878. doi: 10.1002/anie.v49:29
2. [2]
  (2) Donega, C. D. Chem. Soc. Rev. 2011, 40, 1512. doi: 10.1039/c0cs00055h
3. [3]
  (3) Wang, C.; Xu, C. J.; Zeng, H.; Sun, S. H. Adv. Mater. 2009, 21,3045. doi: 10.1002/adma.v21:30
4. [4]
  (4) Mokari, T.; Rothenberg, E.; Popov, I.; Costi, R.; Banin, U.Science 2004, 304, 1787. doi: 10.1126/science.1097830
5. [5]
  (5) Robinson, R. D.; Sadtler, B.; Demchenko, D. O.; Erdonmez, C.K.;Wang, L.W.; Alivisatos, A. P. Science 2007, 317, 355. doi: 10.1126/science.1142593
6. [6]
  (6) Saruyama, M.; So, Y. G.; Kimoto, K.; Taguchi, S.; Kanemitsu,Y.; Teranishi, T. J. Am. Chem. Soc. 2011, 133, 17598. doi: 10.1021/ja2078224
7. [7]
  (7) Habas, S. E.; Yang, P. D.; Mokari, T. J. Am. Chem. Soc. 2008,130, 3294. doi: 10.1021/ja800104w
8. [8]
  (8) Yang, J.; Elim, H. I.; Zhang, Q. B.; Lee, J. Y.; Ji,W. J. Am.Chem. Soc. 2006, 128, 11921. doi: 10.1021/ja062494r
9. [9]
  (9) Zhao, N. N.; Li, L. S.; Huang, T.; Qi, L. M. Nanoscale 2010, 2,2418. doi: 10.1039/c0nr00385a
10. [10]
  (10) Leung, K. C. F.; Xuan, S. H.; Zhu, X. M.;Wang, D.W.; Chak,C. P.; Lee, S. F.; Ho,W. K.W.; Chung, B. C. T. Chem. Soc. Rev.2012, 41, 1911. doi: 10.1039/c1cs15213k
11. [11]
  (11) Buck, M. R.; Bondi, J. F.; Schaak, R. E. Nat. Chem. 2012, 4, 37.
12. [12]
  (12) Guo, X.; Zhang, Q.; Sun, Y. H.; Zhao, Q.; Yang, J. ACS Nano2012, 6, 1165. doi: 10.1021/nn203793k
13. [13]
  (13) Sun, Y. P.; Riggs, J. E.; Rollins, H.W.; Guduru, R. J. Phys.Chem. B 1999, 103, 77. doi: 10.1021/jp9835014
14. [14]
  (14) Xiang, J. H.; Cao, H. Q.;Wu, Q. Z.; Zhang, S. C.; Zhang, X. R.;Watt, A. A. R. J. Phys. Chem. C 2008, 112, 3580. doi: 10.1021/jp710597j
15. [15]
  (15) Wang, H. L.; Qi, L. M. Adv. Funct. Mater. 2008, 18, 1249. doi: 10.1002/adfm.v18:8
16. [16]
  (16) Xiao, C.; Xu, J.; Li, K.; Feng, J.; Yang, J. L.; Xie, Y. J. Am.Chem. Soc. 2012, 134, 4287. doi: 10.1021/ja2104476
17. [17]
  (17) Rycenga, M.; Cobley, C. M.; Zeng, J.; Li,W. Y.; Moran, C. H.;Zhang, Q.; Qin, D.; Xia, Y. N. Chem. Rev. 2011, 111, 3669. doi: 10.1021/cr100275d
18. [18]
  (18) Chaloupka, K.; Malam, Y.; Seifalian, A. M. Trends Biotechnol.2010, 28, 580. doi: 10.1016/j.tibtech.2010.07.006
19. [19]
  (19) Pang, M. L.; Hu, J. Y.; Zeng, H. C. J. Am. Chem. Soc. 2010,132, 10771. doi: 10.1021/ja102105q
20. [20]
  (20) Jiang, F. R.; Tian, Q.W.; Tang, M. H.; Chen, Z. G.; Yang, J. M.;Hu, J. Q. CrystEngComm 2011, 13, 7189. doi: 10.1039/c1ce05632h
21. [21]
  (21) Liu, B.; Ma, Z. F. Small 2011, 7, 1587. doi: 10.1002/smll.v7.11
22. [22]
  (22) Moon, G. D.; Ko, S.; Min, Y.; Zeng, J.; Xia, Y. N.; Jeong, U.Nano Today 2011, 6, 186. doi: 10.1016/j.nantod.2011.02.006
23. [23]
  (23) Qi, L. M. Coord. Chem. Rev. 2010, 254, 1054. doi: 10.1016/j.ccr.2010.02.005
24. [24]
  (24) Huang, T.; Qi, L. M. Sci. China Chem. 2010, 53, 365. doi: 10.1007/s11426-010-0041-z
25. [25]
  (25) Son, D. H.; Hughes, S. M.; Yin, Y. D.; Alivisatos, A. P. Science2004, 306, 1009. doi: 10.1126/science.1103755
26. [26]
  (26) Li, L. S.; Sun, N. J.; Huang, Y. Y.; Qin, Y.; Zhao, N. N.; Gao, J.N.; Li, M. X.; Zhou, H. H.; Qi, L. M. Adv. Funct. Mater. 2008,18, 1194. doi: 10.1002/adfm.v18:8
27. [27]
  (27) Yang, J. H.; Qi, L. M.; Lu, C. H.; Ma, J. M.; Cheng, H. M.Angew. Chem. Int. Edit. 2005, 44, 598. doi: 10.1002/(ISSN)1521-3773
28. [28]
  (28) Gao, J. N.; Li, Q. S.; Zhao, H. B.; Li, L. S.; Liu, C. L.; ng, Q.H.; Qi, L. M. Chem. Mater. 2008, 20, 6263. doi: 10.1021/cm801407q
29. [29]
  (29) Speight, J. G. Langes's Handbook of Chemistry, 16th ed.;McGraw-Hill: New York, 2005.
30. [30]
  (30) Rich, R. L. Inorganic Reactions in Water, 1st ed.; Springer-Verlag: Berlin Heidelberg, 2007; p 271.
31. [31]
  (31) Cozzoli, P. D.; Pellegrino, T.; Manna, L. Chem. Soc. Rev. 2006,35, 1195. doi: 10.1039/b517790c
32. [32]
  (32) Li,W. H.; Shavel, A.; Guzman, R.; Rubio-Garcia, J.; Flox, C.;Fan, J. D.; Cadavid, D.; Ibanez, M.; Arbiol, J.; Morante, J. R.;Cabot, A. Chem. Commun. 2011, 47, 10332. doi: 10.1039/c1cc13803k
33. [33]
  (33) Kruszynska, M.; Borchert, H.; Bachmatiuk, A.; Rümmeli, M.H.; Büchner, B.; Parisi, J.; Kolny-Olesiak, J. ACS Nano 2012, 6,5889. doi: 10.1021/nn302448n
34. [34]
  (34) Kryukov, A. I.; Stroyuk, A. L.; Zin'chuk, N. N.; Korzhak, A. V.;Kuchmii, S. Y. J. Mol. Catal. A-Chem. 2004, 221, 209. doi: 10.1016/j.molcata.2004.07.009
1. [1]
  Yongming Guo , Jie Li , Chaoyong Liu . Green Improvement and Educational Design in the Synthesis and Characterization of Silver Nanoparticles. University Chemistry, 2024, 39(3): 258-265. doi: 10.3866/PKU.DXHX202309057
2. [2]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
3. [3]
  Yang Chen , Peng Chen , Yuyang Song , Yuxue Jin , Song Wu . Application of Chemical Transformation Driven Impurity Separation in Experiments Teaching: A Novel Method for Purification of α-Fluorinated Mandelic Acid. University Chemistry, 2024, 39(6): 253-263. doi: 10.3866/PKU.DXHX202310077
4. [4]
  Lina Liu , Xiaolan Wei , Jianqiang Hu . Exploration of Subject-Oriented Undergraduate Comprehensive Chemistry Experimental Teaching Based on the “STS Concept”: Taking the Experiment of Gold Nanoparticles as an Example. University Chemistry, 2024, 39(10): 337-343. doi: 10.12461/PKU.DXHX202405112
5. [5]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
6. [6]
  Jiaxing Cai , Wendi Xu , Haoqiang Chi , Qian Liu , Wa Gao , Li Shi , Jingxiang Low , Zhigang Zou , Yong Zhou . 具有0D/2D界面的InOOH/ZnIn₂S₄空心球S型异质结用于增强光催化CO₂转化性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407002-. doi: 10.3866/PKU.WHXB202407002
7. [7]
  Laiying Zhang , Yaxian Zhu . Exploring the Silver Family. University Chemistry, 2024, 39(9): 1-4. doi: 10.12461/PKU.DXHX202409015
8. [8]
  Yuanyi Lu , Jun Zhao , Hongshuang Li . Silver-Catalyzed Ring-Opening Minisci Reaction: Developing a Teaching Experiment Suitable for Undergraduates. University Chemistry, 2024, 39(11): 225-231. doi: 10.3866/PKU.DXHX202401088
9. [9]
  Peng GENG , Guangcan XIANG , Wen ZHANG , Haichuang LAN , Shuzhang XIAO . Hollow copper sulfide loaded protoporphyrin for photothermal-sonodynamic therapy of cancer cells. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1903-1910. doi: 10.11862/CJIC.20240155
10. [10]
  Yuhao SUN , Qingzhe DONG , Lei ZHAO , Xiaodan JIANG , Hailing GUO , Xianglong MENG , Yongmei GUO . Synthesis and antibacterial properties of silver-loaded sod-based zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 761-770. doi: 10.11862/CJIC.20230169
11. [11]
  Qijin Mo , Meifang Zhuo , Zhiyi Zhong , Chunfang Gan , Lixia Zhang . Research-Oriented Experimental Teaching in Chemistry Education at Normal University: Taking the Project of Recovering Silver Nitrate from Silver-Containing Waste as an Example. University Chemistry, 2024, 39(6): 201-206. doi: 10.3866/PKU.DXHX202310099
12. [12]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
13. [13]
  Simin Fang , Wei Huang , Guanghua Yu , Cong Wei , Mingli Gao , Guangshui Li , Hongjun Tian , Wan Li . Integrating Science and Education in a Comprehensive Chemistry Design Experiment: The Preparation of Copper(I) Oxide Nanoparticles and Its Application in Dye Water Remediation. University Chemistry, 2024, 39(8): 282-289. doi: 10.3866/PKU.DXHX202401023
14. [14]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
15. [15]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
16. [16]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
17. [17]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
18. [18]
  Xiutao Xu , Chunfeng Shao , Jinfeng Zhang , Zhongliao Wang , Kai Dai . Rational Design of S-Scheme CeO₂/Bi₂MoO₆ Microsphere Heterojunction for Efficient Photocatalytic CO₂ Reduction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309031-. doi: 10.3866/PKU.WHXB202309031
19. [19]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
20. [20]
  Jiaqi Chen , Chunhui Luan , Yue Sun , Qiyun Ma , Wangfei Hao , Yanjia Wang , Xu Wu . Understanding the Dynamics of Heat and Cold through Chemistry: The Interplay of Chemical Energy and Thermal Energy. University Chemistry, 2024, 39(9): 214-223. doi: 10.12461/PKU.DXHX202312020

Get Citation

PDF

XML

Metrics

PDF Downloads(858)
Abstract views(2239)
HTML views(6)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142