Citation: SU Peng, GUO Hui-Lin, PENG San, NING Sheng-Ke. Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208221 shu

Preparation of Nitrogen-Doped Graphene and Its Supercapacitive Properties

1.
1 Key Laboratory of Synthetic and Natural Functional Molecule Chemistry, College of Chemistry and Materials Science, Northwest University, Xi’an 710069, P. R. China;
2 Industry Training Center, Xi’an Technological University, Xi’an 710021, P. R. China

Received Date: 29 May 2012
Available Online: 22 August 2012
Fund Project: 陕西省教育厅专项研究计划(09JK747)资助 (09JK747)

Nitrogen-doped graphene was synthesized by the hydrothermal method with graphene oxide ( ) as the raw material and urea as the reducing-doping agent. The morphology, structure, and components of the as-produced graphene were characterized by scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption-desorption analysis, and electrical conductivity measurements. The results showed that nitrogen was doped into the graphene plane at the same time as the sheets were reduced, and the nitrogen content was between 5.47%-7.56% (atomic fraction). In addition, the electrochemical performance of the graphene was tested. Nitrogen-doped graphene with a nitrogen content of 7.50% showed excellent capacitive behavior and long cycle life. The first cycle specific discharge capacitance for the material was 184.5 F·g^-1 when cycled at 3 A·g^-1, and 12.4% losses were found after 1200 cycles in anaqueous electrolyte of 6 mol·L^-1 KOH.
- Graphene,
- Nitrogen doped,
- Urea,
- Hydrothermal method,
- Supercapacitor
1. [1]
  
  (1) Pandolfo, A. G.; Hollenkamp, A. F. J. Power Sources 2006, 157,11. doi: 10.1016/j.jpowsour.2006.02.065
2. [2]
  (2) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.;Zhang, Y.; Dubonos, S. V.; Gri rieva, I. V.; Firsov, A. A.Science 2004, 306, 666. doi: 10.1126/science.1102896
3. [3]
  (3) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183. doi: 10.1038/nmat1849
4. [4]
  (4) Katsnelson, M. I. Mater. Today 2007, 10 (1-2), 20.
5. [5]
  (5) Park, S.; Ruoff, R. S. Nat. Nanotechnol. 2009, 4, 217. doi: 10.1038/nnano.2009.58
6. [6]
  (6) Hu, Y. J.; Jin, J.; Zhang, H.;Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin. 2010, 26, 2073. [胡耀娟, 金娟, 张卉, 吴萍, 蔡称心. 物理化学学报, 2010, 26, 2073.] doi: 10.3866/PKU.WHXB20100812
7. [7]
  (7) Wei, D. C.; Liu, Y. Q.;Wang, Y.; Zhang, H. L.; Huang, L. P.; Yu,G. Nano Lett. 2009, 9, 1752. doi: 10.1021/nl803279t
8. [8]
  (8) Qu, L. T.; Liu, Y.; Baek, J.-B.; Dai, L. M. ACS Nano 2010, 4,1321. doi: 10.1021/nn901850u
9. [9]
  (9) Meyer, J. C.; Kurasch, S.; Park, H. J.; Skakalova, V.; Kunzel,D.; Groβ, A.; Chuvilin A.; Algara-Siller, G.; Roth, S.; Iwasaki,T.; Starke, U.; Smet, J. H.; Kaiser, U. Nat. Mater. 2011, 10, 209.doi: 10.1038/nmat2941
10. [10]
  (10) Jeong, H. M.; Lee, J.W.; Shin,W. H.; Choi, Y. J.; Shin, H. J.;Kang, J. K.; Choi, J.W. Nano Lett. 2011, 11, 2472. doi: 10.1021/nl2009058
11. [11]
  (11) Shao, Y. Y.; Zhang, S.; Engelhard, M. H.; Li, G. S.; Shao, G. C.;Wang, Y.; Liu, J.; Aksay, I. A.; Lin, Y. H. J. Mater. Chem. 2010,20, 7491. doi: 10.1039/c0jm00782j
12. [12]
  (12) Wang, Y.; Shao, Y. Y; Matson, D.W.; Li, J. H.; Lin, Y. H. ACS Nano 2010, 4, 1790. doi: 10.1021/nn100315s
13. [13]
  (13) Li, N.;Wang, Z. Y.; Zhao, K. K.; Shi, Z. J.; Gu, Z. N.; Xu, S. K.Carbon 2010, 48, 255. doi: 10.1016/j.carbon.2009.09.013
14. [14]
  (14) Panchokarla, L. S.; Subrahmanyam, K. S.; Saha, S. K.; vindaraj, A.; Krisnamurthy, H. R.;Waghmare, U. V.; Rao, C.N. R. Adv. Mater. 2009, 21, 4726. doi: 10.1002/adma.200901335
15. [15]
  (15) Wang, X. R.; Li, X. L.; Zhang, L.; Yoon, Y.;Weber, P. K.;Wang,H. L.; Guo, J.; Dai, H. J. Science 2009, 324, 768. doi: 10.1126/science.1170335
16. [16]
  (16) Guo, B. D.; Liu, Q.; Chen, E. D.; Zhu, H.W.; Fang, L.; ng, J.R. Nano Lett. 2010, 10, 4975. doi: 10.1021/nl103079j
17. [17]
  (17) Sheng, Z. H.; Shao, L.; Chen, J. J.; Bao,W. J.;Wang, F. B.; Xia,X. H. ACS Nano 2011, 5, 4350. doi: 10.1021/nn103584t
18. [18]
  (18) Li, X. L.;Wang, H. L.; Robinson, J. T.; Sanchez, H.; Diankov,G.; Dai, H. J. J. Am. Chem. Soc. 2009, 131, 15939. doi: 10.1021/ja907098f
19. [19]
  (19) Jin, Z.; Yao, J.; Kittrell, C.; Tour, J. M. ACS Nano 2011, 5, 4112.doi: 10.1021/nn200766e
20. [20]
  (20) Reddy, A. L. M.; Srivastava, A.; wda, S. R.; Gullapalli, H.;Dubey, M.; Ajayan, P. M. ACS Nano 2010, 4, 6337. doi: 10.1021/nn101926g
21. [21]
  (21) Qian,W.; Cui, X.; Hao, R.; Hou, Y. L.; Zhang, Z. Y. ACS Appl. Mater. Interfaces 2011, 3, 2259. doi: 10.1021/am200479d
22. [22]
  (22) Mou, Z. G.; Chen, X. Y.; Du, Y. K.;Wang, X. M.; Yang, P.;Wang, S. D. Appl. Surf. Sci. 2011, 258, 1704. doi: 10.1016/j.apsusc.2011.10.019
23. [23]
  (23) Sun, L.;Wang, L.; Tian, C. G.; Tan, T. X.; Xie, Y.; Shi, K. Y.; Li,M. T.; Fu, H. G. RSC Adv. 2012, 2, 4498. doi: 10.1039/c2ra01367c
24. [24]
  (24) Wakeland, S.; Martinez, R.; Grey, J. K.; Luhrs, C. C. Carbon2010, 48, 3463. doi: 10.1016/j.carbon.2010.05.043
25. [25]
  (25) Kovtyukhova, N. I.; Ollivier, P. J.; Martin, B. R.; Mallouk, T. E.;Chizhik, S. A.; Buzaneva, E. V.; rchinskiy, A. D. Chem. Mater. 1999, 11, 771. doi: 10.1021/cm981085u
26. [26]
  (26) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80,1339. doi: 10.1021/ja01539a017
27. [27]
  (27) Xue, L. P.; Zheng, M. B.; Shen, C. F.; Lü, H. L.; Li, N.W.; Pan,L. J.; Cao, J. M. Chin. J. Inorg. Chem. 2010, 26, 1375. [薛露平, 郑明波, 沈辰飞, 吕洪岭, 李念武, 潘力佳, 曹洁明. 无机化学学报, 2010, 26, 1375.]
28. [28]
  (28) Hontoria-Lucas, C.; Lopez-Peinado, A. J.; Lopez- nzalez, J.D.; Rojas-Cervantes, M. L.; Martin-Aranda, R. M. Carbon1995, 33, 1585. doi: 10.1016/0008-6223(95)00120-3
29. [29]
  (29) Guo, H. L.;Wang, X. F.; Qian, Q. Y.;Wang, F. B.; Xia, X. H.ACS Nano 2009, 3, 2653. doi: 10.1021/nn900227d
30. [30]
  (30) Liu, Z. H.;Wang, Z. M.; Yang, X. J.; Ooi, K. Langmuir 2002,18, 4926. doi: 10.1021/la011677i
31. [31]
  (31) Chen, Y.; Zhang, X.; Yu, P.; Ma, Y.W. J. Power Sources 2010,195, 3031. doi: 10.1016/j.jpowsour.2009.11.057
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