Citation: WANG Jia-Rui, YANG Yang, YAN Yun, HUANG Jian-Bin. Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions[J]. Acta Physico-Chimica Sinica, ;2012, 28(10): 2291-2297. doi: 10.3866/PKU.WHXB201208131 shu

Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions

1.
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Received Date: 20 July 2012
Available Online: 13 August 2012
Fund Project: 北京大学校长基金及国家自然科学基金(20903005, 21173011, 51121091, 21073006)资助项目 (20903005, 21173011, 51121091, 21073006)

Fluorescent microcapsules based on coordination supramolecular polymers of rare earth metal ions were prepared via a layer-by-layer technique that used electrostatic interaction. The holes in the capsule walls were very small, which reduced leakage of small molecular payloads. The capsules remained intact at salt concentrations as high as 500 mmol·L^-1, which shows they have potential in practical applications. Multicolored capsules were obtained simply using a mixture of terbium and europium ions.
- Layer-by-layer assembly,
- Fluorescent capsule,
- Metallic coordination supramolecular polymer
1. [1]
  
  (1) Manners, I. Science 2001, 294, 1664. doi: 10.1126/science.1066321
2. [2]
  (2) Takae, S.; Miyata, K.; Oba, M.; Nishiyama, N.; Itaka, K.;Yamasaki, Y.; Koyama, H.; Kataoka, K. J. Am. Chem. Soc.2008, 130, 6001. doi: 10.1021/ja800336v
3. [3]
  (3) Berret, J. F.; Schonbeck, N.; Gazeau, F.; Kharrat, D. E.; Sandre,O.; Vacher, A.; Airiau, M. J. Am. Chem. Soc. 2006, 128, 1755.doi: 10.1021/ja0562999
4. [4]
  (4) Schubert, U. S.; Newkome, G. R.; Manners, I. Metal-Containing and Metallo-Supramolecular Polymers and Materials, Vol. 928;ACS:Washington DC, 2006.
5. [5]
  (5) Burnworth, M.; Knapton, D.; Rowan, S. J.;Weder, C. J. Inorg. Org. Polym. Mater. 2007, 17, 97.
6. [6]
  (6) Kurth, D. G.; Higuchi, M. Soft Matter 2006, 2, 915. doi: 10.1039/b607485e
7. [7]
  (7) Yan, Y.; Huang, J. B. Coord. Chem. Rev. 2010, 254, 1072. doi: 10.1016/j.ccr.2009.12.024
8. [8]
  (8) Caruso, F.; Schuler, C.; Kurth, D. G. Chem. Mater. 1999, 11,3394. doi: 10.1021/cm9911058
9. [9]
  (9) Schutte, M.; Kurth, D. G.; Linford, M. R.; Colfen, H.;Mohwald, H. Angew. Chem. Int. Edit. 1998, 37, 2891. doi: 10.1002/(ISSN)1521-3773
10. [10]
  (10) Song,W. X.; He, Q.; Mohwald, H.; Yang, Y.; Li, J. B.J. Controlled. Release 2009, 139, 160. doi: 10.1016/j.jconrel.2009.06.010
11. [11]
  (11) Yang, L.; Ding, Y.; Yang, Y.; Yan, Y.; Huang, J. B.; de Keizer,A.; Cohen Stuart, M. A. Soft Matter 2011, 7, 2720.
12. [12]
  (12) Vermonden, T. Macromolecules 2003, 36, 735.
13. [13]
  (13) Antipov, A. A.; Shchukin, D.; Fedutik, Y.; Petrov, A. I.;Sukhorukov, G. B.; Mohwald, H. Colloids and Surfaces A: Physicochem. Eng. Aspects 2003, 224, 175. doi: 10.1016/S0927-7757(03)00195-X
14. [14]
  (14) Gao, L.; Fei, J. B.; Zhao, J.; Cui,W.; Cui, Y.; Li, J. B. Chem. Eur. J. 2012, 18, 3185. doi: 10.1002/chem.v18.11
15. [15]
  (15) Cui, J.W.; Zhang, R. J.; Lin, Z. G.; Li, L.; Jin,W. R. Dalton Trans. 2008, 7, 895.
16. [16]
  (16) Lakowicz, J. R. Principles of Fluorescence Spectroscopy, 3rded.; Springer: Berlin, 2006; pp 101-103.
17. [17]
  (17) Nogami, M.; Abe, Y. J. Non-Cryst. Solids 1996, 197, 73. doi: 10.1016/0022-3093(95)00621-4
18. [18]
  (18) Capobianco, J. A.; Proulx, P. P.; Bettinelli, M.; Negrisolo, F.Phys. Rev. B 1990, 42, 5936. doi: 10.1103/PhysRevB.42.5936
19. [19]
  (19) Kamphuis, M. M. J.; Johnston, A. P. R.; Such, G. K.; Dam, H.H.; Evans, R. A.; Scott, A. M.; Nice, E. C.; Heath, J. K.; Caruso,F. J. Am. Chem. Soc. 2010, 132, 15881. doi: 10.1021/ja106405c
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Fluorescent Microcapsules Based on Coordination Supramolecular Polymers of Rare Earth Metal Ions

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com