Citation: CHEN Qiang, NULI Yanna, YANG Jun, KAILIBINUER Kerimu, WANG Jiulin. Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201208032 shu

Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries

1.
School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, P. R. China

Received Date: 20 June 2012
Available Online: 3 August 2012
Fund Project: 国家自然科学基金(20603022, 20973112)资助项目 (20603022, 20973112)

The effects of metal (platinum, nickel, stainless steel (SS), copper and aluminum) and carbon paper (carbon fiber, graphite foil and carbon cloth) current collectors on the anodic stability and magnesium deposition-dissolution of the electrolytes (Mg(AlCl₂BuEt)₂/THF and (PhMgCl)₂-AlCl₃/THF) for rechargeable magnesium batteries were studied by cyclic voltammogram and constant current deposition-dissolution measurements. Nickel, stainless steel, copper and aluminum current collectors occur corrosion upon charging process. Nickel or stainless steel exhibits a higher stability, which can be used as the current collector for the cathode materials with a charging voltage under 2.1V (vs Mg/Mg²⁺). While copper is suitable for the cathode with a charging voltage under 1.8V (vs Mg/Mg²⁺). Furthermore, carbon paper current collectors have a higher anodic stability than metals. Carbon cloth is appropriate for the cathode materials with a charging voltage under 2.25V (vs Mg/Mg²⁺) in Mg(AlCl₂BuEt)₂/THF and 2.95V (vs Mg/Mg²⁺) in (PhMgCl)₂-AlCl₃/THF.
- Rechargeable magnesium battery,
- Current collector,
- Metal,
- Carbon paper,
- Electrolyte
1. [1]
  
  (1) Gre ry, T. D.; Hoffman, R. J.;Winterton, R. C. J. Electrochem. Soc. 1990, 137, 775. doi: 10.1149/1.2086553
2. [2]
  (2) Aurbach, D.; Lu, Z.; Schechter, A.; fer, Y.; Gizbar, H.;Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature2000, 407, 724. doi: 10.1038/35037553
3. [3]
  (3) Yuan, H. T.;Wu, F.;Wu, X. L.; Li, Q. Battery Bimonthly 2002,32, 14. [袁华堂, 吴峰, 武绪丽, 李强. 电池, 2002, 32,14.]
4. [4]
  (4) Shen, J.; Peng, B.; Tao, Z. L.; Chen, J. Progess in Chemistry2012, 22, 515. [沈健, 彭博, 陶占良, 陈军. 化学进展,2010, 22, 515.]
5. [5]
  (5) Zheng, Y. P.; NuLi, Y. N.; Yang, J.; Chen, Q.;Wang, J. L.Chemical Industry and Engineering Progress 2011, 30 (5),1024. [郑育培, 努丽燕娜, 杨军, 陈强, 王久林.化工进展, 2011, 30 (5), 1024.]
6. [6]
  (6) Zhao, Q. S.; Nuli, Y. N.; Guo, Y. S.; Yang, J.;Wang, J. L.Progress in Chemistry 2011, 23, 1598. [赵青松, 努丽燕娜,郭永胜, 杨军, 王久林. 化学进展, 2011, 23, 1598.]
7. [7]
  (7) Aurbach, D.; Schechter, A.; Moshkovich, M.; Cohen, Y.;J. Electrochem. Soc. 2001, 148, A1004.
8. [8]
  (8) Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; ttlieb, H.E.; fer, Y.; ldberg, I. J. Electrochem. Soc. 2002, 149, A115.
9. [9]
  (9) Gizbar, H.; Vestfrid, Y.; Chusid, O.; fer, Y.; ttlieb, H. E.;Marks, V.; Aurbach, D. Organometallics 2004, 23, 3826. doi: 10.1021/om049949a
10. [10]
  (10) Vestfried, Y.; Chusid, O.; fer, Y.; Aped, P.; Aurbach, D.Organometallics 2007, 26, 3130. doi: 10.1021/om061076s
11. [11]
  (11) Viestfried, Y.; Levi, M. D.; fer, Y.; Aurbach, D.J. Electroanal. Chem. 2005, 576, 183. doi: 10.1016/j.jelechem.2004.09.034
12. [12]
  (12) Aurbach, D.; Suresh, G. S.; Levi, E.; Mitelman, A.; Mizrahi, O.;Chusid, O.; Brunelli, M. Adv. Mater. 2007, 19, 4260. doi: 10.1002/(ISSN)1521-4095
13. [13]
  (13) Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.; ttlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D.J. Electrochem. Soc. 2008, 155, A103.
14. [14]
  (14) Pour, N.; fer, Y.; Major, D. T.; Aurbach, D. J. Am. Chem. Soc.2011, 133, 6270. doi: 10.1021/ja1098512
15. [15]
  (15) Arora, P.; White, R. E.; Doyle, M. J. Electrochem. Soc. 1998,145, 3647. doi: 10.1149/1.1838857
16. [16]
  (16) Tarascon, J.; Guyomard, D. Solid State Ionics 1994, 69, 293.doi: 10.1016/0167-2738(94)90418-9
17. [17]
  (17) Kanamura, K.; Toriyama, S.; Shiraishi, S.; Takehara, Z.J. Electrochem. Soc. 1995, 142, 1383. doi: 10.1149/1.2048586
18. [18]
  (18) Dahn, J. R; Fuller, E.W.; Obrovac, M.; Von Sacken, U. Solid State Ionics 1994, 69, 265. doi: 10.1016/0167-2738(94)90415-4
19. [19]
  (19) Amatucci, G.; Tarascon, J.; Klein, L. Solid State Ionics 1996,83, 167.
20. [20]
  (20) Morita, M.; Shibata, T.; Yoshimoto, N.; Ishikawa, M.Electrochim. Acta 2002, 47, 2787. doi: 10.1016/S0013-4686(02)00164-0
21. [21]
  (21) Kanamura, K. J. Power Sources 1999, 81-82, 123.
22. [22]
  (22) Peng, C. X. Research on the Compatibility between CurrentCollectors and New Ionic Liquid Electrolytes for LithiumSecondary Batteries. Ph. D. Dissertation, Shanghai JiaotongUniversity, Shanghai, 2008. [彭成信. 锂离子电池集流体与新型离子液体电解液的相容性及界面电化学行为研究[D].上海: 上海交通大学, 2008.]
23. [23]
  (23) Ni, J. F.; Zhou, H. H.; Chen, J. T.; Zhang, X.Y. Battery Bimonthly2005, 35, 128. [倪江锋, 周恒辉, 陈继涛, 张新祥. 电池,2005, 35, 128.]
24. [24]
  (24) Iwakura, C.; Fukumoto, Y.; Inoue, H.; Ohashi, S.; Kobayashi,S.; Tada, H.; Abe, M. J. Power Sources 1997, 68, 3013.
25. [25]
  (25) Dai, Y. H.; Zhou, Y. M.;Wang, Q.; Tang, Y.W.; Lu, T. H.; Shen,T. Chinese Battery Industry 2007, 12, 31. [戴跃华, 周益明,王青, 唐亚文, 陆天虹, 沈涛. 电池工业, 2007, 12, 31.]
26. [26]
  (26) Aurbach, D.; Turgeman, R.; Chusid, O.; fer, Y. Electrochem. Commun. 2001, 3, 252. doi: 10.1016/S1388-2481(01)00148-5
27. [27]
  (27) Liebenow, C.; Yang, Z.; Lobitz, P. Electrochem. Commun. 2000,2, 641. doi: 10.1016/S1388-2481(00)00094-1
28. [28]
  (28) Tang, Z, Y.; He, Y. B.; Liu, Y. G.; Liu, Q.; Yang, X. X. Corrosion Science and Protection Technology 2007, 19, 265. [唐致远,贺艳兵, 刘元刚, 刘强, 阳晓霞. 腐蚀科学与防腐技术, 2007,19, 265.]
29. [29]
  (29) Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui,M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Energy Environ. Sci. 2012, 5, 5941.
1. [1]
  Peng ZHOU , Xiao CAI , Qingxiang MA , Xu LIU . Effects of Cu doping on the structure and optical properties of Au₁₁(dppf)₄Cl₂ nanocluster. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240047
2. [2]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, doi: 10.3866/PKU.DXHX202308094
3. [3]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, doi: 10.3866/PKU.DXHX202401060
4. [4]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230350
5. [5]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, doi: 10.3866/PKU.DXHX202311091
6. [6]
  Yueguang Chen , Wenqiang Sun . “Carbon” Adventures. University Chemistry, doi: 10.3866/PKU.DXHX202308074
7. [7]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, doi: 10.12461/PKU.DXHX202404023
8. [8]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, doi: 10.3866/PKU.DXHX202311069
9. [9]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202309028
10. [10]
  Zitong Chen , Zipei Su , Jiangfeng Qian . Aromatic Alkali Metal Reagents: Structures, Properties and Applications. University Chemistry, doi: 10.3866/PKU.DXHX202311054
11. [11]
  Qin Tu , Anju Tao , Tongtong Ma , Jinyi Wang . Innovative Experimental Teaching of Escherichia coli Detection Based on Paper Chip. University Chemistry, doi: 10.3866/PKU.DXHX202309062
12. [12]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, doi: 10.3866/PKU.DXHX202308057
13. [13]
  Lei Shu , Zimin Duan , Yushen Kang , Zijian Zhao , Hong Wang , Lihua Zhu , Hui Xiong , Nan Wang . An Exploration of the CO₂-Involved Carbon Cycle World. University Chemistry, doi: 10.3866/PKU.DXHX202309084
14. [14]
  Zuozhong Liang , Lingling Wei , Yiwen Cao , Yunhan Wei , Haimei Shi , Haoquan Zheng , Shengli Gao . Exploring the Development of Undergraduate Scientific Research Ability in Basic Course Instruction: A Case Study of Alkali and Alkaline Earth Metal Complexes in Inorganic Chemistry. University Chemistry, doi: 10.3866/PKU.DXHX202310103
15. [15]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20230293
16. [16]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, doi: 10.3866/PKU.WHXB202312014
17. [17]
  Aiai WANG , Lu ZHAO , Yunfeng BAI , Feng FENG . Research progress of bimetallic organic framework in tumor diagnosis and treatment. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240225
18. [18]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, doi: 10.11862/CJIC.20240014
19. [19]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, doi: 10.3866/PKU.DXHX202312017
20. [20]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, doi: 10.3866/PKU.DXHX202312022

Get Citation

PDF

XML

Metrics

PDF Downloads(1084)
Abstract views(3005)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142