Citation: JIN Jing, XU Xiao-Ting, CONG Sheng-Mei, LI Lei, ZHANG Guang-Ning, NIU Shu-Yun. Syntheses, Structures and Photoelectron Property of a Series of Cu(II/I) Coordination Polymers[J]. Acta Physico-Chimica Sinica doi: 10.3866/PKU.WHXB201207311 shu

Syntheses, Structures and Photoelectron Property of a Series of Cu(II/I) Coordination Polymers

1.
1 School of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China;
2 Institute of Chemistry for Functionalized Materials of Liaoning Normal University, Dalian 116029, Liaoning Province, P. R. China

Received Date: 21 May 2012
Available Online: 31 July 2012
Fund Project: 国家自然科学基金(20571037) (20571037)辽宁省创新团队项目(2007T092)资助 (2007T092)

Three Cu(II/I) coordination polymers/supramolecules were obtained by means of hydrothermal synthesis: (1) [K₂Cu₂(ox)(btec)(MeOH)₂]_n, (2) {[Cu(pdc)(H₂O)₂]?H₂O}_n, and (3) [Cu(cyan)(phen)]?H₂O (where H₂ox is oxalic acid, H4btec is 1,2,4,5-benzenetetracarboxylic acid, MeOH is methanol, H₂pdc is pyridine-2, 5-dicarboxylic acid, phen is 1,10-phenanthroline, and Hcyan is cyanuric acid). These compounds were characterized by single crystal X-ray diffraction, surface photovoltage spectroscopy (SPS), solid phase ultraviolet-visible spectroscopy (UV-Vis), Fourier transform infrared (FTIR) spectroscopy, and elemental analysis. Results indicated that (1) is a three-dimensional (3D) coordination polymer while (2) is a twodimensional (2D) coordination polymer connected into a 3D network through hydrogen bonding. For both (1) and (2), the center metal is a Cu(II) cation. Compound (3) is a Cu(I) mononuclear complex which forms a 2D supramolecule via hydrogen bonding and π-π interactions. The SPS data for these three complexes exhibited photovoltage responses in the range of approximately 300 to 800 nm, indicating that all three possess some capacity for photoelectric conversion. The effects of composition, structure, dimensionality, ligands, valence states, and coordination environment of the central metal ions on the SPS results were investigated and discussed, as was the interrelationship between SPS and UV-Vis spectra.
- Cu (II/I) coordination polymer,
- Synthesis,
- Structure,
- Surface photovoltage spectrum,
- Photoelectron property
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沈阳化工大学材料科学与工程学院沈阳 110142